Induced surface and curvature tension equation of state for hadron resonance gas in finite volumes and its relation to morphological thermodynamics

Here, we develop an original approach to investigate the grand canonical partition function of the multicomponent mixtures of Boltzmann particles with hard-core interaction in finite and even small systems of the volumes above 20 fm3. The derived expressions of the induced surface tension equation of state (EoS) are analyzed in detail. It is shown that the metastable states, which can emerge in the finite systems with realistic interaction, appear at very high pressures at which the hadron resonance gas, most probably, is not applicable at all. It is shown how and under what conditions the obtained results for finite systems can be generalized to include into a formalism the equation for curvature tension. The applicability range of the obtained equations of induced surface and curvature tensions for finite systems is discussed and their close relations to the equations of the morphological thermodynamics are established. The hadron resonance gas model on the basis of the obtained advanced EoS is worked out. Also, this model is applied to analyze the chemical freeze-out of hadrons and light nuclei with the number of (anti-) baryons not exceeding 4. Their multiplicities were measured by the ALICE Collaboration in the central lead–lead collisions at the center-of-mass energy [Formula: see text] TeV.

Binding Reactions at Finite Systems

A perpetual yearn exists among computational scientists to scale-down the size of physical systems, a desire shared as well with experimentalists able to track single molecules. A question then arises whether averages observed at small systems are the same as those observed at large, or macroscopic, systems. Utilizing statistical-mechanics formulations in ensembles in which the total numbers of particles are fixed, we demonstrate that system's properties of binding reactions are not homogeneous functions. That means averages of intensive properties, such as the concentration of the bound-state, at finite-systems are different than those at large-systems. The discrepancy increases with decreasing numbers of particles, temperature, and volume. As perplexing as it may sound, despite these variations in average quantities, extracting the equilibrium constant from systems of different sizes does yield the same value. The reason is that correlations in reactants' concentrations are ought be accounted for in the expression of the equilibrium constant, being negligible at large-scale but significant at small-scale. Similar arguments pertain to the calculations of the reaction rate-constants, more specifically, the bimolecular rate of the forward reaction is related to the average of the product (and not to the product of the averages) of the reactants' concentrations. Furthermore, we derive relations aiming to predict the composition of the system only from the value of the equilibrium constant. All predictions are validated by Monte-Carlo and molecular dynamics simulations. An important significance of these findings is that the expression of the equilibrium constant at finite systems is not dictated solely by the chemical equation but requires knowledge of the elementary processes involved.

Transfer matrix in counting problems

The transfer matrix is a powerful technique that can be applied to statistical mechanics systems as, for example, in the calculus of the entropy of the ice model. One interesting way to study such systems is to map it onto a three-color problem. In this paper, we explicitly build the transfer matrix for the three-color problem in order to calculate the number of possible configurations for finite systems with free, periodic in one direction and toroidal boundary conditions (periodic in both directions)

Observation of higher-order non-Hermitian skin effect

Beyond the scope of Hermitian physics, non-Hermiticity fundamentally changes the topological band theory, leading to interesting phenomena, e.g., non-Hermitian skin effect, as confirmed in one-dimensional systems. However, in higher dimensions, these effects remain elusive. Here, we demonstrate the spin-polarized, higher-order non-Hermitian skin effect in two-dimensional acoustic higher-order topological insulators. We find that non-Hermiticity drives wave localizations toward opposite edges upon different spin polarizations. More interestingly, for finite systems with both edges and corners, the higher-order non-Hermitian skin effect leads to wave localizations toward two opposite corners for all the bulk, edge and corner states in a spin-dependent manner. We further show that such a skin effect enables rich wave manipulation by configuring the non-Hermiticity. Our study reveals the intriguing interplay between higher-order topology and non-Hermiticity, which is further enriched by the pseudospin degree of freedom, unveiling a horizon in the study of non-Hermitian physics.

Becoming Large, Becoming Infinite: The Anatomy of Thermal Physics and Phase Transitions in Finite Systems

This paper presents an in-depth analysis of the anatomy of both thermodynamics and statistical mechanics, together with the relationships between their constituent parts. Based on this analysis, using the renormalization group and finite-size scaling, we give a definition of a large but finite system and argue that phase transitions are represented correctly, as incipient singularities in such systems. We describe the role of the thermodynamic limit. And we explore the implications of this picture of critical phenomena for the questions of reduction and emergence.

A Concretization of an Approximation Method for Non-Affine Fractal Interpolation Functions

The present paper concretizes the models proposed by S. Ri and N. Secelean. S. Ri proposed the construction of the fractal interpolation function(FIF) considering finite systems consisting of Rakotch contractions, but produced no concretization of the model. N. Secelean considered countable systems of Banach contractions to produce the fractal interpolation function. Based on the abovementioned results, in this paper, we propose two different algorithms to produce the fractal interpolation functions both in the affine and non-affine cases. The theoretical context we were working in suppose a countable set of starting points and a countable system of Rakotch contractions. Due to the computational restrictions, the algorithms constructed in the applications have the weakness that they use a finite set of starting points and a finite system of Rakotch contractions. In this respect, the attractor obtained is a two-step approximation. The large number of points used in the computations and the graphical results lead us to the conclusion that the attractor obtained is a good approximation of the fractal interpolation function in both cases, affine and non-affine FIFs. In this way, we also provide a concretization of the scheme presented by C.M. Păcurar .