mica composite
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Coatings ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 98
Author(s):  
Yaling Da ◽  
Jianxing Liu ◽  
Zixian Gao ◽  
Xiangxin Xue

In this work, a series of epoxy acrylate (EA)/mica composite coatings were synthesized through introducing mica powders of different particle size into epoxy acrylate coatings and using an ultraviolet (UV) curing technique to investigate the influence of mica particle size on the coatings. Mica powders of different particle sizes were obtained by ball-milling for 4, 8, 12, 16, and 20 h with a planetary high-energy ball mill. The particle size and morphologies of ball-milled mica powders were characterized by laser particle size analyzer and scanning electron microscopy (SEM). The results indicated that planetary ball-milling reduced the particle size of mica powders effectively. Mica powders that were un-ball-milled and ball-milled were added into the epoxy acrylate matrix by a blending method to synthesize the organic-inorganic UV curable coatings. The optical photographs of the coatings showed greater stability of liquid mixtures with smaller particle size fillers. The chemical structures of EA/mica composite coatings were investigated by Fourier transform infrared spectroscopy (FTIR), and the conversion rate of C=C bonds was calculated. The results indicated that the C=C conversion of coatings with mica powders of smaller particle sizes was higher. Tests of mechanical properties and tests using electrochemical impedance spectroscopy (EIS) showed that pencil hardness, impact resistance, and coating resistance were improved due to the reduction of mica powders particle size.


Materials ◽  
2021 ◽  
Vol 14 (10) ◽  
pp. 2496
Author(s):  
Iftikhar Ahmed Channa ◽  
Ali Dad Chandio ◽  
Muhammad Rizwan ◽  
Aqeel Ahmed Shah ◽  
Jahanzeb Bhatti ◽  
...  

Organic photovoltaics (OPVs) die due to their interactions with environmental gases, i.e., moisture and oxygen, the latter being the most dangerous, especially under illumination, due to the fact that most of the active layers used in OPVs are extremely sensitive to oxygen. In this work we demonstrate solution-based effective barrier coatings based on composite of poly(vinyl butyral) (PVB) and mica flakes for the protection of poly (3-hexylthiophene) (P3HT)-based organic solar cells (OSCs) against photobleaching under illumination conditions. In the first step we developed a protective layer with cost effective and environmentally friendly methods and optimized its properties in terms of transparency, barrier improvement factor, and bendability. The developed protective layer maintained a high transparency in the visible region and improved oxygen and moisture barrier quality by the factor of ~7. The resultant protective layers showed ultra-flexibility, as no significant degradation in protective characteristics were observed after 10 K bending cycles. In the second step, a PVB/mica composite layer was applied on top of the P3HT film and subjected to photo-degradation. The P3HT films coated with PVB/mica composite showed improved stability under constant light irradiation and exhibited a loss of <20% of the initial optical density over the period of 150 h. Finally, optimized barrier layers were used as encapsulation for organic solar cell (OSC) devices. The lifetime results confirmed that the stability of the OSCs was extended from few hours to over 240 h in a sun test (65 °C, ambient RH%) which corresponds to an enhanced lifetime by a factor of 9 compared to devices encapsulated with pristine PVB.


High Voltage ◽  
2020 ◽  
Vol 5 (2) ◽  
pp. 184-190 ◽  
Author(s):  
Nikhil Mondal ◽  
Nasirul Haque ◽  
Sovan Dalai ◽  
Sivaji Chakravorti ◽  
Biswendu Chatterjee

2019 ◽  
Vol 125 (9) ◽  
Author(s):  
Feiming Wei ◽  
Yonggang Xu ◽  
Wei Gao ◽  
Dianliang Zheng ◽  
Ting Liu

2018 ◽  
Vol 25 (6) ◽  
pp. 2212-2219 ◽  
Author(s):  
Tomokazu Tanase ◽  
Tetsuji Kato ◽  
Shingo Tanaka ◽  
Akihiro Sano ◽  
Hiroaki Kojima ◽  
...  

JOM ◽  
2017 ◽  
Vol 69 (6) ◽  
pp. 1084-1092 ◽  
Author(s):  
Qiangbin Yang ◽  
Yi He ◽  
Yi Fan ◽  
Han Li ◽  
Wei Xu ◽  
...  

2016 ◽  
Vol 23 (5) ◽  
pp. 573-577 ◽  
Author(s):  
Qingbo Tian ◽  
Deyu Kong ◽  
Tongguang Zhai

AbstractA machinable α-Al2O3/mica composite was prepared by hot-press sintering. In this experiment, a mica-contained glass ceramic in the MgO-Al2O3-SiO2-F glassy system was employed and the base glass powders were obtained by traditional melting-quenched method. Then, α-Al2O3 milling swarf was introduced by medium α-alumina milling ball to the glass powders. The test results indicate that the composites consist of mica crystal and mullite crystal, which are precipitated in the base glass. The α-Al2O3 shows an irregular polygon, which is inlayed in the base material. With the decrease of size of the base glass powders, the boundaries of composites among the sintered powders gradually vanish. The mica crystals in the composite also show an interlocking characteristic, which is a prerequisite of mica-contained glass ceramics with good machinability. Under different pressures, the tendency of preferred orientation is decreased with the reduction in grain size of glass powders, and the microstructure is proved to be consistent, significantly decreasing the composite’s hardness. Therefore, the machinability of the composite is improved.


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