Thermoplastic Composites: Modelling Melting, Decomposition and Combustion of Matrix Polymers

In thermoplastic composites, the polymeric matrix upon exposure to heat may melt, decompose and deform prior to burning, as opposed to the char-forming matrices of thermoset composites, which retain their shape until reaching a temperature at which decomposition and ignition occur. In this work, a theoretical and numerical heat transfer model to simulate temperature variations during the melting, decomposition and early stages of burning of commonly used thermoplastic matrices is proposed. The scenario includes exposing polymeric slabs to one-sided radiant heat in a cone calorimeter with heat fluxes ranging from 15 to 35 kW/m2. A one-dimensional finite difference method based on the Stefan approach involving phase-changing and moving boundary conditions was developed by considering convective and radiative heat transfer at the exposed side of the polymer samples. The polymers chosen to experimentally validate the simulated results included polypropylene (PP), polyester (PET), and polyamide 6 (PA6). The predicted results match well with the experimental results.

Preparation of a Photosensitive Composite Carbon Fiber for Spilled Oil Cleaning

This paper deals with preparing a functional composite carbon fiber with a large surface area for spilled oil cleaning. The composite fiber consisted of photosensitive oxide particles and polymer-derived carbon. It was made by co-spinning the polymer and metallic compounds. After heat treatment at high temperatures, an activated carbon fiber containing oxide particles was obtained. The particles were found distributed in the fiber and at the surface of the fiber. The composite fiber was found sensitive to sunlight. Fiber mats made of the composite fiber possessed a high surface area for oil absorption and removal. Cobalt(II) titanate particles were obtained from the reaction of titanium dioxide and cobalt oxide. The reaction happened in situ through the hydrolysis of metallic compounds in the spun fiber. The titanium dioxide and cobalt(II) titanate particle-containing fibers demonstrated the photoactivity in the visible light spectrum. It was concluded that particle-containing composite carbon fiber mats can be prepared successfully by co-electrospinning. Due to the oleophilic property and the high active surface area, the composites are suitable for spilled oil cleaning through fast absorption.

Thermoelectric Performance of Polypropylene/Carbon Nanotube/Ionic Liquid Composites and Its Dependence on Electron Beam Irradiation

The thermoelectric behavior of polypropylene (PP) based nanocomposites containing single walled carbon nanotubes (SWCNTs) and five kinds of ionic liquids (Ils) dependent on composite composition and electron beam irradiation (EB) was studied. Therefore, several samples were melt-mixed in a micro compounder, while five Ils with sufficiently different anions and/or cations were incorporated into the PP/SWCNT composites followed by an EB treatment for selected composites. Extensive investigations were carried out considering the electrical, thermal, mechanical, rheological, morphological and, most significantly, thermoelectric properties. It was found that it is possible to prepare n-type melt-mixed polymer composites from p-type commercial SWCNTs with relatively high Seebeck coefficients when adding four of the selected Ils. The highest Seebeck coefficients achieved in this study were +49.3 µV/K (PP/2 wt.% SWCNT) for p-type composites and −27.6 µV/K (PP/2 wt.% SWCNT/4 wt.% IL type AMIM Cl) for n-type composites. Generally, the type of IL is decisive whether p- or n-type thermoelectric behavior is achieved. After IL addition higher volume conductivity could be reached. Electron beam treatment of PP/SWCNT leads to increased values of the Seebeck coefficient, whereas the EB treated sample with IL (AMIM Cl) shows a less negative Seebeck coefficient value.

Role of Solvent Polarity on Dispersion Quality and Stability of Functionalized Carbon Nanotubes

Dispersion of carbon nanotubes (CNT) in solvents and/or polymers is essential to reach the full potential of the CNTs in nanocomposite materials. Dispersion of CNTs is especially challenging due to the van-der-Waals attraction forces between the CNTs, which let them tend to re-bundle and/or re-aggregate. This paper presents a brief analysis of the quality and stability of functionalized multiwalled carbon nanotubes (fMWCNT) dispersion on polar solvents. A comparative study of functionalized CNT dispersion in water, methyl, and alcohol-based organic solvents has been carried out and the dispersion has been characterized by UV-VIS spectroscopy, electrochemical characterization such as cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). Visual analysis of the dispersion has been investigated for up to 14 days to assess the dispersion’s stability. Based on the material characterization, it was observed that the degree of affinity fMWCNT with -COOH group highly depends on the polarity of the solvent, where the higher the polarity, the better the interaction of fMWCNT with solvents.

A Review on the Performance Evaluation of Autonomous Self-Healing Bacterial Concrete: Mechanisms, Strength, Durability, and Microstructural Properties

The development of cracks, owing to a relatively lower tensile strength of concrete, diverse loading, and environmental factors driving the deterioration of structures, is an inescapable key concern for engineers. Reparation and maintenance operations are thus extremely important to prevent cracks from spreading and mitigating the lifetime of structures. However, ease of access to the cracked zone may be challenging, and it also needs funds and manual power. Hence, autonomous sealing of cracks employing microorganisms into the concrete sans manual intervention is a promising solution to the dilemma of the sustainable improvement of concrete. ‘Ureolytic bacteria’, key organism species in rumen-producing ‘urease’ enzymes such as Bacillus pasteurii or subtilis—when induced—are capable of producing calcium carbonate precipitations into the concrete. As their cell wall is anionic, CaCO3 accumulation on their surface is extensive, and the whole cell, therefore, becomes crystalline and ultimately plugs pores and cracks. This natural induction technique is an environmentally friendly method that researchers are studying intensively. This manuscript reviews the application process of bacterial healing to manufacture autonomous self-healing bacterial concrete. Additionally, it provides a brief review of diverse attributes of this novel concrete which demonstrate the variations with the auto-addition of different bacteria, along with an evaluation of crack healing as a result of the addition of these bacteria directly into concrete or after encapsulation in a protective shell. Comparative assessment techniques for autonomous, bio-based self-healing are also discussed, accompanied by progress, potential, modes of application of this technique, and its resultant benefits in the context of strength and durability. Imperatives for quantitative sustainability assessment and industrial adoption are identified, along with the sealing of artificially cracked cement mortar with sand as a filling material in given spaces, as well as urea and CaCl2 medium treatment with Bacillus pasteurii and Sporosarcina bacteria. The assessment of the impact on the compressive strength and rigidity of cement mortar cubes after the addition of bacteria into the mix is also considered. Scanning electron microscope (SEM) images on the function of bacteria in mineral precipitation that is microbiologically induced are also reviewed. Lastly, future research scope and present gaps are recognised and discussed.

Thermal Qualification of the UHTCMCs Produced Using RF-CVI Technique with VMK Facility at DLR

Ultra high-temperature ceramic matrix composites (UHTCMCs) based on carbon fibre (Cf) have been shown to offer excellent temperature stability exceeding 2000 °C in highly corrosive environments, which are prime requirements for various aerospace applications. In C3Harme, a recent European Union-funded Horizon 2020 project, an experimental campaign has been carried out to assess and screen a range of UHTCMC materials for near-zero ablation rocket nozzle and thermal protection systems. Samples with ZrB2-impregnated pyrolytic carbon matrices and 2.5D woven continuous carbon fibre preforms, produced by slurry impregnation and radio frequency aided chemical vapour infiltration (RF-CVI), were tested using the vertical free jet facility at DLR, Cologne using solid propellants. When compared to standard CVI, RFCVI accelerates pyrolytic carbon densification, resulting in a much shorter manufacturing time. The samples survived the initial thermal shock and subsequent surface temperatures of >2000 °C with a minimal ablation rate. Post-test characterisation revealed a correlation between surface temperature and an accelerated catalytic activity, which lead to an understanding of the crucial role of preserving the bulk of the sample.

Thermal Behavior of a Light Timber-Frame Wall vs. a Theoretical Simulation with Various Insulation Materials

The objective of this paper is to compare the thermal behavior of a light frame timber wall by measuring 15 test samples with various insulation materials versus a theoretical simulation with the use of a software. This work establishes the variance between the two different methods to measure the thermal transmittance coefficient of timber walls. It is verified that the mean percentage alteration between the two methods is 4.25%. Furthermore, this approach proved that with the use of a simulation software, additional readings (humidity, vapor flux, heat flux, and vapor pressure) can also be considered and measured, enhancing the overall development of a timber wall. This can provide additional information regarding to the characteristics of the masonry’s elements assisting in an improved design of a timber wall with upgraded performance.

FEM-Validated Optimal Design of Laminate Process Parameters Based on Improved Genetic Algorithm

In tape placement process, the laying angle and laying sequence of laminates have proven their significant effects on the mechanical properties of carbon fibre reinforced composite material, specifically, laminates. In order to optimise these process parameters, an optimisation algorithm is developed based on the principles of genetic algorithms for improving the precision of traditional genetic algorithms and resolving the premature phenomenon in the optimisation process. Taking multi-layer symmetrically laid carbon fibre laminates as the research object, this algorithm adopts binary coding to conduct the optimisation of process parameters and mechanical analysis with the laying angle as the design variable and the strength ratio R as the response variable. A case study was conducted and its results were validated by the finite element analyses. The results show that the stresses before and after optimisation are 116.0 MPa and 100.9 MPa, respectively, with a decrease of strength ratio by 13.02%. The results comparison indicates that, in the iterative process, the search range is reduced by determining the code and location of important genes, thereby reducing the computational workload by 21.03% in terms of time consumed. Through multiple calculations, it validates that “gene mutation” is an indispensable part of the genetic algorithm in the iterative process.

Chemical Supercritical Fluid Infiltration of Pyrocarbon with Thermal Gradients: Deposition Kinetics and Multiphysics Modeling

The chemical supercritical fluid infiltration process is a recent variation of the chemical vapor infiltration (CVI) process that allows rapid and efficient manufacturing of ceramic-matrix composites (CMCs), albeit still needing optimization. This article proposes a quantitative assessment of the process dynamics through experiments and modeling. The kinetics of carbon deposition were determined through two sets of experiments: CVD on a single filament at pressures between 10 and 50 bar and infiltration at pressures ranging between 50 and 120 bar. The CVI experiments were conducted under important thermal gradients and were interpreted using a model-based reconstitution of these gradients. We found that (i) the kinetic law has to incorporate the potential effect of the reverse reaction (i.e., etching of C by H2); (ii) the activation energy and pre-exponential factor both decrease with pressure up to 50 bar, then remain roughly constant, and (iii) although the apparent activation energy is modest, a favorable situation occurs in which an infiltration front builds up and travels from the hottest to the coldest part of the preform due to the presence of sufficient heat flux. A numerical simulation of the process, based on the solution of momentum, heat, and mass balance equations, fed with appropriate laws for the effective transfer properties of the porous medium and their evolution with infiltration progress, was performed and validated by comparing the simulated and actual infiltration profiles.

Integrating Soft Hydrogel with Nanostructures Reinforces Stem Cell Adhesion and Differentiation

Biophysical cues can regulate stem cell behaviours and have been considered as critical parameters of synthetic biomaterials for tissue engineering. In particular, hydrogels have been utilized as promising biomimetic and biocompatible materials to emulate the microenvironment. Therefore, well-defined mechanical properties of a hydrogel are important to direct desirable phenotypes of cells. Yet, limited research pays attention to engineering soft hydrogel with improved cell adhesive property, which is crucial for stem cell differentiation. Herein, we introduce silica nanoparticles (SiO2 NPs) onto the surface of methacrylated hyaluronic (MeHA) hydrogel to manipulate the presentation of cell adhesive ligands (RGD) clusters, while remaining similar bulk mechanical properties (2.79 ± 0.31 kPa) to that of MeHA hydrogel (3.08 ± 0.68 kPa). RGD peptides are either randomly decorated in the MeHA hydrogel network or on the immobilized SiO2 NPs (forming MeHA–SiO2). Our results showed that human mesenchymal stem cells exhibited a ~1.3-fold increase in the percentage of initial cell attachment, a ~2-fold increase in cell spreading area, and enhanced expressions of early-stage osteogenic markers (RUNX2 and alkaline phosphatase) for cells undergoing osteogenic differentiation with the osteogenic medium on MeHA–SiO2 hydrogel, compared to those cultured on MeHA hydrogel. Importantly, the cells cultivated on MeHA–SiO2 expressed a ~5-fold increase in nuclear localization ratio of the yes-associated protein, which is known to be mechanosensory in stem cells, compared to the cells cultured on MeHA hydrogel, thereby promoting osteogenic differentiation of stem cells. These findings demonstrate the potential use of nanomaterials into a soft polymeric matrix for enhanced cell adhesion and provide valuable guidance for the rational design of biomaterials for implantation.