Effects of solution pH and polyethylene oxide concentrations on molybdenite−molybdenite, molybdenite−kaolinite, and molybdenite−quartz interaction forces: AFM colloidal probe study

Author(s):  
Yingwei Wang ◽  
Yijun Cao ◽  
Shanshan Hu ◽  
Junchao Wang ◽  
Fayang Guo ◽  
...  
2008 ◽  
Vol 155 (4) ◽  
pp. H218 ◽  
Author(s):  
Silvia Armini ◽  
Ruslan Burtovyy ◽  
Mansour Moinpour ◽  
Igor Luzinov ◽  
Joke De Messemaeker ◽  
...  

2006 ◽  
Vol 5 (3) ◽  
pp. 251-256
Author(s):  
Susumu KUROSAWA ◽  
Masashi MIZUKAMI ◽  
Hisao SATO ◽  
Jun NOZAWA ◽  
Keiichi TSUJIMOTO ◽  
...  

2020 ◽  
Vol 4 (3) ◽  
pp. 41
Author(s):  
Illia Dobryden ◽  
Elizaveta Mensi ◽  
Allan Holmgren ◽  
Nils Almqvist

Dispersion and aggregation of nanomagnetite (Fe3O4) and silica (SiO2) particles are of high importance in various applications, such as biomedicine, nanoelectronics, drug delivery, flotation, and pelletization of iron ore. In directly probing nanomagnetite–silica interaction, atomic force microscopy (AFM) using the colloidal probe technique has proven to be a suitable tool. In this work, the interaction between nanomagnetite and silica particles was measured with AFM in aqueous Ca2+ solution at different pH levels. This study showed that the qualitative changes of the interaction forces with pH and Ca2+ concentrations were consistent with the results from zeta-potential measurements. The repulsion between nanomagnetite and silica was observed at alkaline pH and 1 mM Ca2+ concentration, but no repulsive forces were observed at 3 mM Ca2+ concentration. The interaction forces on approach were due to van der Waals and electrical double-layer forces. The good fitting of experimental data to the DLVO model and simulations supported this conclusion. However, contributions from non-DLVO forces should also be considered. It was shown that an increase of Ca2+ concentration from 1 to 3.3 mM led to a less pronounced decrease of adhesion force with increasing pH. A comparison of measured and calculated adhesion forces with a few contact mechanics models demonstrated an important impact of nanomagnetite layer nanoroughness.


Author(s):  
C.N. Sun

The present study demonstrates the ultrastructure of the gingival epithelium of the pig tail monkey (Macaca nemestrina). Specimens were taken from lingual and facial gingival surfaces and fixed in Dalton's chrome osmium solution (pH 7.6) for 1 hr, dehydrated, and then embedded in Epon 812.Tonofibrils are variable in number and structure according to the different region or location of the gingival epithelial cells, the main orientation of which is parallel to the long axis of the cells. The cytoplasm of the basal epithelial cells contains a great number of tonofilaments and numerous mitochondria. The basement membrane is 300 to 400 A thick. In the cells of stratum spinosum, the tonofibrils are densely packed and increased in number (fig. 1 and 3). They seem to take on a somewhat concentric arrangement around the nucleus. The filaments may occur scattered as thin fibrils in the cytoplasm or they may be arranged in bundles of different thickness. The filaments have a diameter about 50 A. In the stratum granulosum, the cells gradually become flatted, the tonofibrils are usually thin, and the individual tonofilaments are clearly distinguishable (fig. 2). The mitochondria and endoplasmic reticulum are seldom seen in these superficial cell layers.


Author(s):  
G. G. Cocks ◽  
C. E. Cluthe

The freeze etching technique is potentially useful for examining dilute solutions or suspensions of macromolecular materials. Quick freezing of aqueous solutions in Freon or propane at or near liquid nitrogen temperature produces relatively large ice crystals and these crystals may damage the structures to be examined. Cryoprotective agents may reduce damage to the specimem, hut their use often results in the formation of a different set of specimem artifacts.In a study of the structure of polyethylene oxide gels glycerol and sucrose were used as cryoprotective agents. The experiments reported here show some of the structures which can appear when these cryoprotective agents are used.Figure 1 shows a fractured surface of a frozen 25% aqueous solution of sucrose. The branches of dendritic ice crystals surrounded hy ice-sucrose eutectic can be seen. When this fractured surface is etched the ice in the dendrites sublimes giving the type of structure shown in Figure 2. The ice-sucrose eutectic etches much more slowly. It is the smooth continuous structural constituent surrounding the branches of the dendrites.


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