Temperature relaxation in strongly-coupled binary ionic mixtures

New facilities such as the National Ignition Facility and the Linac Coherent Light Source have pushed the frontiers of high energy-density matter. These facilities offer unprecedented opportunities for exploring extreme states of matter, ranging from cryogenic solid-state systems to hot, dense plasmas, with applications to inertial-confinement fusion and astrophysics. However, significant gaps in our understanding of material properties in these rapidly evolving systems still persist. In particular, non-equilibrium transport properties of strongly-coupled Coulomb systems remain an open question. Here, we study ion-ion temperature relaxation in a binary mixture, exploiting a recently-developed dual-species ultracold neutral plasma. We compare measured relaxation rates with atomistic simulations and a range of popular theories. Our work validates the assumptions and capabilities of the simulations and invalidates theoretical models in this regime. This work illustrates an approach for precision determinations of detailed material properties in Coulomb mixtures across a wide range of conditions.

Risk decreasing of water waste through spontaneous fracturing in injectors by integrated well-testing and production logging

Background. When creating an effective reservoir pressure maintenance system, unstable spontaneous hydraulic fractures can be created in injection wells. This can both negatively and positively affect hydrocarbon production. First, fracture improves reservoir connectivity, which increases injection efficiency. On the other hand, unstable fractures can cause behind-the-casing flows and unproductive injection into off-target layers or fingering. Goal. The paper is devoted to the analysis of well testing (PTA) and production logging (PLT) improvement for the diagnosis of unstable fractures in injection wells. Materials and methods. The analysis is based on the results of modeling the pressure in the reservoir system, describing the penetration reservoirs by an unrestricted conductivity unstable fracture. It is taken into account that the fracture can cross both the perforated formation and the thickness not penetrated by the perforation, and can grow with increasing overbalance. The modeling results made it possible both to assess the potential informative capabilities of well testing and to substantiate recommendations for the practical use of the obtained results. Conclusions. The proposed approaches to the technology of well testing and production logging and the interpretation of their results make it possible to estimate the additional thicknesses of the reservoirs connected by the spontaneous hydraulic fracturing to injection, the proportion of nonproductive injection in the total volume of the well. The research technology used by the authors is based on continuous measurements of pressure and flow rate during cyclic change of pressure and assessment of the effective transmissibility of the formation system at different heights of unstable fractures. The role of the PLT is to determine the effective production thickness of the reservoirs. When assessing the injectivity profile when penetrating the injector with the spontaneous hydraulic fracturing, the key role belongs to non-stationary temperature logging. In this case, it is necessary to take into account the specific features of temperature relaxation in the wellbore after the injection cycle, related to hydraulic fracturing, primarily the increase in the relaxation rate with increasing fracture length.

Organosilica-Modified Multiblock Copolymers for Membrane Gas Separation

Organosubstituted silica derivatives were synthesized and investigated as modifiers of block copolymers based on macroinitiator and 2,4-toluene diisocyanate. A peculiarity of the modified block copolymers is the existence in their structure of coplanar rigid polyisocyanate blocks of acetal nature (O-polyisocyanates). Organosubstituted silica derivatives have a non-additive effect on high-temperature relaxation and α-transitions of modified polymers and exhibit the ability to influence the supramolecular structure of block copolymers. The use of the developed modifiers leads to a change in the gas transport properties of block copolymers. The increase of the permeability coefficients is due to the increase of the diffusion coefficients. At the same time, the gas solubility coefficients do not change. An increase in the ideal selectivity for a number of gas pairs is observed. An increase in the selectivity for the CO2/N2 gas pair (from 25 to 39) by 1.5 times demonstrates the promising use of this material for flue gases separation.

The Transition to Equilibrium in a System with Gravitationally Interacting Particles. I. Temperature Relaxation

The distribution function of systems in equilibrium must have the canonical form of the Gibbs distribution. To substantiate this behavior of systems, attempts have been made for more than 100 years to involve their mechanical behavior. In other words, it seems that a huge number of particles of the medium as a result of interaction with each other according to dynamic laws, is able to explain the statistical behavior of systems during their transition to equilibrium. Modeling of gravitationally interacting particles is carried out and it is shown that in this case, the distribution function does not evolve to the canonical form. Earlier, the same results were obtained for classical Coulomb plasma. On the other hand, such a statistical effect as relaxation is well described by the dynamic behavior of the system, and the simulation data are in agreement with the known theoretical results obtained in various statistical approaches.

Implementation of neutralizing fields for particle–particle simulations using like charges

The particle–particle (PP) model has a growing number of applications in plasma simulations, because of its high accuracy of solving Coulomb collisions. One of the main issues restricting the practical use of the PP model is its large computational cost, which is now becoming acceptable thanks to state-of-art parallel computing techniques. Another issue is the singularity that occurs when two particles are too close. The most effective approach of avoiding the singularity would be to simulate particles with only like charges plus a neutralizing field, such that the short-range collisions are equivalent to those of using unlike charges. In this paper, we introduce a way of adding the neutralizing field by using the analytical solution of the electric field in the domain filled with uniformly distributed charges, for applications with homogeneous and quasi-neutral plasmas under a reflective boundary condition. Two most common Cartesian domain geometries, cubic and spherical, are considered. The model is verified by comparing simulation results with an analytical solution of an electron–ion temperature relaxation problem, and a corresponding simulation using unlike charges. In addition, it is found that a PP simulation using like charges can achieve a significant speed-up of 100 compared with a corresponding simulation using unlike charges, due to the capability of using larger time steps while maintaining the same energy conservation.

Temperature relaxation in strongly-coupled binary ionic mixtures

New facilities such as the National Ignition Facility and the Linac Coherent Light Source have pushed the frontiers of high energy-density matter. These facilities offer unprecedented opportunities for exploring extreme states of matter, ranging from cryogenic solid-state systems to hot, dense plasmas, with applications to inertial-confinement fusion and astrophysics. However, significant gaps in our understanding of material properties in these rapidly evolving systems still persist. In particular, non-equilibrium transport properties of strongly-coupled Coulomb systems remain an open question. Here, we study ion-ion temperature relaxation in a binary mixture, exploiting a recently-developed dual-species ultracold neutral plasma. We compare measured relaxation rates with atomistic simulations and a range of popular theories. Our work validates the assumptions and capabilities of the simulations and invalidates theoretical models in this regime. This work illustrates an approach for precision determinations of detailed material properties in Coulomb mixtures across a wide range of conditions.