Transformation of Sulfur during Co-Hydrothermal Carbonization of Coal Waste and Food Waste

Co-hydrothermal carbonization (Co-HTC) is an emerging technology for processing multiple waste streams together to improve their fuel properties in the solid product, known as hydrochar, compared to the hydrothermal carbonization (HTC) of those individual streams. Sulfur is considered one of the most toxic contaminants in solid fuel and the combustion of this sulfur results in the emission of SOx. It was reported in the literature that, besides the fuel properties, Co-HTC reduced the total sulfur content in the hydrochar phase significantly. However, the transformation of different forms of sulfur has not yet been studied. Therefore, this study investigated the transformation of different forms of sulfur under the Co-HTC treatment. In the study, the Co-HTC of food waste (FW) and two types of coal wastes (middle bottom (CW1) and 4 top (CW2)) were conducted at 180 °C, 230 °C and 280 °C for 30 min. Different forms of sulfur were measured by using elemental analysis (total sulfur), and a wet chemical method (sulfate sulfur and pyritic sulfur). The organic sulfur was measured by the difference method. The results showed that a maximum of 49% and 65% decrease in total sulfur was achieved for CW1FW and CW2FW, respectively, at 230 °C. Similar to the total sulfur, the organic sulfur was also decreased about 85% and 75% for CW1FW and CW2FW, respectively. Based on these results, a sulfur transformation mechanism under Co-HTC treatment was proposed.

Seasonal Changes in Microbial Dissolved Organic Sulfur Transformations in Coastal Waters

The marine trace gas dimethylsulfide (DMS) is the single most important biogenic source of atmospheric sulfur, accounting for up to 80% of global biogenic sulfur emissions. Approximately 300 million tons of DMS are produced annually, but the majority is degraded by microbes in seawater. The DMS precursor dimethylsulfoniopropionate (DMSP) and oxidation product dimethylsulphoxide (DMSO) are also important organic sulfur reservoirs. However, the marine sinks of dissolved DMSO remain unknown. We used a novel combination of stable and radiotracers to determine seasonal changes in multiple dissolved organic sulfur transformation rates to ascertain whether microbial uptake of dissolved DMSO was a significant loss pathway. Surface concentrations of DMS ranged from 0.5 to 17.0 nM with biological consumption rates between 2.4 and 40.8 nM·d−1. DMS produced from the reduction of DMSO was not a significant process. Surface concentrations of total DMSO ranged from 2.3 to 102 nM with biological consumption of dissolved DMSO between 2.9 and 111 nM·d−1. Comparisons between 14C2-DMSO assimilation and dissimilation rates suggest that the majority of dissolved DMSO was respired (>94%). Radiotracer microbial consumption rates suggest that dissimilation of dissolved DMSO to CO2 can be a significant loss pathway in coastal waters, illustrating the significance of bacteria in controlling organic sulfur seawater concentrations.