Highly anisotropic thermal conductivity and electrical insulation of nanofibrillated cellulose/Al2O3@rGO composite films: effect of the particle size

Abstract: Nanofibrillated cellulose (NFC) film has received tremendous attention due to its excellent electrical insulation, which shows great application prospects in the field of electronic devices. However, the low efficient heat dissipation of NFC film largely limits its use in advanced applications. In this work, the rGO hybrid fillers loaded alumina (Al2O3) particles with different sizes were synthesized by different drying methods and then they were mixed with NFC to prepare a series of NFC-based composite films. The effect of Al2O3 particle sizes on the thermal conductivity of NFC-based composite films was studied. The results showed that the surface areas of l-Al2O3 particles were smaller than that of s-Al2O3 particles, resulting in the smaller interface thermal resistance and superior thermal conductivity of the film containing l-Al2O3 particles. The NFC-based composite films showed great potential for the applications in thermal management by adjusting the particle size of fillers.

Impact of Al2O3 Particle Size on the Open Porosity of Ni/Al2O3 Composites Prepared by the Thermal Oxidation at Moderate Temperatures

The performance of attractive Ni-based composites can be affected by changing their microstructures, e.g., introducing pores. Here, we report a novel, relatively low-cost process to fabricate Ni/Al2O3 composites with open porosity modified by the size of Al2O3 particles. The mixture of powders was subjected to thermal oxidation twice in air after a maximal temperature of 800 °C was reached in a stepwise manner and maintained for 120 min. The oxidation kinetics were determined thermogravimetrically. The open porosity was evaluated by an Archimedes’ principle-based method. Localization and quantification of NiO, newly formed on the Ni particle surface and acting as a mechanical bonding agent, were explored by scanning electron microscopy with energy dispersive X-ray spectroscopy and X-ray diffractometry. Larger ceramic particles prevented merging of NiO layers on adjacent Ni particles more efficiently; therefore, the open porosity increased from 21% to 24.2% when the Al2O3 particle diameter was increased from 5–20 µm to 32–45 µm. Because both Ni/Al2O3 composites exhibited similar flexural strength, the composite with larger Al2O3 particles and the higher open porosity could be a better candidate for infiltration by molten metal, or it can be directly used in a variety of filtration applications.

Phase Transformations and Subsurface Changes in Three Dental Zirconia Grades after Sandblasting with Various Al2O3 Particle Sizes

Although sandblasting is mainly used to improve bonding between dental zirconia and resin cement, the details on the in-depth damages are limited. The aim of this study was to evaluate phase transformations and subsurface changes after sandblasting in three different dental zirconia (3, 4, and 5 mol% yttria-stabilized zirconia; 3Y-TZP, 4Y-PSZ, and 5Y-PSZ). Zirconia specimens (14.0 × 14.0 × 1.0 mm3) were sandblasted using different alumina particle sizes (25, 50, 90, 110, and 125 µm) under 0.2 MPa for 10 s/cm2. Phase transformations and residual stresses were investigated using X-ray diffraction and the Williamson-Hall method. Subsurface damages were evaluated with cross-sections by a focused ion beam. Stress field during sandblasting was simulated by the finite element method. The subsurface changes after sandblasting were the emergence of a rhombohedral phase, micro/macro cracks, and compressive/tensile stresses depending on the interactions between blasting particles and zirconia substrates. 3Y-TZP blasted with 110-µm particles induced the deepest transformed layer with the largest compressive stress. The cracks propagated parallel to the surface with larger particles, being located up to 4.5 µm under the surface in 4Y- or 5Y-PSZ subgroups. The recommended sandblasting particles were 110 µm for 3Y-TZP and 50 µm for 4Y-PSZ or 5Y-PSZ for compressive stress-induced phase transformations without significant subsurface damages.

Microstructure, Mechanical, and Corrosion Behavior of Al2O3 Reinforced Mg2Zn Matrix Magnesium Composites

Powder metallurgy (PM) method is one of the most effective methods for the production of composite materials. However, there are obstacles that limit the production of magnesium matrix composites (MgMCs), which are in the category of biodegradable materials, by this method. During the weighing and mixing stages, risky situations can arise, such as the exposure of Mg powders to oxidation. Once this risk is eliminated, new MgMCs can be produced. In this study, a paraffin coating technique was applied to Mg powders and new MgMCs with superior mechanical and corrosion properties were produced using the hot pressing technique. The content of the composites consist of an Mg2Zn matrix alloy and Al2O3 particle reinforcements. After the debinding stage at 300 °C, the sintering process was carried out at 625 °C under 50 MPa pressure for 60 min. Before and after the immersion process in Hank’s solution, the surface morphology of the composite specimens was examined by scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) analysis. With the hot pressing technique, composite specimens with a very dense and homogeneous microstructure were obtained. While Al2O3 reinforcement improved the mechanical properties, it was effective in changing the corrosion properties up to a certain extent (2 wt.% Al2O3). The highest tensile strength value of approximately 191 MPa from the specimen with 8 wt.% Al2O3. The lowest weight loss and corrosion rate were obtained from the specimen containing 2 wt.% Al2O3 at approximately 9% and 2.5 mm/year, respectively. While the Mg(OH)2 structure in the microstructure formed a temporary film layer, the apatite structures containing Ca, P, and O exhibited a permanent behavior on the surface, and significantly improved the corrosion resistance.

Al2O3 Particle Erosion Induced Phase Transformation: Structure, Mechanical Property, and Impact Toughness of an SLM Al-10Si-Mg Alloy

This study investigated the microstructure, mechanical properties, impact toughness, and erosion characteristics of Al-10Si-Mg alloy specimens manufactured using the selective laser melting (SLM) method with or without subsequent T6 heat treatment. Furthermore, the erosion phase transformation behavior of the test specimens was analyzed, and the effect of the degradation mechanism on the tensile mechanical properties and impact toughness of the SLM Al-10Si-Mg alloy specimens before and after particle erosion was compared. The experimental results indicated that the Al-10Si-Mg alloy subjected to T6 heat treatment has better erosion resistance than the as-fabricated material. The tensile strength and fracture toughness of both specimen groups decreased due to the formation of microcracks on the surface caused by particle erosion. Nevertheless, the erosion-induced silicon nanoparticle solid solution softens the Al matrix and improves the elongation of the SLM Al-10Si-Mg alloy.

Effects of Particle Properties on Visualizing Flows in a Two- Stage Electrostatic Precipitator Using Particle Image Velocimetry

The amount of particulate matter (PM) in the environment has been confirmed to be health risks on human bodies[1, 2], and therefore removing suspended particles has become the research goal of many studies. Electrostatic precipitator (ESP) is one of the high-efficiency particle collection technologies[3-7]. Particle Image Velocimetry (PIV) has been an effective tool for visualizing the flow patterns in experimental fluid mechanics, and many studies adopted this technique to study flows in ESP[8-10]. However, particles charged by the electric field can cause deviation in measurement results since it does not follow the ionized air flow which can be charged differently from the tracer particles. In this study, the observation of the effects of different particle properties on flow field in a two-stage ESP is the objectives of this study. A two-stage ESP was built and four different seeding particles, aluminum oxide (Al2O3) particle, oil droplet particle, sodium chloride (NaCl) particle, and titanium dioxide (TiO2) particle, are tested in the current study. In this study, the streamwise velocity of the flows ranges from 2.36 m/s to 4.18 m/s, the voltage of the corona electrode varies from 8 kV to 12 kV with a positive polarity, and the voltage of the collector electrode is fixed at 16 kV. To investigate the 3-D flow patterns inside the channel, data at different planes were taken for comparison. The results show that by increasing charge voltage from 8 kV to 12 kV with a streamwise flow velocity the 2.36 m/s, the y-component velocity for Al2O3 particle, oil droplet particle, NaCl particle and TiO2 particle increased by 50.6%, 76.0%, 33.5% and 51.9%, respectively. Moreover, for the case of the 4.18 m/s primary flow, the y-component velocity for Al2O3 particle, oil droplet particle, NaCl particle and TiO2 particle increase by 52.7%, 59.2%, 59.4% and 65.9% after the voltages increase from 8 kV to 12 kV. PIV results for oil droplet particle shows slower y-component velocities, which can be due to the lower Archimedes number of 3.12E-06 and the mobility number that is larger than 3. On the contrary, in most of results from TiO2 particles show high y-component velocity, which is due to the highest Archimedes number of 1.15E-03 of the seeding particles tested in this study. This result shows that the particle is less affected by buoyancy effect. The PIV results of the middle plane also shows that the ycomponent of velocity from -2.6 m/s to -0.5 m/s, in contrast to -1.0 m/s to 1.0 m/s from the near wall observation plane. These results are consistent to simulation results of the electric field distribution, whichshows unequal electric field strengths between the middle and near wall regions of the test section. Only half of the cage shape distribution of the electric field can be observed, and primary flow influences the ionic wind to move to the downstream area. Based on the results, the oil droplet and TiO2 particles are more suitable for the role of tracer particles compared to aluminum oxide and sodium chloride particles.

Mechanical, tribological, and corrosion properties of composite NiP-Al2O3 with different amount of particles

In this study, the influence of Al2O3 particle amounts on the mechanical, tribological, and corrosion properties of the composite NiP-Al2O3 coating was evaluated. AISI 4140 steel was coated with NiP through an autocatalytic bath with the addition of Al2O3 particles maintained in suspension by mechanical stirring. Following, the coated samples were annealed at 600 °C to increase the hardness and to create an interdiffusion layer, which improves coating adhesion and corrosion resistance. The coating surface was characterized by SEM/EDS, XRD, microhardness, wear resistance, and corrosion tests. The results showed that the coating particles' amount depends on the bath agitation speed, the sample orientation during the deposition, and the volume of Al2O3 particles in the bath composition. Also, the number of particles in the coating affects the deposition kinetics, the thickness of the interdiffusion layer, which affects the wear and corrosion resistance.

PREPARATION OF Cu MATRIX COMPOSITE REINFORCED WITH IN-SITU NANOSIZED Al2O3 PARTICLE POWDER FROM METAL NITRATES

The objective of the present work is to investigate the feasibility of the synthesis of copper matrix composite reinforced with in-situ nanosized Al2O3 particle powder via combustion synthesis method from metal nitrates followed by reducing process at high temperature. The starting nitrates Cu(NO3)2.3H2O and Al(NO3)3·9H2O composition corresponds to Cu-30%Al2O3. X-ray Diffraction (XRD) patterns of the obtained powders indicated the presence of the oxides CuO and CuAl2O4. The powder had the size of 75 ± 10 nm after deagglomerating by soft ball milling for 24h. After reducing in CO at 1000oC for 3h, the peaks of the oxides were no longer observed and were replaced by the peaks of Cu and -Al2O3. The morphology of the reduced powders observed by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS) analysis showed well distribution of the -Al2O3 particles within the Cu matrix with an average particle size of 40 nm.