AbstractWe review Lie polynomials as a mathematical framework that underpins the structure of the so-called double copy relationship between gauge and gravity theories (and a network of other theories besides). We explain how Lie polynomials naturally arise in the geometry and cohomology of $$\mathcal {M}_{0,n}$$
M
0
,
n
, the moduli space of n points on the Riemann sphere up to Mobiüs transformation. We introduce a twistorial correspondence between the cotangent bundle $$T^*_D\mathcal {M}_{0,n}$$
T
D
∗
M
0
,
n
, the bundle of forms with logarithmic singularities on the divisor D as the twistor space, and $$\mathcal {K}_n$$
K
n
the space of momentum invariants of n massless particles subject to momentum conservation as the analogue of space–time. This gives a natural framework for Cachazo He and Yuan (CHY) and ambitwistor-string formulae for scattering amplitudes of gauge and gravity theories as being the corresponding Penrose transform. In particular, we show that it gives a natural correspondence between CHY half-integrands and scattering forms, certain $$n-3$$
n
-
3
-forms on $$\mathcal {K}_n$$
K
n
, introduced by Arkani-Hamed, Bai, He and Yan (ABHY). We also give a generalization and more invariant description of the associahedral $$n-3$$
n
-
3
-planes in $$\mathcal {K}_n$$
K
n
introduced by ABHY.