Evolution of the earth pressure coefficient of carbonate sand undergoing varying rate of dissolution

In fluid-saturated granular materials, the physicochemical interaction between pore-fluids and grain minerals alters packing conditions, which in turn leads to stress change deformation and, in extreme cases, even collapse. Chemical weathering, either naturally occurring or induced by human activities, is among such natural processes. This article presents an experimental study illustrating the major effects of chemical weathering on the deformation and stress state of granular materials, emphasising particulate systems entirely made by highly soluble carbonate grains. Laboratory experiments are conducted by subjecting acidic environments to granular assemblies under oedometric condition. The reaction rate is controlled by regulating various testing parameters, such as acid concentration and pore fluid flow rate. Experiments revealed that the lateral earth pressure steadily reduces in some cases, while others exhibit non-monotonic evolution. From a macroscopic standpoint, the rate of the chemical reaction was critical to determine the emergence of either of these trends. Such findings are relevant for any particulate system in which the stress conditions are controlled by multi-physical processes proceeding at different rates, such as waste products within bioreactors, gouge materials within faults and natural deposits subjected to the injection/extraction of reactive fluids.

Parent crater for Australasian tektites beneath the sands of the Alashan Desert, Northwest China: Best candidate ever?

ABSTRACT Australasian tektites represent the largest group of tektites on Earth, and their strewn field covers up to one sixth of Earth’s surface. After several decades of fruitless quest for a parent crater for Australasian tektites, mostly in the main part of the strewn field in Indochina, the crater remains undiscovered. We elaborate upon a recently suggested original hypothesis for the impact in the Alashan Desert in Northwest China. Evidence from geochemical and isotopic compositions of potential source materials, gravity data, and geographic, paleoenvironmental, and ballistic considerations support a possible impact site in the Badain Jaran part of the Alashan Desert. In further support of an impact location in China, glassy microspherules recovered from Chinese loess may be the right age to relate to the Australasian tektite event, perhaps as part of the impacting body. The most serious shortcomings of the commonly accepted Indochina impact location include signs of little chemical weathering of source materials of Australasian tektites, unlike highly weathered sedimentary targets in Indochina, and questionable assumptions about transport of distal ejecta.

The typology of rubies and their industrial significance

Information on the International Genetic Classification of Noble Corundum is given. The scheme of location of the main deposits and occurrences of ruby-bearing complexes of the world is attached: 1 – magmatic; 2 – metamorphogenic; 3 – sedimentary (residual ancient crusts of chemical weathering, alluvial and dealluvial-alluvial placers). The location of ruby objects is shown, including the largest areas of depleted, currently operating and promising for the near future ruby deposits in 36 countries around the world. The main typological features of rubies are described. It is emphasized that all properties of rubies are determined by their primary indigenous origin. The typology of rubies is based on the principles of the relationship between magmatism and metamorphism in the formation of the groups under consideration. Hydroblasting and selective crushing methods for mining of corundum-bearing complexes are characterised. The trend towards increased research into the commercial exploitation of the primary sources of ruby-bearing complexes is highlighted. In countries with highly developed mining industries, underground mining is the main way to extract gemstones.

Ge/Si Ratio of River Water in the Yarlung Tsangpo: Implications for Hydrothermal Input and Chemical Weathering

Germanium/Silicon (Ge/Si) ratio is a common proxy for primary mineral dissolution and secondary clay formation yet could be affected by hydrothermal and anthropogenic activities. To decipher the main controls of riverine Ge/Si ratios and evaluate the validity of the Ge/Si ratio as a weathering proxy in the Tibetan Plateau, a detailed study was presented on Ge/Si ratios in the Yarlung Tsangpo River, southern Tibetan Plateau. River water and hydrothermal water were collected across different climatic and tectonic zones, with altitudes ranging from 800 m to 5000 m. The correlations between TDS (total dissolved solids) and the Ge/Si ratio and Si and Ge concentrations of river water, combined with the spatial and temporal variations of the Ge/Si ratio, indicate that the contribution of hydrothermal water significantly affects the Ge/Si ratio of the Yarlung Tsangpo River water, especially in the upper and middle reaches. Based on the mass balance calculation, a significant amount of Ge (11–88%) has been lost during its transportation from hydrothermal water to the river system; these could result from the incorporation of Ge on/into clays, iron hydroxide, and sulfate mineral. In comparison, due to the hydrothermal input, the average Ge/Si ratio in the Yarlung Tsangpo River is a magnitude order higher than the majority of rivers over the world. Therefore, evaluation of the contribution of hydrothermal sources should be considered when using the Ge/Si ratio to trace silicate weathering in rivers around the Tibetan Plateau.

Rapid response of silicate weathering rates to climate change in the Himalaya

Chemical weathering of continental rocks plays a central role in regulating the carbon cycle and the Earth’s climate (Walker et al., 1981; Berner et al., 1983), accounting for nearly half the consumption of atmospheric carbon dioxide globally (Beaulieu et al., 2012). However, the role of climate variability on chemical weathering is still strongly debated. Here we focus on the Himalayan range and use the lithium isotopic composition of clays in fluvial terraces to show a tight coupling between climate change and chemical weathering over the past 40 ka. Between 25 and 10 ka ago, weathering rates decrease despite temperature increase and monsoon intensification. This suggests that at this timescale, temperature plays a secondary role compared to runoff and physical erosion, which inhibit chemical weathering by accel-erating sediment transport and act as fundamental controls in determining the feedback between chemical weathering and atmospheric carbon dioxide.

Characterization by Cone Penetration Tests of the decalcified Zandvliet Sand (Lillo Formation, North Belgium)

The sandy Zandvliet Member represents a particular, decalcified facies in the top of the Pliocene Lillo Formation in northern Belgium. Based on the correlation with nearby boreholes at the type locality of the Zandvliet Member, we were able to characterize this unit on Cone Penetration Tests. Compared to the underlying Merksem Member, the Zandvliet Member generally shows markedly lower cone resistance values. Since besides the decalcification, the Zandvliet Member is lithologically nearly identical to the underlying Merksem Member, the lower cone resistance values in the Zandvliet Member compared to the Merksem Member can only be the result of the decalcification of the Zandvliet Member. Indeed, the partly decalcified top of the Merksem Member also gives similar cone resistance values as the Zandvliet Member. Decalcification of the Eocene Brussel Sand in central Belgium is also known to have resulted in lower cone resistance values. Our Cone Penetration Test interpretations show that the thickness of the Zandvliet Member strongly varies across short distances (>10 m across 1 km). As the Zandvliet Member thickens, the underlying Merksem Member thins and vice versa. This trend is not in line with that of the under- and overlying strata, i.e. intraformational, nor with the depositional environment of these units. The thickness changes of the Zandvliet Member therefore purely reflect changes in depth of the post-depositional decalcification into the original shell-bearing sand (i.e. original Merksem Member). This confirms the existing hypothesis that the Zandvliet Member actually represents the decalcified part of the Merksem Member. The anomalous heavy mineralogy of the Zandvliet Member compared to the other members of the Lillo Formation cannot be readily explained by the acid chemical weathering which caused the decalcification. This may rather be related to a change in the primary heavy mineral signal of the upper part of the Merksem Member and equivalent Zandvliet Member compared to the underlying sequences of the Lillo Formation. The reason for the post-depositional decalcification could be similar to the Pleistocene changes in soil acidity invoked for decalcification of time-equivalent Red Crag sand in England.

Organic Petrographic and Geochemical Evaluation of the Black Shale of the Duwi Formation, El Sebaiya, Nile Valley, Egypt

This study evaluates the palynologic, organic, inorganic, and petrographic properties of organic-rich black shale (Mahamid Mine) in the El Sebaiya area, Nile Valley, Egypt. Black shale is composed of quartz (50%), calcite (10%), kaolinite (25%) and montmorillonite (15%). Organic and inorganic analyses revealed that this shale was deposited under oxic to anoxic marine conditions during strong chemical weathering. Black shale has poor to very good organic richness, and poor to fair hydrocarbon potential. Organic petrography indicates that the kerogen is mixed types II/III and III and is immature to marginally mature (%VRo is 0.44 and 0.53). Liptinite macerals consist of alginite, cutinite, and bituminite. The hydrocarbon products to be generated at higher maturity are expected to be oil and gas.