Highly Dispersed Surfactant-Free Nickel Nanoparticles and Their Remarkable Catalytic Activity in the Hydrolysis of Ammonia Borane for Hydrogen Generation

2012 ◽  
Vol 51 (27) ◽  
pp. 6753-6756 ◽  
Author(s):  
Pei-Zhou Li ◽  
Arshad Aijaz ◽  
Qiang Xu
2015 ◽  
Vol 5 (1) ◽  
pp. 525-530 ◽  
Author(s):  
Jun Li ◽  
Qi-Long Zhu ◽  
Qiang Xu

Non-noble bimetallic CuCo alloy nanoparticles were successfully encapsulated in the pores of MIL-101 without aggregation on the external surfaces of the host framework, which exhibit excellent catalytic activity for hydrolytic dehydrogenation of ammonia borane.


2016 ◽  
Vol 852 ◽  
pp. 252-256
Author(s):  
Wei Dong Qi ◽  
Li Xian Sun ◽  
Fen Xu ◽  
Yong Jin Zou ◽  
Hai Liang Chu

Ammonia borane received extensive attention due to its hydrogen content as high as 19.6%. In present article we prepared the Pt-Co/C catalyst via ultrasonic immersion method and in situ reduction method. The catalyst was characterized by measuring the specific area. The influence of the catalyst on the properties of the hydrolysis of ammonia borane was tested, and the catalytic activity of the catalyst in cycle use was verified. Results shows that the catalytic activity of Pt0.5Co0.5/C is the highest, and the maximum hydrogen generation rate is 7229.613 mL/ (g ·min). It was verified that it remained good catalytic activity after cycle use for more than 10 times.


2014 ◽  
Vol 2 (39) ◽  
pp. 16652-16659 ◽  
Author(s):  
Mojtaba Mahyari ◽  
Ahmad Shaabani

Nickel nanoparticles immobilized on three-dimensional nitrogen-doped graphene-based frameworks (NiNPs@3D-(N)GFs) were synthesized and examined for hydrogen generation from the hydrolytic dehydrogenation of ammonia borane.


2017 ◽  
Vol 41 (7) ◽  
pp. 2793-2799 ◽  
Author(s):  
Guangyin Fan ◽  
Xiaojing Li ◽  
Yuling Ma ◽  
Yun Zhang ◽  
Jiangtao Wu ◽  
...  

Magnetic recyclable PtyCo1−y/Ti3C2X2 (X = O, F) catalyst exhibits excellent catalytic performance for the hydrolysis of AB at room temperature.


2017 ◽  
Vol 7 (2) ◽  
pp. 322-329 ◽  
Author(s):  
Jiankang Zhang ◽  
Chaoqiu Chen ◽  
Shuai Chen ◽  
Qingmin Hu ◽  
Zhe Gao ◽  
...  

Highly active Pt nanoparticles deposited on CNTs were synthesized by atomic layer deposition used for hydrogen generation from AB hydrolysis.


2018 ◽  
Vol 148 (6) ◽  
pp. 1739-1749 ◽  
Author(s):  
Hongli Wang ◽  
Dawei Gao ◽  
Liying Wang ◽  
Yue Chi ◽  
Minggang Wang ◽  
...  

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