Charge State Of Impurity Atoms In Semiconductors Studyed By The Emission Mössbauer Spectroscopy Method

When studying the charge state and symmetry of the local environment of impurities, based on the data of nuclear gamma-resonance spectroscopy, it is concluded that the state of impurity atoms depends both on the type of conductivity and on whether these atoms are in the surface layer or in the bulk of semiconductors.

Peculiarities of crystal structure and superfine interactions in alloys Ti-Co-Sn

Alloys with the general formula TiCo2-хSn were produced by way of sintering primary components – pure metals in an argon atmosphere. The alloys were homogenized by annealing in the evacuated quartz vessel at T=1070 K during 500 h. X-ray diffraction analysis confirmed single-phase condition of all samples. Nuclear gamma resonance (NGR) analysis was made at T=295 and 80 K using radiation source BaSn119Sn. It was established, that Sn atoms in samples with x=0.6 and 1.0 are in two crystallographic positions, pyramids (1) and tetrahedrons (2) to which isomer shifts correspond (relative to SnO2 1.52-1.65 mm/s for Sn(1) and 2.99 mm/s for Sn(2). Zeeman splitting for Sn(1) in TiCo2Sn takes place at T=295 and 80 K, and for compositions with x=0.3-1.0 at T=80 K only. For Sn(2) it is noted only in alloy TiCoSn at T=80 K. The conclusion has been made on the reason of formation of effective magnetic fields on non-magnetic tin atoms nuclei.

Influence of Thermomagnetic Treatment on the Damping Properties and Structure of Iron-Based Alloys

The paper describes the influence of thermomagnetic treatment on the parameters of the amplitude dependence of internal friction, the crystal and magneto-crystalline structure of Fe alloys with ferrite structure: Fe – 8%Cr, Fe – 16%Cr, Fe – 19%Cr, Fe – 4%Cr – 2%V, Fe – 3%Cr – 3%Al, and Fe–1.2%C–2% Si–2%Al graphitic steel with graphite and ferrite structure. The thermomagnetic treatment was carried out at a temperature of 450ºС. The structure was studied by means of metallography, X-ray crystal structure analysis, ferromagnetic resonance, and nuclear gamma resonance spectroscopy. It is shown that, the larger the ferrite grain in alloys with ferrite structure is, the greater an increase in internal friction is, in the amplitude range up to approximately the amplitude of its maximum owing to thermomagnetic treatment. The change of the damping properties of graphitic steel caused by thermomagnetic treatment is relatively small, due to a large number of diamagnetic inclusions of graphite and quite fine-grained ferrite matrix. The results of the X-ray crystal structure analysis, the ferromagnetic resonance and nuclear gamma resonance spectroscopy have shown that, in the case of thermomagnetic treatment, diffusion redistribution of atoms of alloying elements, combined with the change of structural anisotropy, takes place in Fe-Cr alloys.

Use of nuclear physics methods for investigation of short-range ordering and defects in iron based simulatuing alloys

The changes of short range ordering and electron density were investigated by means of the nuclear gamma-resonance and the positron annihilation spectroscopies in model alloys containing tungsten, chromium, molybdenum, and vanadium used as dopants. The change of the short-range ordering parameter sign was detected in alloys containing vanadium. Different ordering was also observed in binary and ternary iron alloys. It was shown that dislocations were the main defects in these materials after rolling.

Исследование Sr-допированных ферроманганитов иттербия методами ЭПР и мессбауэровской спектроскопии

In this paper, we have studied the crystal structure of strontium-substituted manganite and ytterbium ferromanganites Yb_0.82Sr_0.18Mn_1 – x Fe_ x O_3 ( x = 0–0.2) by using X-ray diffraction analysis. Magnetic microstructure has been studied by electron paramagnetic resonance and nuclear gamma-resonance (Mössbauer) spectroscopy. We have observed phase separation in the ceramics for antiferromagnetic, superparamagnetic, and ferromagnetic phases.