X-ray shields used for medical purposes are manufactured using lead, which is inexpensive and easy to manufacture. However, as lead can be a major factor contributing toward environmental contamination, such as lead poisoning, a radiation-shielding plate was manufactured in this study using a tungsten plate, an eco-friendly material, through a rolling process at different temperatures. In addition, the shielding plate produced via the hot-rolling method exhibited better shielding performance than that of the plate produced using the cold-rolling method, and the multilayer structure was well formed, as indicated in the cross-sectional image analysis. Upon applying a peak voltage of 100 kVp to the X-ray tube, the shielding performance observed was 80% and 96% when the plate thickness was 0.1 mm and 0.3 mm, respectively. Therefore, it is expected that, in the future, the pure tungsten-based shield presented in this study will replace lead plates, owing to its superior standardization and reproducibility of the shielding performance.