International Journal of Electrochemistry
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275
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Published By Hindawi Publishing Corporation (Sage-Hindawi Access To Research)

2090-3537, 2090-3529

2021 ◽  
Vol 2021 ◽  
pp. 1-13
Author(s):  
F. M. Alshareef ◽  
M. I. Orif ◽  
E. A. Al-Harbi ◽  
M. S. El-Shahawi

The current strategy reports a highly sensitive and selective square wave-cathodic stripping voltammetric protocol for malathion determination. The established method was based on the controlled adsorptive accumulation of malathion in the presence of Cu2+ ions in an aqueous solution of pH 2 onto the hanging mercury dropping electrode (HMDE) and measuring the resulting cathodic peak current of the adsorbed species at −0.42 V versus Ag/AgCl electrode. The low limits of detection (LOD) and quantification (LOQ) of malathion of the assay were estimated to be 3.1 × 10−10 and 1.03 × 10−9 M with a linear dynamic range of 1.03×10−9 – 2.0 × 10−7 M, respectively. The method was satisfactorily applied and validated for malathion determination in environmental samples. The experimental Student texp and Fexp values did not exceed the tabulated ttab (2.78) and Ftab (6.39) at 95% (P = 0.05) confidence (n = 5), confirming the precision and independence on the matrix. The developed sensing platform for the detection of malathion shows superior performance to conventional electrochemical methods. The proposed sensor offered simple, economical, reproducible, and applicable approach for the determination of malathion in environmental samples.


2021 ◽  
Vol 2021 ◽  
pp. 1-9
Author(s):  
Neetha John ◽  
K. E. Abraham

The present study reports the design of the Mn3O4-Cn electrode and its use for simultaneous detection of selenium and nickel in water. The designed electrode can be used as a convenient electrochemical device for on-site testing of Se (IV) and Ni (II) levels in affected regions. The best responses are obtained with 0.1 M phosphate buffer saline (PBS) and 5 mM Fe (CN)6 as supporting electrolyte. The scan rate and the number of cyclic repetitions have a great effect on peak shape and intensity. It is seen from our study that peak intensity is directly proportional to Se (IV) and Ni (II) concentrations in the range of 5 to 250 µg/L (correlation coefficients 0.952 and 0.984) when the optimized parameters are used. The detection limit of 0.533 µg/L Se (IV) and 0.718 µg/L for Ni (VI) with a response time of 18 s for 5–250 µg/L concentration is obtained, respectively. Enhanced analytical results for different water samples establish that the proposed method is appropriate for Se (IV) and Ni (II) detection. FESEM images confirm the Mn3O4-Cn nanocomposite formation on the electrode.


2020 ◽  
Vol 2020 ◽  
pp. 1-11
Author(s):  
Nnaemeka Nnaji ◽  
Njemuwa Nwaji ◽  
Tebello Nyokong

Tetrakis[(benzo[d]thiazol-2-yl-thio) phthalocyaninato] gallium(III)chloride (1) and tetrakis[(benzo[d]thiazol-2ylphenoxy) phthalocyaninato] gallium(III)chloride (2) were successfully electrodeposited onto aluminium for corrosion retardation in 1.0 M hydrochloric acid solution. The aim of this study was to compare the corrosion resistance of electrodeposited metallated phthalocyanines. Scanning electron microscopy, X-ray diffraction, electrochemical impedance spectroscopy (EIS), and polarization confirmed the aluminium corrosion inhibition potentials of complexes 1 and 2. EIS and polarization techniques showed that complex 2 performed better than complex 1, with values from EIS measurements of 82% for 1 and 86% for 2 in 1.0 M hydrochloric acid solution. The importance of electrodeposition in industries and a dearth of research on the use of electrodeposited metallated phthalocyanines necessitated this study, and results show that coatings formed by electrodeposition of 1 and 2 onto aluminium reduced its susceptibility to corrosion attack.


2020 ◽  
Vol 2020 ◽  
pp. 1-10 ◽  
Author(s):  
Y. Koumya ◽  
R. Idouhli ◽  
A. Oukhrib ◽  
M. Khadiri ◽  
A. Abouelfida ◽  
...  

The corrosion of stainless steel is one of the major industries’ issues that gained wide interest among researchers. It became necessary to develop and apply eco-friendly approaches to corrosion control. This work explores the inhibitory effect of a newly synthesized amino cadalene (ACM) on the corrosion of stainless steel type 321 in sulfuric acid 1M. Particularly, the experimental study consisting of electrochemical and surface analyses was conducted in conjunction with a theoretical approach. The electrochemical results showed that ACM acted as a mixed-type corrosion inhibitor and the inhibition efficiency attained 91% at 10−3M. EIS measurements revealed that both metal charge transfer and diffusion processes are involved in the interfacial metal/solution reactions. The interfacial mechanism is thoroughly investigated; the physisorption of the protonated molecules was preceded by the formation of a negative layer due to adsorption of the solution anionic species. The experimental insights are corroborated with the quantum chemical calculations.


2020 ◽  
Vol 2020 ◽  
pp. 1-6
Author(s):  
K. Kammer Hansen

Four LnMnO3+δ (Ln = La, Pr, Sm, and Gd) perovskites were synthesized and characterized by powder XRD. It was shown that the perovskite lattice became more and more distorted when lowering the size of the A-site cation. The manganite-based perovskites were evaluated for the ability to electrochemically reduce oxygen and nitric oxide in the temperature range of 200 to 400°C. At the lowest temperature, the electrodes were better at reducing nitric oxide than oxygen. At higher temperatures, the activity for the reduction of oxygen and nitric oxide became similar. The activation energies for the reduction of oxygen and nitric oxide were markedly different for LaMnO3+δ and PrMnO3+δ whereas it was similar for SmMnO3+δ and GdMnO3+δ.


2019 ◽  
Vol 2019 ◽  
pp. 1-5
Author(s):  
Ravindar Dharavath ◽  
Ashwin Murali ◽  
Abdul Wasi Tarapathi ◽  
Balasubramanian Trichy Srinivasan ◽  
Rambabu Kammili

The conductivity of an electrolyte plays a significant role in deciding the performance of any battery over a wide temperature range from −40°C to 60°C. In this work, the conductivity of lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) at a varied salt concentration range from 0.2 M to 2.0 M in a multisolvent organic electrolyte system over a wide temperature range from −40°C to 60°C is reported. The mixed solvents used were 1,3-dioxolane (DOL), 1,2-dimethoxyethane (DME), and tetraethylene glycol dimethyl ether (TEGDME) with an equal ratio of DOL : DME : TEGDME (1 : 1 : 1 by volume). The experimental analysis performed over a wide temperature range revealed the maximum conductivity at salt concentrations ranging from 1.0 M to 1.4 M for equal molar solvents. The optimum salt concentration and maximum conductivity in a different solvent composition ratio (i.e., 3 : 2 : 1) for all the temperatures is reported herein. The temperature-dependence conductivity of the salt concentration did not fit the Arrhenius plot, but it resembled the Vogel–Tamman–Fulcher plot behavior. The present conductivity study was carried out to evaluate the overall operable temperature limit of the electrolyte used in the lithium-sulfur battery.


2019 ◽  
Vol 2019 ◽  
pp. 1-11 ◽  
Author(s):  
María J. Lavorante ◽  
Carla Y. Reynoso ◽  
Juan I. Franco

The challenges to be overtaken with alkaline water electrolysis are the reduction of energy consumption, the maintenance, and the cost as well as the increase of durability, reliability, and safety. Having these challenges in mind, this work focused on the reduction of the electrical resistance of the electrolyte which directly affects energy consumption. According to the definition of electrical resistance of an object, the reduction of the space between electrodes could lower the electrical resistance but, in this process, the formation of bubbles could modify this affirmation. In this work, the performance analyses of nine different spaces between stainless steel 316L electrodes were carried out, although the spaces proposed are not the same as those from the positive electrode (anode) to the separator and from the separator to the negative electrode (cathode). The reason why this is studied is that stoichiometry of the reaction states that two moles of hydrogen and one mole of oxygen can be obtained per every two moles of water. The proposed spaces were 10.65, 9.20, 8.25, 7.25, 6.30, 6.05, 4.35, 4.15, and 3.40 millimetres. From the nine different analysed distances between electrodes, it can be said that the best performance was reached by one of the smallest distances proposed, 4.15 mm. When the same distance between electrodes was compared (the same and different distance between electrodes and separator), the one that had almost twice the distance (negative compartment) presented an increase in current density of approximately 33% with respect to that where both distances (from electrodes to separator) are the same. That indicates that the stichometry of the electrolysis reaction influenced the performance.


2019 ◽  
Vol 2019 ◽  
pp. 1-7 ◽  
Author(s):  
Maheeka Yapa Abeywardana ◽  
Nina Laszczynski ◽  
Matthias Kuenzel ◽  
Dominic Bresser ◽  
Stefano Passerini ◽  
...  

LiNi0.5Mn1.5O4 (LNMO), which has an operating voltage of 4.8 vs Li/Li+ and a theoretical capacity of 147 mAh g−1, is an interesting cathode material for advanced lithium ion batteries. However, electrolyte decomposition at the electrode can gradually decrease the capacity of the battery. In this study, the surface of the LNMO cathode has been modified with phosphoric acid (PA) to improve the capacity of the LNMO/graphite full cell. Modification of LNMO cathodes by PA is confirmed by surface analysis. Additionally, the presence of lithium bis-(oxalato) borate (LiBOB) as an electrolyte additive further enhances the performance of PA modified LNMO/graphite cells. The improved performance of PA modified cathodes and electrolytes containing LiBOB can be attributed to the suppressed Mn and Ni deposition on the anode. Elemental analysis suggests that the Mn and Ni dissolution is significantly reduced compared to unmodified LNMO/graphite cells with standard electrolyte.


2019 ◽  
Vol 2019 ◽  
pp. 1-13 ◽  
Author(s):  
Ragi Kooliyat ◽  
Joby Thomas Kakkassery ◽  
Vinod P. Raphael ◽  
Sini Varghese Cheruvathur ◽  
Binsi M. Paulson

Schiff base 2,2’-(5,5-dimethylcyclohexane-1,3-diylidene)bis(azan-1-yl-1-ylidene) diphenol (DmChDp) was synthesized and characterized using spectroscopic methods (IR, UV, NMR, and Mass) and cyclic voltammetric (CV) studies. The corrosion inhibition potency of (DmChDp) on mild steel (MS) in 1M HCl and 0.5M H2SO4 was investigated. The corrosion monitoring techniques employed for this purpose are gravimetric and electrochemical methods (EIS and potentiodynamic polarization studies). The study reveals that the Schiff base, DmChDp, acts as excellent corrosion inhibitor on mild steel in 1M HCl. DmChDp obeys Langmuir adsorption isotherm both in 1M HCl and 0.5M H2SO4 on MS. Polarization studies show that DmChDp behaves as a mixed type inhibitor in both media. Scanning electron microscopic analysis established the protective nature of DmChDp on mild steel surface. The impact of temperature on the corrosion of MS was also evaluated using gravimetric method.


2019 ◽  
Vol 2019 ◽  
pp. 1-6 ◽  
Author(s):  
Vladimir P. Vasiliev ◽  
Roman A. Manzhos ◽  
Alexander G. Krivenko

Current-voltage characteristics of few-layer graphene structures (FLGS) obtained by plasma-assisted electrochemical exfoliation of graphite in Na2SO4 solution were measured. FLGS are shown to possess electronic conductivity, which indicates the predominant functionalization of the edges of graphene planes and the preservation of the structure of basal planes in obtained nanostructures as in the source graphite. The effect of humidity on the conductivity of FLGS films was studied. The resistance of films was found to increase with an increase in the relative humidity of the environment due to the shielding of FLGS flakes by a film of water. The effect of different solvents on the current-voltage characteristics of FLGS was analyzed. The conductivity of films significantly decreased in vapors of polar protic solvents, while there was a minor effect of nonpolar aprotic solvents on the conductivity of FLGS films.


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