ABSTRACTCeramic tools were made in lowland Mesopotamia from about 4500 to 2750 B.C.E. At first hammers, adzes, axes and sickles were made. By about 3300-3100 B.C.E., only sickles were made. We reverse engineered the technology to show that local, salty montmorillonite clay and quartz sand were formed into a composite blade and handle from a biconical coil and fired to 1120-1170°C based on analysis of refiring tests. At 1200°C the montmorillonite clay transforms to glass, so the firing range was right on the edge of slumping the ceramic into a useless mass. To prevent plastic deformation of the clay about 25-33 vol% of quartz sand was added. The extensive glassy matrix phase enabled the best blades to be resharpened by pressure flaking. The compositions, phase assemblage, firing temperature range, material limits on processing, and properties have been characterized for 15 sickle samples from Nippur using Xeroradiography, SEM-EDS, EPMA, and analysis of refiring tests. Strength and hardness tests and toughness calculations were conducted on replicate test tiles made using clay from Pit M at Nippur, Iraq, and sand.Based on finds of small groups of well-fused sickles that were overfired and melted together and our experiments that demonstrated the difficulty of controlling peak temperature range and firing time for the somewhat variable raw material, the sickles probably were fired in small groups, of perhaps 10-15, in small arched, tunnel kilns that achieved high temperatures by facing somewhat predictable oncoming wind flows that provided natural draft. No evidence of workshops has been located, but, based on the archaeological finds at Nippur and our analyses, we propose that sickle-making may have been practiced as a local, seasonal, popular technology with tools being made by farmers or part-time specialists who fired in small, temporary tunnel kilns in fields or near settlements during the dependable seasonal winds. This research investigated the sickles as a well-engineered, but risk-prone ceramic manufacture that fulfilled an important a societal need, agricultural success. The technological choices of craftsmen were narrowed by raw material constraints, risk-taking, practice and workmanship to achieve desired properties and performance characteristics.
The influence of metahalloysite addition on tobermorite formation studied by X-ray powder diffraction and scanning electron microscope