EFFECT OF HOT CORROSION AND OXIDATION ON COBALT - BASE SUPERALLOYS COATED BY ALUMINUM WITH PRESENCE OF THERMAL BARRIER ZRO2 AND MIXTURE OF (NACL) AND (NA2SO4) STEAMSALTSAT HIGH TEMPERATURES

The aim of the study was to investigate the Mechanisms properties of thermal barrier coatings (TBCs) to enhance of performance evaluation characteristics and develop TBCs.Cobalt –base superalloy has been used as a substrate and zirconium stabilized Aluminum as ceramic topcoat , in addition the study include degradation behavior of system during thermal cycling (3hr per cycle in furnace) the failure of the aluminized was due to thermally grown oxide (TGO) interface. The fractures propagatethrough the interface and produce a deformation of the bond coating . the effect of cycle will result a spallation failure of the TBCsand this is also corresponding to a slightdegradation .The steam of salt (Nacl)and(Na2So4) mixture will affecton the coating lifetimes .The high temperature have a strong effect thermally grown oxide (TGO) which consistent with a first order growth of scale failer variation.

Predicting EBC Temperature Limits for Industrial Gas Turbines

Higher turbine inlet temperatures may require the use of ceramic matrix composites (CMC) such as SiC/SIC, which require environmental barrier coatings (EBCs) to protect them against the detrimental effect of water vapor. The goal of this project is to determine the maximum bond coating temperature for EBCs for land-based turbines, where the minimum coating lifetime is 25,000 h. If the temperature exceeds the 1414°C melting point of the Si bond coating, then coatings without a bond coating also need to be evaluated. Thus, current Yb2Si2O7 EBCs with a Si bond coating and next-generation EBCs without a Si bond coating are being evaluated in laboratory testing using 1-h cycles in air+90%H2O. For this initial work, coatings were deposited on CVD SiC coupons. Reaction kinetics at 1250°, 1300° and 1350°C have been evaluated by measuring the thickness of the thermally grown silica scale after 100–500 h exposures. For comparison, scale growth rates for uncoated SiC and Si specimens in dry and wet environments were included as minimum and maximum values, respectively. Based on a critical scale thickness failure criteria, estimated maximum temperatures were calculated for both EBC systems using this initial data.

Effect of Air Plasma Sprayed Flash Bond Coatings on Furnace Cycle Lifetime of Disks and Rods

Air plasma sprayed (APS) flash coatings on high velocity oxygen fuel (HVOF) bond coatings are well known to extend the lifetime of thermal barrier coatings (TBCs). Recent work compared flash coatings of NiCoCrAlY and NiCoCrAlYHfSi applied to both rods and disk substrates of alloy 247. For rod specimens, 100 h cycles were used at 1100 °C in wet air. Both flash coatings significantly improved the lifetime compared to HVOF-only and vacuum plasma spray (VPS)-only MCrAlY bond coatings with no statistical difference between the two flash coatings. For disk specimens tested in 1 h cycles at 1100 °C in wet air, the NiCoCrAlY flash coating significantly outperformed an HVOF-only NiCoCrAlYHfSi bond coating and a NiCoCrAlYHfSi flash coating. The flash coatings formed a mixed oxide-metal zone that appeared to inhibit crack formation and therefore extend lifetime. In addition to the flash coating increasing the bond coating roughness, the underlying HVOF layer acted as a source of Al for this intermixed zone and prevented the oxide from penetrating deeper into the bond coating. The lower Y+Hf content in the Y-only flash coating appeared to minimize oxidation in the flash layer, thereby increasing the benefit compared to a NiCoCrAlYHfSi flash coating.

Comprehensive Numerical Simulation on Thermally Grown Oxide and Internal Stress Evolutions in Thermal Barrier Coatings

TBCs (Thermal Barrier Coatings) is deposited on gas turbine blades to protect the substrate from a combustion gas flow. One of the serious problems occurred in gas turbine is TBC delamination which is caused by startup, steady and stop operation in service. TBC delamination results from subjecting to both cyclic thermal stress and evolution of internal stress due to thermally grown oxide (TGO). In this study, the finite element code which can simulate thermal and internal stress fields generated in TBC was developed. The developed code involves the follows: inelastic constitutive equation for ceramic coating, bilinear-type constitutive equation for bond coating and Chaboche-type inelastic constitutive equation for the substrate, and mass transfer equation in consideration of oxygen diffusion and chemical reaction with aluminum. Thermal cycling simulation was conducted using the developed code. It was confirmed that maximum stress and its location in the ceramic coating/bond coating interface were matched with the associated experimental results.

Effect of APS Flash Bond Coatings on Furnace Cycle Lifetime of Disks and Rods

Air plasma sprayed (APS) flash coatings on high velocity oxygen fuel (HVOF) bond coatings are well known to extend the lifetime of thermal barrier coatings. Recent work compared flash coatings of NiCoCrAlY and NiCoCrAlYHfSi applied to both rods and disk substrates of alloy 247. For rod specimens, 100-h cycles were used at 1100°C in wet air. Both flash coatings significantly improved the lifetime compared to HVOF-only and VPS-only MCrAlY bond coatings with no statistical difference between the two flash coatings. For disk specimens tested in 1-h cycles at 1100°C in wet air, the NiCoCrAlY flash coating significantly outperformed an HVOF-only NiCoCrAlYHfSi bond coating and a NiCoCrAlYHfSi flash coating. The flash coatings formed a mixed oxide-metal zone that appeared to inhibit crack formation and extend lifetime. In addition to the flash coating increasing the bond coating roughness, the underlying HVOF layer acted as a source of Al for this intermixed zone and prevented the oxide from penetrating deeper into the bond coating. The lower Y+Hf level in the Y-only flash coating appeared to minimize oxidation in the flash layer, thereby increasing the benefit compared to a NiCoCrAlYHfSi flash coating.

Laser Thermal Gradient Test of a Thermal Barrier Coating and Failure Analysis

Thermal barrier coatings (TBC) are used to protect the hot components of gas turbine engines to enhance thermal efficiency and component service life. It is critical for TBC development that a testing method be used to understand the potential and limitation of coating’s durability and integrity under the gas turbine engine operation conditions. In this paper, laser high heat flux testing with an applied temperature gradient across TBC coated buttons is presented. The ceramic coating is ZrO2-8 wt.% Y2O3 applied via the air plasma spraying process on top of a NiCoCrAlY bond coating and an Inconel alloy substrate button of 25.4 mm diameter. The coated button is subject to precisely-controlled laser heating on the top side (1150°C) and temperature gradient of 63.9°C/mm through the button overall thickness. The TBC button lasts 160.9 hr or 570 cycles of laser heating. Analysis of void fraction change before and after the test, thermal conductivity change during the laser test, and failure assessment are presented. After the test, the top coating has cracks in vertical or oblique directions and significant horizontal cracks near the top coating and bond coating interface. Significant horizontal top coating cracks close to the interface between the top coating and bond coating appear near the button center. Although the coating delamination has not occurred yet, at the end of the laser testing the button is close to delamination. Based on the horizontal cracks and the thermally grown oxide layer geometry, a finite element analysis is conducted to calculate the residual stress and the strain energy release rate. A possible approach to combine laser rig test result and finite element computation for developing a TBC service life model is discussed.

Contribution of High Mechanical Fatigue to Gas Turbine Blade Lifetime during Steady-State Operation

In this study, the contribution of high thermomechanical fatigue to the gas turbine lifetime during a steady-state operation is evaluated for the first time. An evolution of the roughness on the surface between the thermal barrier coating and bond coating is addressed to elucidate the correlation between operating conditions and the degradation of a gas turbine. Specifically, three factors affecting coating failure are characterized, namely isothermal operation, low-cycle fatigue, and high thermomechanical fatigue, using laboratory experiments and actual service-exposed blades in a power plant. The results indicate that, although isothermal heat exposure during a steady-state operation contributes to creep, it does not contribute to failure caused by coating fatigue. Low-cycle fatigue during a transient operation cannot fully describe the evolution of the roughness between the thermal barrier coating and the bond coating of the gas turbine. High thermomechanical fatigue during a steady-state operation plays a critical role in coating failure because the temperature of hot gas pass components fluctuates up to 140 °C at high operating temperatures. Hence, high thermomechanical fatigue must be accounted for to accurately predict the remaining useful lifetime of a gas turbine because the current method of predicting the remaining useful lifetime only accounts for creep during a steady-state operation and for low-cycle fatigue during a transient operation.