Coal samples of Eocene age (Shella Formation) from four different mines (Bapung, Jaintia, Sutunga, and Lakadong) of the Jaintia Hills of Meghalaya, Northeast India, were collected and investigated to observe the sulphur content and to understand the palaeoenvironment, utilisation prospects, and environmental impact. The study reveals that these coal samples contain sulphur in higher concentration (4.46% to 7.26%) both organic and inorganic forms. There are 3 coal seams exposed in the area. The organic sulphur is higher (2.53%-5.49%) than the inorganic forms (1.26%-1.77%). The upper seam is found to contain higher concentration of sulphur than the lower seam. Intra seam pyritic sulphur also shows an upward increasing trend. The high sulphur content in the coal seams suggests the marine influence in the peat-forming swamps. These coals are classified as High Sulphur coal (>1%) which is the main obstacle in the utilization although high volatile matter and hydrogen content strongly suggest that these coals are good for liquefaction. Moreover, during coal combustion emissions of sulphur dioxide produce acid rain, affecting the environment of the mine areas.