Optical Detection of VOC Vapors Using Nb2O5 Bragg Stack in Transmission Mode

In this study, an emphasis is put on vapor-sensitive Bragg stacks as an important class of optical sensors. All-niobia Bragg stacks were deposited by spin-coating of sol-gel Nb2O5 thin films alternated with mesoporous layers after proper design through optimization of operating wavelength and number of layers in the stack. Mesoporous Nb2O5 films with different morphology and identical structure were obtained using organic templates (Pluronics PE6200 and PE6800) and subsequent annealing. Transmittance measurements were performed as a detection method that offers technological simplicity and accuracy. It was demonstrated that stacks including PE6200 templated films exhibit higher sensitivity than stacks templated with PE6800. It was assumed and verified by computer-aided modelling of experimental data that mesoporous films prepared with addition of PE6200, although less porous, were more stable compared to those templated with PE6800, and did not collapse during the thermal treatment of the stacks. Furthermore, the reproducibility of optical response was studied by sorption and desorption cycles of acetone vapors. The suitability of all-niobia Bragg stacks for optical sensing of VOCs was discussed.

Offretite Zeolite Single Crystals Synthesized by Amphiphile-Templating Approach

Offretite zeolite synthesis in the presence of cetyltrimethylammonium bromide (CTABr) is reported. The offretite crystals were synthesized with a high crystallinity and hexagonal prismatic shape after only 72 h of hydrothermal treatment at 180 °C. The CTABr has dual-functions during the crystallization of offretite, viz. as structure-directing agent and as mesoporogen. The resulting offretite crystals, with a Si/Al ratio of 4.1, possess more acid sites than the conventional offretite due to their high crystallinity and hierarchical structure. The synthesized offretite is also more reactive than its conventional counterpart in the acylation of 2-methylfuran for biofuel production under non-microwave instant heating condition, giving 83.5% conversion with 100% selectivity to the desired product 2-acetyl-5-methylfuran. Hence, this amphiphile synthesis approach offers another cost-effective and alternative route for crystallizing zeolite materials that require expensive organic templates.

Controlling the Secondary Assembly of Porous Anionic Uranyl-organic Polyhedra through Organic Cationic Templates

Herein, we report a new uranyl-organic polyhedron U4L4 (L=BTPCA) assembled from uranyl and a semirigid tritopic ligand. By adjusting the carbon chain length of the organic templates, two complexes can...