Methodology for composite materials shrinkage definition for use in shipbuilding and marine technology

Deformations of steel material in shipbuilding and marine technology applications as a result of mechanical or temperature influences are a well-known problem. However, in the modern shipbuilding industry, the application of alternative materials, especially composite materials, in the structure and for the equipment of the ship is increasingly represented. Consequently, there is a need to determine the deformation and change of characteristics of such composite materials as a result of various mechanical, and especially temperature influences that cause the so-called shrinkage. The basic composite production process involves connecting the matrix with a catalyst and accelerators that create temperature, then the material shrinks by cooling when it can change its dimensions and characteristics. Also, in order to achieve the best possible mechanical properties, composite materials are specially heated and then cooled according to strictly defined processes and curves. The ability to predict the characteristics and parameters of such deformations is important in the context of the application of composite materials. To define such deformations, different methods are used within individual numerical solvers, whose results can differ significantly from each other. Therefore, the authors in this paper present an established methodology for predicting mechanical and temperature deformations, and modelling of composite materials, based on the analysis of analytical methods and numerical solvers with the aim of defining the most accurate numerical solver. By applying the presented methodology, it is expected to raise the level of accuracy and quality of composite materials production as well as to raise the quality of design solutions and efficiency of production procedures during shipbuilding in particular, but also within different marine technology applications and during the product’s life cycle.

Production and Characterization of Animal Waste Reinforced Composite Materials By Powder Metallurgy

Boron carbide is a product used for reinforcement in composite production and frequently used in the defense industry. The fact that boron carbide behaves similarly to the mechanical properties of bone and that titanium is strengthened with boron carbide, which is used as a biomaterial, causes it to be preferred among composite materials. It also makes it attractive to use in industrial applications at high temperatures. It is known that Fe-B4C composites are used together with Fe matrix materials to improve the properties of the group in addition to elements such as Cr, especially Ti, Co, Mo and Fe in various application areas. This makes it frequently used in the sintering process. In this study, 98,33%Fe-1,66%B4C, 96.66%Fe-1,66%B4C-1,66%eggshell powders, 95%Fe-1,66%B4C-3,32%eggshell powders, 93,33%Fe-1,66%B4C-5%eggshell powders and 91,66%Fe-1,66%B4C-6,66% eggshell powder samples were prepared using the compositions of. It is formed in a single axis press under 400bar pressure. When the mechanical and metallographic properties of the samples produced after sintering at 1400 ᵒC were examined, the effects of eggshell powders on composite samples produced by adding Fe-B4C composite and eggshell powders in different compositions were observed. 1,66% to 6,66% eggshell powders additive was used in the compositions and mechanical properties were determined in the produced samples. Structural features were tried to be determined by looking at metallographic analyses. The densities of the produced samples were calculated and their hardness and strength were determined. According to the analysis results, 3,33% Egshelters composition and 3,71 gr/cm3 density and 285,5 HV hardness values ​​at 1400 °C were obtained.

Chemical and Mechanical Characterization of Licorice Root and Palm Leaf Waste Incorporated into Poly(urethane-acrylate) (PUA)

A poly(urethane-acrylate) polymer (PUA) was synthesized, and a sufficiently high molecular weight starting from urethane-acrylate oligomer (UAO) was obtained. PUA was then loaded with two types of powdered ligno-cellulosic waste, namely from licorice root and palm leaf, in amounts of 1, 5 and 10%, and the obtained composites were chemically and mechanically characterized. FTIR analysis of final PUA synthesized used for the composite production confirmed the new bonds formed during the polymerization process. The degradation temperatures of the two types of waste used were in line with what observed in most common natural fibers with an onset at 270 °C for licorice waste, and at 290 °C for palm leaf one. The former was more abundant in cellulose (44% vs. 12% lignin), whilst the latter was richer in lignin (30% vs. 26% cellulose). In the composites, only a limited reduction of degradation temperature was observed for palm leaf waste addition and some dispersion issues are observed for licorice root, leading to fluctuating results. Tensile performance of the composites indicates some reduction with respect to the pure polymer in terms of tensile strength, though stabilizing between data with 5 and 10% filler. In contrast, Shore A hardness of both composites slightly increases with higher filler content, while in stiffness-driven applications licorice-based composites showed potential due to an increase up to 50% compared to neat PUA. In general terms, the fracture surfaces tend to become rougher with filler introduction, which indicates the need for optimizing interfacial adhesion.

Aluminum Alloy Selection for In Situ Composite Production by Oxygen Blowing

We considered the possibility of using AlMg10, AlCu5, AlCu5Cd, AlSi12, and AlSi7Zn9 as initial alloys for in situ composites production via oxygen blowing of hydrogen pre-saturated melts as an alternative to AlSi7Fe. The production process provides the destruction of the oxide film on the melt surface. It was demonstrated that oxide film on AlMg10 alloy did not get destroyed due to the heavy thickness because of the porous structure that contributed to its kinetically based growth. Copper-bearing alloys AlCu5 and AlCu5Cd were characterized by the low-strength oxide film and got destroyed before floating, causing the oxide porosity. Silicon-bearing alloys AlSi12 and AlSi7Zn9 provide the dense structure, which makes it clear that to understand the Pilling–Bedworth ratio for basic alloying elements is required for a non-destructed oxide void floating and shall exceed the range of 1.64–1.77. However, the oxide film in silicon-bearing alloys under investigation did not get destroyed into fine particles. AlSi7Zn9 alloy had inclusions of smaller sizes as compared to AlSi12 alloy due to the ZnO that embrittled the film, but which were grouped to form oxide islands. Moreover, zinc was evaporated during blowing. The mechanical properties of the produced composites were based on the alloys under investigation which were in line with their structures. A higher value of the Pilling–Bedworth ratio of impurities was required for fine crushing: The conventionally used AlSi7Fe alloy met this requirement and was therefore considered to be the optimum version.

Rice waste–based polymer composites for packaging applications: A review

Rice wastes are abundant, low-cost, cellulosic-based materials. The potential of using rice waste such as husk, straw, and bran in bio-composite production is a crucial target of the composite industry. Chemical composition is the main factor that offers diverse possible applications of rice wastes in bio-composite-based materials. Eco-friendly products of bio-composite polymers can be produced by reinforcing and filling polymer matrices with high cellulosic content materials such as rice waste. From manufacturing point of view, rice wastes can be used to reduce the production cost of polymer-based products and meet the requirements for green packaging materials.

Electrochemical and photoluminescence response of laser-induced graphene/electrodeposited ZnO composites

The inherent scalability, low production cost and mechanical flexibility of laser-induced graphene (LIG) combined with its high electrical conductivity, hierarchical porosity and large surface area are appealing characteristics for many applications. Still, other materials can be combined with LIG to provide added functionalities and enhanced performance. This work exploits the most adequate electrodeposition parameters to produce LIG/ZnO nanocomposites. Low-temperature pulsed electrodeposition allowed the conformal and controlled deposition of ZnO rods deep inside the LIG pores whilst maintaining its inherent porosity, which constitute fundamental advances regarding other methods for LIG/ZnO composite production. Compared to bare LIG, the composites more than doubled electrode capacitance up to 1.41 mF cm−2 in 1 M KCl, while maintaining long-term cycle stability, low ohmic losses and swift electron transfer. The composites also display a luminescence band peaked at the orange/red spectral region, with the main excitation maxima at ~ 3.33 eV matching the expected for the ZnO bandgap at room temperature. A pronounced sub-bandgap tail of states with an onset absorption near 3.07 eV indicates a high amount of defect states, namely surface-related defects. This work shows that these environmentally sustainable multifunctional nanocomposites are valid alternatives for supercapacitors, electrochemical/optical biosensors and photocatalytic/photoelectrochemical devices.

Utilization of Thermally Treated SiC Nanowhiskers and Superplasticizer for Cementitious Composite Production

Nanomaterials are potential candidates to improve the mechanical properties and durability of cementitious composites. SiC nanowhiskers (NWs) present exceptional mechanical properties and have already been successfully incorporated into different matrices. In this study, cementitious composites were produced with a superplasticizer (SP) and 0–1.0 wt % SiC NWs. Two different NWs were used: untreated (NT-NW) and thermally treated at 500 °C (500-NW). The rheological properties, cement hydration, mechanical properties, and microstructure were evaluated. The results showed that NWs incorporation statistically increased the yield stress of cement paste (by up to 10%) while it led to marginal effects in viscosity. NWs enhanced the early cement hydration, increasing the main heat flow peak. NWs incorporation increased the compressive strength, tensile strength, and thermal conductivity of composites by up to 56%, 66%, and 80%, respectively, while it did not statistically affect the water absorption. Scanning electron microscopy showed a good bond between NWs and cement matrix in addition to the bridging of cracks. Overall, the thermal treatment increased the specific surface area of NWs enhancing their effects on cement properties, while SP improved the NWs dispersion, increasing their beneficial effects on the hardened properties.

Are Natural-Based Composites Sustainable?

This paper assesses the aspects related to sustainability of polymer composites, focusing on the two main components of a composite, the matrix and the reinforcement/filler. Most studies analyzed deals with the assessment of the composite performance, but not much attention has been paid to the life cycle assessment (LCA), biodegradation or recyclability of these materials, even in those papers containing the terms “sustainable” (or its derivate words), “green” or “eco”. Many papers claim about the sustainable or renewable character of natural fiber composites, although, again, analysis about recyclability, biodegradation or carbon footprint determination of these materials have not been studied in detail. More studies focusing on the assessment of these composites are needed in order to clarify their potential environmental benefits when compared to other types of composites, which include compounds not obtained from biological resources. LCA methodology has only been applied to some case studies, finding enhanced environmental behavior for natural fiber composites when compared to synthetic ones, also showing the potential benefits of using recycled carbon or glass fibers. Biodegradable composites are considered of lesser interest to recyclable ones, as they allow for a higher profitability of the resources. Finally, it is interesting to highlight the enormous potential of waste as raw material for composite production, both for the matrix and the filler/reinforcement; these have two main benefits: no resources are used for their growth (in the case of biological materials), and fewer residues need to be disposed.

Electrochemical and Photoluminescence Response of Laser-induced Graphene/Electrodeposited ZnO Composites

The inherent scalability, low production cost and mechanical flexibility of laser-induced graphene (LIG) combined with its high electrical conductivity, hierarchichal porosity and large surface area are appealing characteristics for many applications. Still, other materials can be combined with LIG to provide added functionalities and enhanced performance. This work exploits the most adequate electrodeposition parameters to produce LIG/ZnO nanocomposites. Low-temperature pulsed electrodeposition allowed the conformal and controlled deposition of ZnO rods deep inside the LIG pores whilst maintaining its inherent porosity, which constitute fundamental advances regarding other methods for LIG/ZnO composite production. Compared to bare LIG, the composites more than doubled electrode capacitance up to 1.41 mF.cm-2 in 1 M KCl, whilst maintaining long-term cycle stability, low ohmic losses and swift electron transfer. The composites also display a luminescence band peaked at the orange/red spectral region, with main excitation maxima at ~3.33 eV matching the expected for the ZnO bandgap. A pronounced sub-bandgap tail of states with an onset absorption near 3.07 eV indicates a high amount of surface states. This work shows that these environmentally sustainable multifunctional nanocomposites are valid alternatives for supercapacitors, electrochemical/optical biosensors and photocatalytic/photoelectrochemical devices.