Obtaining and plasma-electrolyte modification of fibers of ultralight magnesium alloy

The results of researches for the transformation to fiber state the Mg-8Li-1Al-0.6Ce-0.3Y ultralight magnesium alloy by the Pendant Drop Melt Extraction (PDME), and subsequent modifying obtained fibers by Plasma-Electrolytic Treatment (PET) are presented. The results demonstrate possibility of successful application of the above-mentioned methods in relation to chemically active materials. Purposeful modifying of ultralight magnesium alloys by PDME and PET methods is capable to significantly expand areas of using to these materials.

Features of anodic plasma electrolytic treatment of an ultra-light alloy of the Mg-Li system in an aqueous electrolyte

The possibility of plasma electrolytic treatment of an alloy of the Mg-Li system in an aqueous solution of ammonium chloride, ammonium nitrate and boric acid has been studied. The specific features of the process in the voltage range from 10 to 600 V are determined. The current-voltage and voltage-temperature characteristics during alloy processing are shown, as well as the effect of the processing time on the temperature of the samples. Plasma electrolytic boronitriding of the alloy can be carried out to study the efficiency of the technology at avoltage of 240 V, which corresponds to a sample temperature of 300 ± 10 °C.

Evaluation of tribotechnical properties of modified surfaces after plasma electrolytic treatment

The article considers the study of the effect of plasma electrolytic processing on the tribotechnical characteristics of medium-carbon steel. Friction tests were carried out in dry friction mode. Electron microscope and profilometer were used to study the friction tracks. For a comprehensive assessment of the quality of the modified surface layer, the Kragelsky-Kombalov complex parameter was calculated. It was found that plasma electrolytic treatment leads to a decrease in the coefficient of friction and weight wear in comparison with hardened and untreated steel. It has been determined that the mechanism of wear of samples after plasma electrolytic treatment is fatigue wear at boundary friction and plastic contact.

Electrolytic Oxidation as a Sustainable Method to Transform Urine into Nutrients

In this work, the transformation of urine into nutrients using electrolytic oxidation in a single-compartment electrochemical cell in galvanostatic mode was investigated. The electrolytic oxidation was performed using thin film anode materials: boron-doped diamond (BDD) and dimensionally stable anodes (DSA). The transformation of urine into nutrients was confirmed by the release of nitrate (NO3−) and ammonium (NH4+) ions during electrolytic treatment of synthetic urine aqueous solutions. The removal of chemical oxygen demand (COD) and total organic carbon (TOC) during electrolytic treatment confirmed the conversion of organic pollutants into biocompatible substances. Higher amounts of NO3− and NH4+ were released by electrolytic oxidation using BDD compared to DSA anodes. The removal of COD and TOC was faster using BDD anodes at different current densities. Active chlorine and chloramines were formed during electrolytic treatment, which is advantageous to deactivate any pathogenic microorganisms. Larger quantities of active chlorine and chloramines were measured with DSA anodes. The control of chlorine by-products to concentrations lower than the regulations require can be possible by lowering the current density to values smaller than 20 mA/cm2. Electrolytic oxidation using BDD or DSA thin film anodes seems to be a sustainable method capable of transforming urine into nutrients, removing organic pollution, and deactivating pathogens.