Ni-Doped Protonated Layered Titanate/TiO2 Composite with Efficient Photocatalytic Activity for NO x Decomposition Reactions

A unique structural transformation of a lepidocrocite-type layered titanate, K0.8Ti1.73Li0.27O4, into a rutile-type TiO2 has recently been realized via dilute HCl treatment and subsequent drying at room temperature for producing rutile-nanoparticle-decorated protonated layered titanate exhibiting highly efficient photocatalytic activity. Herein, the authors report synthesis of a lepidocrocite-type layered cesium titanate with nominal compositions of C s 0.7 T i 1.825 ‐ x / 2 N i x □ 0.175 ‐ x / 2 O 4 ( x = 0 , 0.05, 0.1, and 0.35) through solid-state reactions of Cs2CO3, TiO2, and Ni(CH3COO)2·4H2O at different temperatures (600 or 800°C), followed by treatment with dilute HCl and subsequent drying to produce a Ni-doped protonated layered titanate/TiO2 composite. C s 0.7 T i 1.825 ‐ x / 2 N i x □ 0.175 ‐ x / 2 O 4 with an optimized Ni content obtained at a lower temperature was converted into a Ni-doped protonated layered titanate/TiO2 composite to exhibit high photocatalytic activity for NO x decomposition reactions.

Remarkably Enhanced Ion-Exchange Capacity of H2O2-Intercalated Layered Titanate

The H2O2-intercalated layered titanate H1.07Ti1.73O4 (H2O2-HTO) exhibits a dramatically enhanced ion-exchange capacity and remarkably improved reaction rate with various divalent cations. The intercalation can increase negative charge density of TiO6...

Introducing a conductive pillar: a polyaniline intercalated layered titanate for high-rate and ultra-stable sodium and potassium ion storage

An in situ formed polyaniline pillared layered titanate with uniform TiO2 coating for sodium and potassium ion storage is proposed.