Investigation of H2S Solubility in Aqueous N- Methyldiethanolamine + Amine Functionalized UiO-66 as a nano solvent

In this paper, the experimental solubility of hydrogen sulfide in aqueous N- Methyldiethanolamine + Amine Functionalized UiO-66 (UiO-66-NH2) was studied. UiO-66-NH2 was produced using solvothermal process, and its physicochemical properties were investigated by different techniques including XRD, TGA, TEM, BET, and FTIR to realize its crystalline structure, morphology, thermal stability, and porous structure. The Zeta potential of the solution was turned out to be about 26.6 mV (millivolt), meaning that UiO-66-NH2 particles are moderately stable in aqueous 40 wt.% MDEA. The solubility of hydrogen sulfide has been carried out using the isochoric saturation / or static method in two concentration grades of 0.1 and 0.5 wt.% of UiO-66-NH2 in the aqueous solution of 40 wt.% MDEA known as nanofluid. Experimental measurements were carried out at temperatures of 303.15 through 333.15 K, and pressures up 1100 kPa. Results showed that the addition of UiO-66-NH2 nanoparticles to the MDEA solution altered the results less than 3% , while the mean value of uncertainty reported in this work is about 4% , meaning that the addition of nanoparticles do not have remarkable effect on H2S solubility. In contrast, it causes an increased capacity of CO2 absorption of that solution up to 10% .

Comparative seismic analysis study of G+ 20 story building with flat slab and conventional slab using ETABS

In the study, three dimensional analytical models of G+20 story buildings have been generated and analysed using CSI ETABS software version 2016. The earthquake zone III in India is considered for buildings during analysis. Here, the analysis and design is done of G+20 story building with flat slab(with drops) and conventional slab system. In earthquake zone the displacement and drift of the structures will be more so to have more stiffness to the structure shear wall is to be provided therefore a study is made by comparing between conventional slab & flat slab (with drops) building. Comparison of various parameters like story drift, story displacement, story stiffness and time period is done. The equivalent static method is used to design and analyze the structures, as categorized by Indian Standard Code for earthquake resistant structures. The study shows that story drift is 10% more in conventional slab as compared to flat slab; story displacements is observed linearly increasing with height of the building and is 11% more in conventional slab as compared to flat slab . Keywords: Equivalent Static Method, Flat Slab, ETABS 2016, story displacement, story stiffness, story drift, time period

Analytical Investigation of Composite Structure in Comparison of RCC Structure

High rise structures becoming very common everywhere due to scarcity of land and increasing population. Though we have RCC structure system as high-rise buildings, but in RCC buildings due to bulky size of the components of the structure self-weight will be more due to the heavy density of materials. By observing the difficulties and challenges in the field of high-rise structures engineers are using efficient structural system that is Steel Concrete Composite Structure. Composite structure consists composite deck slab, composite beam and composite column. Composite Structure complies of Concrete which is good in compression and structural steel which good in tension and composition of these material makes structure better in ductility which comparatively on higher side than RCC structure. Here G+7 high rise structure is considered for analysis by ETABS software. This paper involves Analysis of Commercial building by Equivalent static method on Composite structure and RCC structure with same plan of building and same design data. The structure is in earthquake zone III and wind speed 44m/s. Analytical comparisons of both Composite and RCC frame based on structural parameters are made with help of graphs and tables. By comparing the results, we found that Steel-Concrete Composite Structures are more desirable than RCC structures.

Comparative Analysis of Structure with and without Seismic Load

Engineers are mostly adopting complex non-linear methods to research multi-storey residential apartment structure to withstand earthquake forces. This paper uses much simpler Equivalent Static method to analyse G+5 storey structure to repel earthquake forces using Staad pro software. The seismic analysis is further compared with non-seismic analysis of an equivalent structure using dead load + super load combination. it had been observed that the seismic results obtained consisted of significantly increased maximum moments and shear forces than the non-seismic analysis From past earthquakes it is proved that many of structure ar completely or partly broken because of earthquake. So, it’s a necessity to figure out unstable responses of such structures. The main aim of the present work is to make a comparative study of seismic and non-Seismic structure. The analysis was performed as per the specification of IS codes IS 1893, IS 875, IS 456:2000.

Dynamic life-cycle carbon analysis for fast pyrolysis biofuel produced from pine residues: implications of carbon temporal effects

Background Woody biomass has been considered as a promising feedstock for biofuel production via thermochemical conversion technologies such as fast pyrolysis. Extensive Life Cycle Assessment studies have been completed to evaluate the carbon intensity of woody biomass-derived biofuels via fast pyrolysis. However, most studies assumed that woody biomass such as forest residues is a carbon–neutral feedstock like annual crops, despite a distinctive timeframe it takes to grow woody biomass. Besides, few studies have investigated the impacts of forest dynamics and the temporal effects of carbon on the overall carbon intensity of woody-derived biofuels. This study addressed such gaps by developing a life-cycle carbon analysis framework integrating dynamic modeling for forest and biorefinery systems with a time-based discounted Global Warming Potential (GWP) method developed in this work. The framework analyzed dynamic carbon and energy flows of a supply chain for biofuel production from pine residues via fast pyrolysis. Results The mean carbon intensity of biofuel given by Monte Carlo simulation across three pine growth cases ranges from 40.8–41.2 g CO2e MJ−1 (static method) to 51.0–65.2 g CO2e MJ−1 (using the time-based discounted GWP method) when combusting biochar for energy recovery. If biochar is utilized as soil amendment, the carbon intensity reduces to 19.0–19.7 g CO2e MJ−1 (static method) and 29.6–43.4 g CO2e MJ−1 in the time-based method. Forest growth and yields (controlled by forest management strategies) show more significant impacts on biofuel carbon intensity when the temporal effect of carbon is taken into consideration. Variation in forest operations and management (e.g., energy consumption of thinning and harvesting), on the other hand, has little impact on the biofuel carbon intensity. Conclusions The carbon temporal effect, particularly the time lag of carbon sequestration during pine growth, has direct impacts on the carbon intensity of biofuels produced from pine residues from a stand-level pine growth and management point of view. The carbon implications are also significantly impacted by the assumptions of biochar end-of-life cases and forest management strategies.

The Advanced Multilevel Predictor-Corrector Quasi-Static Method for Pin-Resolved Neutron Kinetics Simulation

The Advanced Multilevel Predictor-Corrector Quasi-static Method (AML-PCQM) is proposed in this work. The four computational levels, including transport, Multi-Group (MG) Coarse Mesh Finite Difference (CMFD), One-Group (1G) CMFD, and Exact Point-Kinetics Equation (EPKE), are coupled with a new dynamic iteration strategy. In each coupling algorithm, the original Transient Fixed Source Problem (TFSP) is solved in the predictor process using coarse time step, and then the flux distribution is factorized to the functions of amplitude and shape in the next corrector process. Finally, multiple fine time steps are used to adjust the predicted solution. Two heterogeneous single assembly problems with the prompt control rod withdrawal event are used to verify the AML-PCQM scheme’s accuracy and efficiency. The numerical results obtained by different cases are compared and analyzed. The final results indicate that the AML-PCQM performs the remarkable advantages of efficiency and accuracy with the reference cases.

Tensoresistive properties of single crystals TlIn1−xGaxSe2

In this work, single crystals of TlIn[Formula: see text]Ga[Formula: see text]Se2 solid solutions were grown by the methods of zone recrystallization, technologies for the manufacture of strain gauges based on them were developed and the tensoresistive properties of these phases were studied, the coefficient of strain sensitivity was determined by the static method depending on the temperature, the magnitude of mechanical deformation and optical illumination. Revealing that the single crystals have a high strain sensitivity coefficient, by the variation of the composition, quantity of mechanical deformation and the optical illumination, it is possible to control the phase coefficients investigated tensosensitivity.

Structural renovation of residential building in Zagreb after the 22 March 2020 earthquake

The phases that must be completed so that a building damaged in earthquake that struck Zagreb on 22 March 2020 can be renovated and strengthened to the required level of seismic resistance are presented in the paper. All phases are therefore presented, starting from the rapid and then detailed inspection, and continuing with preparation of the structural condition assessment report, preparation of renovation design and, finally, ending with realisation of work with expert supervision. A special attention is paid to structural analysis that is conducted using a nonlinear static method based on displacements, the so called pushover analysis, which is considered to be one of the most appropriate methods for seismic analysis of existing masonry structures. All procedures conducted in the scope of this renovation were realised in accordance with legislation that entered into force after the earthquake.

Pool Boiling Heat Transfer Coefficients in Mixtures of Water and Glycerin

Heat transfer coefficients were investigated for saturated nucleate pool boiling of binary mixtures of water and glycerin at atmospheric pressure in a wide range of concentrations and heat fluxes. Mixtures with water mass fractions from 100% to 40% were boiled on a horizontal flat copper surface at heat fluxes from about 25 up to 270kWm−2. Experiments were carried out by static and dynamic method of measurement. Results of the static method show that the impact of mixture effects on heat transfer coefficient cannot be neglected and ideal heat transfer coefficient has to be corrected for all investigated concentrations and heat fluxes. Experimental data are correlated with the empirical correlation α=0.59q0.714+0.130ωw with mean relative error of 6%. Taking mixture effects into account, data are also successfully correlated with the combination of Stephan and Abdelsalam (1980) and Schlünder (1982) correlations with mean relative error of about 15%. Recommended coefficients of Schlünder correlation C0=1 and βL=2×10−4ms−1 were found to be acceptable for all investigated mixtures. The dynamic method was developed for fast measurement of heat transfer coefficients at continuous change of composition of boiling mixture. The dynamic method was tested for water–glycerin mixtures with water mass fractions from 70% down to 35%. Results of the dynamic method were found to be comparable with the static method. For water–glycerin mixtures with higher water mass fractions, precise temperature measurements are needed.