Non-perturbative determination of collisional broadening and medium induced radiation in QCD plasmas

We supply recently obtained results from lattice EQCD with the correct UV limit to construct the collisional broadening kernel C(b⊥) in a QCD plasma. We discuss the limiting behavior of C(b⊥) at small and large impact parameters b⊥, and illustrate how the results can be used to compute medium-induced radiation rates.

H2O Collisional Broadening Coefficients at 1.37 µm and Their Temperature Dependence: A Metrology Approach

We report self- and air collisional broadening coefficients for the H2O line at 7299.43 cm−1 and corresponding temperature coefficients for a temperature range spanning 293–573 K. New laser spectroscopic setups specifically designed for this purpose have been developed and are described. The line parameters reported here are in good agreement with those values reported in the HITRAN 2020 database, but the uncertainties have been reduced by factors of about 4, 1.3 and 4.4 for the self-broadening coefficient, air broadening coefficient and the temperature exponent of air broadening, respectively. Further, we combined our measurement approach with metrological data quality objectives, addressing the traceability of the results to the international system of units (SI) and evaluated the uncertainties following the guide to the expression of uncertainty in measurement (GUM).

Ultraviolet spectroscopy of pressurized and supercritical carbon dioxide

Carbon dioxide (CO2) is prevalent in planetary atmospheres and sees use in a variety of industrial applications. Despite its ubiquitous nature, its photochemistry remains poorly understood. In this work we explore the density dependence of pressurized and supercritical CO2 electronic absorption spectra by vacuum ultraviolet spectroscopy over the wavelength range 1455-2000 Å. We show that the lowest absorption band transition energy is unaffected by a density increase up to and beyond the thermodynamic critical point (137 bar, 308 K). However, the diffuse vibrational structure inherent to the spectrum gradually decreases in magnitude. This effect cannot be explained solely by collisional broadening and/or dimerization. We suggest that at high densities close proximity of neighboring CO2 molecules with a variety of orientations perturbs the multiple monomer electronic state potential energy surfaces, facilitating coupling between binding and dissociative states. We estimate a critical radius of ~4.1 Å necessary to cause such perturbations.