Temperature-Driven Hydrocarbon Generation-Expulsion and Structural Transformation of Organic-Rich Shale Assessed by in situ Heating SEM

Mud shale can serve as source or cap rock but also as a reservoir rock, and so the development of pores or cracks in shale has become of great interest in recent years. However, prior work using non-identical samples, varying fields of view and non-continuous heating processes has produced varying data. The unique hydrocarbon generation and expulsion characteristics of shale as a source rock and the relationship with the evolution of pores or cracks in the reservoir are thus not well understood. The present work attempted to monitor detailed structural changes during the continuous heating of shale and to establish possible relationships with hydrocarbon generation and expulsion by heating immature shale samples while performing in situ scanning electron microscopy (SEM) imaging and monitoring the chamber vacuum. Samples were heated at 20°C/min from ambient to 700°C with 30 min holds at 100°C intervals during which SEM images were acquired. The SEM chamber vacuum was found to change during sample heating as a consequence of hydrocarbon generation and expulsion. Two episodic hydrocarbon expulsion stages were observed, at 300 and 500°C. As the temperature was increased from ambient to 700°C, samples exhibited consecutive shrinkage, expansion and shrinkage, and the amount of structural change in the vertical bedding direction was greater than that in the bedding direction. At the same time, the opening, closing and subsequent reopening of microcracks was observed. Hydrocarbon generation and expulsion led to the expansion of existing fractures and the opening of new cracks to produce an effective fracture network allowing fluid migration. The combination of high-resolution SEM and a high-temperature heating stage allowed correlation between the evolution of pores or cracks and hydrocarbon generation and expulsion to be examined.

Geochemical Characteristics and Origin of Formation Water From the Upper Triassic Xujiahe Tight Sandstone in the Xiaoquan-Fenggu Structural Belt, Western Sichuan Depression, China

Formation water represents an important driving force and carrier for the migration and accumulation of oil and gas; thus, research on its origin is a hot spot in petroleum geology. The Upper Triassic Xujiahe Formation in the Xiaoquan-Fenggu Structural Belt in the western Sichuan Depression, China, has developed thick tight sandstone gas reservoirs. However, previous studies have provided different conclusions on the origin of the formation water in the Xujiahe tight sandstone reservoir. In this paper, the origin of the formation water in the Xujiahe Formation was determined based on the latest major and minor elemental concentration data, hydrogen and oxygen isotopes data of formation water, and carbon and oxygen isotope data of carbonate cements. The results show that the salinity of the formation water of the Xujiahe Formation in the study area is generally greater than 50 g/L. The water type is mainly the CaCl2 type, although a small proportion of NaHCO3 type water with high salinity is observed, which is related to hydrocarbon expulsion by overpressure. Moreover, the formation water in the sandstone of the Xujiahe Formation is obviously rich in Br, which is related to membrane infiltration, overpressured hydrocarbon expulsion of shale and diagenesis of organic matter. The composition of Cl− and Na+ ions in the formation water in the Xujiahe tight sandstone reservoir is consistent with the seawater evaporation curve, which deviates significantly from the freshwater evaporation curve. The hydrogen and oxygen isotopes of condensate water in the Xujiahe Formation tight sandstone are similar to those of atmospheric precipitation water, while the hydrogen and oxygen isotopes of the formation water in the Xujiahe Formation show that it is of seawater origin. Therefore, to use hydrogen and oxygen isotopes to determine the origin of formation water, condensate water must be accurately differentiated from formation water. Otherwise, if the condensate water is misjudged as formation water, then incorrect conclusions will be drawn, e.g., that the formation water of the Xujiahe Formation originated from fresh water. Affected by organic carbon, the carbon isotope Z value of the carbonate cements in the Xujiahe Formation is low (mainly distributed between 110 and 130). A Z value of less than 120 does not indicate that the ancient water bodies formed by cements were fresh water or mixed water bodies. However, Z values greater than 120 correspond to a formation temperature lower than 80 C, which indicates that carbonate cement was not affected by organic carbon; thus, the Z value can reflect the origin of ancient water bodies. The results of this study indicate that the formation water of the Xujiahe tight sandstone in the study area is of seawater origin. The determination of the origin of the formation water and seawater of the Xujiahe Formation provides strong evidence for the determination of the marine sedimentary environment of the Xujiahe Formation in the study area, and can provide scientific guidance for the search for high-quality reservoirs.

Comprehensive basin-wide 3D petroleum systems modelling providing new insights into proven petroleum systems and remaining prospectivity in the Exmouth Sub-basin, Australia

The Exmouth Sub-basin is part of the Northern Carnarvon Basin, offshore north-west Australia, and has undergone a complex tectonic history. Hydrocarbon exploration resulted in the discovery of a variety of oil and gas accumulations; however, their distribution and charge history from different petroleum systems is still poorly understood due to limited knowledge of the deeper basin architecture. The basin-wide, long-offset, broadband 2017 Exmouth 3D multiclient seismic dataset allowed a seamless interpretation into this deeper section. This work revealed new insights on the tectono-stratigraphic evolution of the Exmouth Sub-basin. Mesozoic extension, that was restricted to the latest Triassic, was followed by a sag phase with homogeneous, shale-dominated deposition, resulting in source rock potential for the entire Jurassic section. These findings, together with potential field modelling, were integrated into this first basin-wide 3D petroleum system model to better constrain the thermal history and petroleum systems. The model improved our understanding of the complex charge history of hydrocarbon fields. It predicts that hydrocarbon expulsion from Late Jurassic source rocks continued into the Late Cretaceous, a period when the regional Early Cretaceous Muderong Formation was an efficient seal rock. This implies that, in addition to long-distance, sub-Muderong migration, vertical, short-distance migration may have contributed significant petroleum charge to the discovered accumulations in the southern Exmouth Sub-basin. The model also predicts additional prospective areas: fault-seal structures within Early Cretaceous intervals north of the Novara Arch, intra-formational Late Jurassic sandstones north of the current fields (with low biodegradation risk) and Triassic reservoirs along the basin margins and north of the Jurassic depocentre.