scholarly journals Influence of Cu content on the phase composition and thermoelectric properties of deposited Cu-Se films

2022 ◽  
Vol 28 ◽  
pp. 101651
Author(s):  
Guipeng Li ◽  
Guihong Song ◽  
Nan Wang ◽  
Fang Hu ◽  
Yusheng Wu ◽  
...  
2021 ◽  
Vol 16 (3) ◽  
pp. 351-356
Author(s):  
A. A. Ivanov ◽  
R. Kh. Akchrin ◽  
D. I. Bogomolov ◽  
V. T. Bublik ◽  
M. V. Voronov ◽  
...  

Materials ◽  
2018 ◽  
Vol 11 (5) ◽  
pp. 773 ◽  
Author(s):  
Lihong Huang ◽  
Junchen Wang ◽  
Xi Chen ◽  
Ran He ◽  
Jing Shuai ◽  
...  

2020 ◽  
Vol 4 (1) ◽  
pp. 67-85
Author(s):  
M.M. Kubenova ◽  
M.Kh. Balapanov ◽  
K.A. Kuterbekov ◽  
R.Kh. Ishembetov ◽  
A.M. Kabyshev ◽  
...  

2021 ◽  
Vol 38 (11) ◽  
pp. 117201
Author(s):  
Zhongmou Yue ◽  
Kunpeng Zhao ◽  
Hongyi Chen ◽  
Pengfei Qiu ◽  
Lidong Chen ◽  
...  

Coupling of a phase transition to electron and phonon transports provides extra degree of freedom to improve the thermoelectric performance, while the pertinent experimental and theoretical studies are still rare. Particularly, the impaction of chemical compositions and phase transition characters on the abnormal thermoelectric properties across phase transitions are largely unclear. Herein, by varying the Cu content x from 1.75 to 2.10, we systemically investigate the crystal structural evolution, phase transition features, and especially the thermoelectric properties during the phase transition for Cu x Se. It is found that the addition of over-stoichiometry Cu in Cu x Se could alter the phase transition characters and suppress the formation of Cu vacancies. The critical scatterings of phonons and electrons during phase transitions strongly enhance the Seebeck coefficient and diminish the thermal conductivity, leading to an ultrahigh dimensionless thermoelectric figure of merit of ∼1.38 at 397 K in Cu2.10Se. With the decreasing Cu content, the critical electron and phonon scattering behaviors are mitigated, and the corresponding thermoelectric performances are reduced. This work offers inspirations for understanding and tuning the thermoelectric transport properties during phase transitions.


2017 ◽  
Vol 1 (1) ◽  
pp. 113-122 ◽  
Author(s):  
Britta Ryll ◽  
Andreas Schmitz ◽  
Johannes de Boor ◽  
Alexandra Franz ◽  
Pamela S. Whitfield ◽  
...  

2017 ◽  
Vol 18 (2) ◽  
pp. 211-214 ◽  
Author(s):  
M.O. Haluschak ◽  
I.V. Horichok ◽  
T.O. Semko ◽  
S.I. Mydryi ◽  
S. Optasyuk ◽  
...  

The phase composition and thermoelectric properties of solid solutions Pb16Sn2Ag2Te20 and Pb14Sn4Ag2Te20 are researched. Biphasic structure of the samples is installed, which providing to low values of thermal conductivity. Best samples have values of dimensionless thermoelectric figure of merit ZT ≈ 0,55.


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