X-ray spectral diagnostics of the local environment of zinc in the arachidic acid layers

The article describes the behaviour of the Zn ions in aqueous subphase in presence of arachidic acid films at the air/liquid interface first studied by XANES spectroscopy in the fluorescent mode under total external reflection conditions. Fingerprint analysis of experimental spectra was carried out to determine the local structure of zinc ions in arachidic acid. It showed that zinc is surrounded by oxygen atoms, which may correspond to the interaction of zinc ions with polar groups of arachidic acid.

Demixing in the plasma created in capillary discharges with polymeric wall

The results of spectral diagnostics of erosion plasma obtained in a pulsed discharge in a capillary with an evaporating wall made of hydrogen-carbon and fluorine-carbon polymers - polymethylmethacrylate and polytetrafluoroethylene - are presented. It was found that in both cases the distribution of chemical elements along the discharge radius is highly inhomogeneous, and their concentration ratio differs significantly from that in the capillary wall. The mass of particles is a common sign characterizing the demixing degree of chemical elements and direction of diffusion flows in fluorine-carbon and hydrogen-carbon plasmas. In both cases, lightweight particles are concentrated in the central high-temperature region, while heavy ones run away onto the low-temperature peripheral region of the discharge. Estimates show that the thermal diffusion mechanism is quite capable for providing the observed demixing degree of chemical elements. Favorable conditions for thermal diffusion processes are formed in the layer adjacent to the capillary wall, where the intense dissociation of radicals occurs, and the temperature gradient reaches up to ΔT∼10 eV/mm.

SPECTRAL DIAGNOSTICS OF THE HYDROCARBON FUEL COMBUSTION PROCESS

It is proposed to use the methods of applied optical spectroscopy to solve the problem of control and diagnostics of gaseous hydrocarbon fuel combustion in this work. The results of an experimental study of spectroscopic informative parameters characterizing the propane combustion process are presented for three modes: combustion of pure propane without air supply, stoichiometric combustion and combustion with a change in the amount of supplied air relative to stoichiometric combustion. As a result of the experiment, it was found that the most intense bands in the emission spectrum of the flame arising from the combustion of propane correspond to the spectral bands of radicals of combustion products: OH, CH, and C2. While the intensities of various systems of bands in the flame spectrum depend significantly on the composition of the combustible mixture.

Broad UV Emission Lines in Type-1 Active Galactic Nuclei: A Note on Spectral Diagnostics and the Excitation Mechanism

This paper reviews several basic emission properties of the UV emission lines observed in the spectra of quasars and type-1 active galactic nuclei, mainly as a function of the ionization parameter, metallicity, and density of the emitting gas. The analysis exploits a general-purpose 4D array of the photoionization simulations computed using the code CLOUDY, covering ionization parameter in the range 10−4.5–10+1.0, hydrogen density nH∼107–1014 cm−3, metallicity Z between 0.01 and 100 Z⊙, and column density in the range 1021–1023 cm−2. The focus is on the most prominent UV emission lines observed in quasar spectra, namely Nvλ1240, Siivλ1397, Oiv]λ1402, Civλ1549, Heiiλ1640, Aliiiλ1860, Siiii]λ1892, and Ciii]λ1909, and on the physical conditions under which electron-ion impact excitation is predicted to be the dominant line producer. Photoionization simulations help constrain the physical interpretation and the domain of applicability of spectral diagnostics derived from measurements of emission line ratios, reputed to be important for estimating the ionization degree, density, and metallicity of the broad line emitting gas, as well as the relative intensity ratios of the doublet or multiplet components relevant for empirical spectral modeling.

A multi-diagnostic spectral analysis of penumbral microjets

Context. Penumbral microjets (PMJs) are short-lived, jet-like objects found in the penumbra of sunspots. They were first discovered in chromospheric lines and have later also been shown to exhibit signals in transition region (TR) lines. Their origin and manner of evolution is not yet settled. Aims. We perform a comprehensive analysis of PMJs through the use of spectral diagnostics that span from photospheric to TR temperatures to constrain PMJ properties. Methods We employed high-spatial-resolution Swedish 1-m Solar Telescope observations in the Ca II 8542 Å and H α lines, IRIS slit-jaw images, and IRIS spectral observations in the Mg II h & k lines, the Mg II 2798.75 Å & 2798.82 Å triplet blend, the C II 1334 Å & 1335 Å lines, and the Si IV 1394 Å & 1403 Å lines. We derived a wide range of spectral diagnostics from these and investigated other secondary phenomena associated with PMJs. Results. We find that PMJs exhibit varying degrees of signal in all of our studied spectral lines. We find low or negligible Doppler velocities and velocity gradients throughout our diagnostics and all layers of the solar atmosphere associated with these. Dark features in the inner wings of H α and Ca II 8542 Å imply that PMJs form along pre-existing fibril structures. We find evidence for upper photospheric heating in a subset of PMJs through emission in the wings of the Mg II triplet lines. There is little evidence for ubiquitous twisting motion in PMJs. There is no marked difference in onset-times for PMJ brightenings in different spectral lines. Conclusions. PMJs most likely exhibit only very modest mass-motions, contrary to earlier suggestions. We posit that PMJs form at upper photospheric or chromospheric heights at pre-existing fibril structures.