mixed valency
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Femtosecond X-ray Spectroscopy Directly Quantifies Transient Excited-State Mixed Valency

2022 ◽  
pp. 378-386
Author(s):  
Chelsea Liekhus-Schmaltz ◽  
Zachary W. Fox ◽  
Amity Andersen ◽  
Kasper S. Kjaer ◽  
Roberto Alonso-Mori ◽  
...  
Keyword(s):  
Excited State ◽  
Mixed Valency ◽  
X Ray

scholarly journals Ferrocene Metallopolymers of Intrinsic Microporosity (MPIMs)

2021 ◽  
Author(s):  
Tianran Zhai ◽  
Kenson Ambrose ◽  
Adit Nyayachavadi ◽  
Kelly G. Walter ◽  
Simon Rondeau-Gagné ◽  
...  
Keyword(s):  
Surface Area ◽  
Spectroscopic Analysis ◽  
Building Blocks ◽  
Accessible Surface Area ◽  
Mixed Valency ◽  
Surface Areas ◽  
Accessible Surface ◽  
Intrinsic Microporosity ◽  
As Solubility

We show here that non-network metallopolymers can possess intrinsic microporosity stemming from contortion introduced by metallocene building blocks. Metallopolymers constructed from ferrocenyl building blocks linked by phenyldiacetylene bridges are synthesized and possess BET surface areas up to 400 m2/g. As solubility imparted by pendant groups reduces porosity, copolymerization is used to simultaneously improve both accessible surface area and solubility. Spectroscopic analysis provides evidence that mixed valency between neighboring ferrocenyl units is supported in these polymers.

scholarly journals Femtosecond X-ray Spectroscopy Directly Quantifies Transient Excited State Mixed Valency and Subsequent Vibronic Dynamics

2021 ◽  
Author(s):  
Chelsea Liekhus-Schmaltz ◽  
Zachary Fox ◽  
Amity Andersen ◽  
Kasper Kjaer ◽  
Roberto Alonso-Mori ◽  
...  
Keyword(s):  
Excited State ◽  
Mixed Valency ◽  
X Ray

Interdigitated Pt–Br chains with π-stacking: an approach toward Robin–Day class I mixed valency in MX-chain complexes

2021 ◽  
Author(s):  
Unjila Afrin ◽  
Kentaro Fuku ◽  
Mengxing Cui ◽  
Hiroaki Iguchi ◽  
Mohammad Rasel Mian ◽  
...  
Keyword(s):  
Chain Complex ◽  
Class I ◽  
Mixed Valency ◽  
Π Stacking ◽  
Chain Complexes

The first interdigitated MX-type chain complex with infinite π-stacked arrays was synthesized.

scholarly journals Di- and Tri-nuclear VIII and CrIII Complexes of Dipyridyltriazoles: Ligand Rearrangements, Mixed Valency and Ferromagnetic Coupling

2020 ◽  
Vol 8 ◽  
Author(s):  
Julia Rinck ◽  
Jonathan A. Kitchen ◽  
Anthony B. Carter ◽  
Yanhua Lan ◽  
Christopher E. Anson ◽  
...  
Keyword(s):  
Ferromagnetic Coupling ◽  
Mixed Valency ◽  
Ligand Rearrangements

scholarly journals Dynamical Bonding Driving Mixed Valency in a Metal Boride

2020 ◽  
Vol 132 (27) ◽  
pp. 11089-11095
Author(s):  
Paul J. Robinson ◽  
Julen Munarriz ◽  
Michael E. Valentine ◽  
Austin Granmoe ◽  
Natalia Drichko ◽  
...  
Keyword(s):  
Metal Boride ◽  
Mixed Valency

scholarly journals Dynamical Bonding Driving Mixed Valency in a Metal Boride

2020 ◽  
Vol 59 (27) ◽  
pp. 10996-11002
Author(s):  
Paul J. Robinson ◽  
Julen Munarriz ◽  
Michael E. Valentine ◽  
Austin Granmoe ◽  
Natalia Drichko ◽  
...  
Keyword(s):  
Metal Boride ◽  
Mixed Valency

Effects of Mixed Valency in an Fe-Based Framework: Coexistence of Slow Magnetic Relaxation, Semiconductivity, and Redox Activity

2020 ◽  
Vol 59 (6) ◽  
pp. 3619-3630 ◽  
Author(s):  
Ryuichi Murase ◽  
Christopher J. Commons ◽  
Timothy A. Hudson ◽  
Guy N. L. Jameson ◽  
Chris D. Ling ◽  
...  
Keyword(s):  
Magnetic Relaxation ◽  
Redox Activity ◽  
Mixed Valency ◽  
Slow Magnetic Relaxation

MnO1.88/R-MnO2/Ti3C2(OH/F)x composite electrodes for high-performance pseudo-supercapacitors prepared from reduced MXenes

2020 ◽  
Vol 44 (16) ◽  
pp. 6583-6588
Author(s):  
Xinhua Huang ◽  
Xingxing Zhu ◽  
Shaohong Luo ◽  
Ru Li ◽  
Nitul Rajput ◽  
...  
Keyword(s):  
High Performance ◽  
Electrode Materials ◽  
Reducing Agent ◽  
Composite Electrodes ◽  
Mixed Valency

Mixed-valency MnOx (MnO1.88 and MnO2)/Ti3C2(OH/F)x composites electrode materials were in situ growth of MnOx on the surface of Ti3C2(OH/F)x, where the Ti3C2(OH/F)x acts as both template and reducing agent.

A Diruthenium Complex of an N ‐Pyridyl‐ o ‐aminophenol Derivative: A Route to Mixed Valency

2019 ◽  
Vol 25 (65) ◽  
pp. 14901-14911 ◽  
Author(s):  
Debarpan Dutta ◽  
Suman Kundu ◽  
Prasanta Ghosh
Keyword(s):  
Mixed Valency ◽  
Diruthenium Complex
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