Fluid inclusions of the high-pressure granulites from the Namche Barwa complex of the eastern Himalayan syntaxis, Tibet: Fluid composition and evolution in the continental subduction-zone

2010 ◽  
Vol 38 (1-2) ◽  
pp. 44-56 ◽  
Author(s):  
Kun Shen ◽  
Jinli Wang ◽  
Xin Dong
Keyword(s):  
High Pressure ◽  
Subduction Zone ◽  
Fluid Inclusions ◽  
Fluid Composition ◽  
Continental Subduction ◽  
Namche Barwa ◽  
Eastern Himalayan Syntaxis

scholarly journals Up the down escalator: the exhumation of (ultra)-high pressure terranes during on-going subduction

2012 ◽  
Vol 4 (1) ◽  
pp. 745-781 ◽  
Author(s):  
C. J. Warren
Keyword(s):  
High Pressure ◽  
Subduction Zone ◽  
Continental Crust ◽  
Subduction Zones ◽  
Crustal Material ◽  
Time And Space ◽  
Ultra High Pressure ◽  
Tectonic Environment ◽  
Tectonic Style ◽  
Weak Material

Abstract. The exhumation of high and ultra-high pressure rocks is ubiquitous in Phanerozoic orogens created during continental collisions, and is common in many ocean-ocean and ocean-continent subduction zone environments. Three different tectonic environments have previously been reported, which exhume deeply buried material by different mechanisms and at different rates. However it is becoming increasingly clear that no single mechanism dominates in any particular tectonic environment, and the mechanism may change in time and space within the same subduction zone. In order for buoyant continental crust to subduct, it must remain attached to a stronger and denser substrate, but in order to exhume, it must detach (and therefore at least locally weaken) and be initially buoyant. Denser oceanic crust subducts more readily than more buoyant continental crust but exhumation must be assisted by entrainment within more buoyant and weak material such as serpentinite or driven by the exhumation of structurally lower continental crustal material. Weakening mechanisms responsible for the detachment of crust at depth include strain, hydration, melting, grain size reduction and the development of foliation. These may act locally or may act on the bulk of the subducted material. Metamorphic reactions, metastability and the composition of the subducted crust all affect buoyancy and overall strength. Subduction zones change in style both in time and space, and exhumation mechanisms change to reflect the tectonic style and overall force regime within the subduction zone. Exhumation events may be transient and occur only once in a particular subduction zone or orogen, or may be more continuous or occur multiple times.

High-pressure experimental verification of rutile-ilmenite oxybarometer: Implications for the redox state of the subduction zone

2017 ◽  
Vol 60 (10) ◽  
pp. 1817-1825 ◽  
Author(s):  
RenBiao Tao ◽  
LiFei Zhang ◽  
Vincenzo Stagno ◽  
Xu Chu ◽  
Xi Liu
Keyword(s):  
High Pressure ◽  
Subduction Zone ◽  
Experimental Verification ◽  
Redox State

Are Vapor-Like Fluids Viable Ore Fluids for Cu-Au-Mo Porphyry Ore Formation?

2021 ◽  
Author(s):  
Nicole C. Hurtig ◽  
Artas A. Migdisov ◽  
Anthony E. Williams-Jones
Keyword(s):  
Fluid Inclusions ◽  
Metal Content ◽  
Ore Deposits ◽  
Fluid Composition ◽  
Ore Formation ◽  
Metal Solubility ◽  
Gas Condensates ◽  
Intermediate Density ◽  
Metallic Species ◽  
Metal Ratios

Abstract Ore formation in porphyry Cu-Au-(Mo) systems involves the exsolution of metal-bearing fluids from magmas and the transport of the metals in magmatic-hydrothermal plumes that are subject to pressure fluctuations. Deposition of ore minerals occurs as a result of cooling and decompression of the hydrothermal fluids in partly overlapping ore shells. In this study, we address the role of vapor-like fluids in porphyry ore formation through numerical simulations of metal transport using the Gibbs energy minimization software, GEM-Selektor. The thermodynamic properties of the hydrated gaseous metallic species necessary for modeling metal solubility in fluids of moderate density (100–300 kg/m3) were derived from the results of experiments that investigated the solubility of metals in aqueous HCl- and H2S-bearing vapors. Metal transport and precipitation were simulated numerically as a function of temperature, pressure, and fluid composition (S, Cl, and redox). The simulated metal concentrations and ratios are compared to those observed in vapor-like and intermediate-density fluid inclusions from porphyry ore deposits, as well as gas condensates from active volcanoes. The thermodynamically predicted solubility of Cu, Au, Ag, and Mo decreases during isothermal decompression. At elevated pressure, the simulated metal solubility is similar to the metal content measured in vapor-like and intermediate-density fluid inclusions from porphyry deposits (at ~200–1,800 bar). At ambient pressure, the metal solubility approaches the metal content measured in gas condensates from active volcanoes (at ~1 bar), which is several orders of magnitude lower than that in the high-pressure environment. During isochoric cooling, the simulated solubility of Cu, Ag, and Mo decreases, whereas that of Au reaches a maximum between 35 ppb and 2.6 ppm depending on fluid density and composition. Similar observations are made from a compilation of vapor-like and intermediate-density fluid inclusion data showing that Cu, Ag, and Mo contents decrease with decreasing P and T. Increasing the Cl concentration of the simulated fluid promotes the solubility of Cu, Ag, and Au chloride species. Molybdenum solubility is highest under oxidizing conditions and low S content, and gold solubility is elevated at intermediate redox conditions and elevated S content. The S content of the vapor-like fluid strongly affects metal ratios. Thus, there is a decrease in the Cu/Au ratio as the S content increases from 0.1 to 1 wt %, whereas the opposite is the case for the Mo/Ag ratio; at S contents of >1 wt %, the Mo/Ag ratio also decreases. In summary, thermodynamic calculations based on experiments involving gaseous metallic species predict that vapor-like fluids may transport and efficiently precipitate metals in concentrations sufficient to form porphyry ore deposits. Finally, the fluid composition and pressure-temperature evolution paths of vapor-like and intermediate-density fluids have a strong effect on metal solubility in porphyry systems and potentially exert an important control on their metal ratios and zoning.

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