Destruction of C2H4O2 isomers in ice-phase by X-rays: Implication on the abundance of acetic acid and methyl formate in the interstellar medium

2017 ◽  
Vol 13 (S332) ◽  
pp. 418-424
Author(s):  
Marina G. Rachid ◽  
K. Faquine ◽  
S. Pilling
Keyword(s):  
Acetic Acid ◽  
Cross Sections ◽  
Methyl Formate ◽  
X Rays ◽  
Formation Cross Section ◽  
X Ray ◽  
Synchrotron Light ◽  
The Difference ◽  
Astrophysical Ices

AbstractC2H4O2 isomers, methyl formate (HCOOCH3), acetic acid (CH3COOH) and glycoaldehyde (HOCH2CHO), have been detected in a lot of sources in ISM. However, their abundances are very different, with methyl formate much more abundant than the other two isomers. This fact may be related to the different destruction by ionizing radiation of these molecules. The goal of this work is experimentally study the photodissociation processes of methyl formate and acetic acid ices when exposed to broadband soft X-ray from 6 up to 2000 eV. The experiments were performed coupled to the SGM beamline in the Brazilian Synchrotron Light Source (LNLS/CNPEM) at Campinas, Brazil. The simulated astrophysical ices (12K) were monitored throughout the experiment using infrared vibrational spectroscopy. The analysis of processed ices allowed the determination of the effective destruction cross sections of the parent molecules as well as the effective formation cross section of daughter molecular species. The relative abundance between acetic acid and methyl formate (NCH3COOH/NHCOOCH3) in different astronomical scenarios and their column density evolution in the presence of X-rays were calculated and our results suggests that such radiation field can be one of the factors that explain the difference in the isomers C2H4O2 abundances. We also quantified the daugther species after the establishment of a chemical equilibrium in the samples.

scholarly journals Photoproduction of H3+ from gaseous methanol inside dense molecular clouds

2008 ◽  
Vol 4 (S251) ◽  
pp. 369-370
Author(s):  
S. Pilling ◽  
D. P. P. Andrade ◽  
A. C. F. Santos ◽  
H. M. Boechat-Roberty
Keyword(s):  
Cross Sections ◽  
Molecular Clouds ◽  
Mass Spectra ◽  
Column Density ◽  
X Rays ◽  
Alternative Source ◽  
X Ray ◽  
Flight Mass Spectrometry ◽  
Dense Molecular Cloud ◽  
Synchrotron Light

AbstractWe present experimental results obtained from photoionization and photodissociation processes of abundant interstellar methanol (CH3OH) as an alternative route for the production of H3+ in dense clouds. The measurements were taken at the Brazilian Synchrotron Light Laboratory (LNLS) employing soft X-ray and time-of-flight mass spectrometry. Mass spectra were obtained using the photoelectron-photoion coincidence techniques. Absolute averaged cross sections for the production of H3+ due to molecular dissociation of methanol by soft X-rays (C1s edge) were determined. The H3+'s photoproduction rate and column density were been estimated adopting a typical soft X-ray luminosity inside dense molecular and the observed column density of methanol. Assuming a steady state scenario, the highest column density value for the photoproduced H3+ was about 1011 cm2, which gives the ratio photoproduced/observed of about 0.05%, as in the case of dense molecular cloud AFGL 2591. Despite the small value, this represent a new and alternative source of H3+ into dense molecular clouds and it is not been considered as yet in interstellar chemistry models.

Determination of K shell absorption parameters for some lanthanides using the X-ray attenuation method

2015 ◽  
Vol 93 (12) ◽  
pp. 1532-1540 ◽  
Author(s):  
F. Akman ◽  
R. Durak ◽  
M.R. Kaçal
Keyword(s):  
Cross Section ◽  
Cross Sections ◽  
Experimental Results ◽  
Secondary Source ◽  
X Rays ◽  
Strength Parameters ◽  
X Ray ◽  
Total Attenuation ◽  
First Time

The total attenuation cross section at the K edge, absorption jump ratio, jump factor, Davisson–Kirchner ratio, and oscillator strength parameters for the K shell were determined by measuring the total attenuation cross sections around the K edge for Pr, Nd2O3, and Sm. The measurements were performed in a secondary excitation geometry using the Kα2, Kα1, Kβ1, and Kβ2 X-rays (in the region from 31.817 to 55.293 keV) from different secondary source targets excited by the 59.54 keV γ-photons from an 241Am annular source. It is the first time that the Davisson–Kirchner ratio values have been determined for present samples. The experimental results were compared with the theoretically calculated and other available experimental results.

scholarly journals An experimental study of diffuse X-ray reflexion by single crystals

1941 ◽  
Vol 179 (976) ◽  
pp. 8-50 ◽  
Keyword(s):  
Experimental Study ◽  
Single Crystals ◽  
Reciprocal Lattice ◽  
Organic Crystals ◽  
X Rays ◽  
X Ray ◽  
The Difference ◽  
Lattice Planes ◽  
Diffuse Spot

A historical introduction outlines the development of experimental and theoretical interest in the diffuse diffraction of X-rays by single crystals. The present experimental study, illustrated by numerous photographs, has consisted in taking Laue, oscillation and rotation photographs, in many different orientations, of inorganic and organic crystals belonging to various systems, using Cu, Mo and Ag radiations, unfiltered, filtered or monochromatized. Rules are laid down for the indexing of diffuse spots and for the determination of the conditions under which such spots appear. Attention is drawn to the presence of non-radial streaks and to the difference in origin of these and of the more usual radial streaks. The relations of the intensity, shape, size, position and persistence of the diffuse spots to the nature, structure, perfection, orientation and temperature of the crystal examined, to the radiation used and to the conditions of photography, are considered in some detail. The use of diffuse spot patterns as a subsidiary method of crystal structure determination is emphasized. It is pointed out that in reciprocal space each reflecting lattice point is surrounded by a region of diffuse scattering, whose physical significance is open to various theoretical interpretations. These diffusely reflecting regions are not, in general, spherical, but are extended along reciprocal lattice planes and axes.

Application of Multilayer Structures to the Determination of Optical Constants in the X-Ray, Soft X-Ray and Extreme Ultra Violet Spectral Ranges

1988 ◽  
Vol 143 ◽  
Author(s):  
Troy W. Barbee
Keyword(s):  
Cross Sections ◽  
Optical Constants ◽  
Extreme Ultraviolet ◽  
Ultra Violet ◽  
Multilayer Structures ◽  
X Rays ◽  
X Ray ◽  
Spectral Ranges ◽  
Scattering Cross Sections

AbstractThe dispersion of x-rays (XR), soft x-rays (SXR) and extreme ultraviolet (EUV) light by multilayer structures is dependent on the scattering and absorption cross-sections of the elements used to synthesize the multilayer. In this paper it will be shown that this dependence provides a means for the accurate experimental determination of the optical constants of the multilayer constituents. Two specific approaches will be presented and discussed. First, it will be shown that detailed analysis of the energy dependence of the reflectivity of a simple depth periodic multilayer allows the unfolding of the optical constants. Secondly a new optic structure, the multilayer diffraction grating, will be described and it will be demonstrated that such combined microstructure optics allow the scattering cross-sections of the multilayer constituents to be accurately determined over broad spectral ranges.

scholarly journals Determination of the mass attenuation coefficient for Aluminum element using (Cu,Mo) X-rays tubes

2019 ◽  
Vol 24 (1) ◽  
pp. 82
Author(s):  
Ahmad Mohamed Kheder ◽  
Muhsin Hasan Ali
Keyword(s):  
Experimental Data ◽  
Attenuation Coefficient ◽  
Cross Sections ◽  
Mass Attenuation Coefficient ◽  
X Rays ◽  
Attenuation Coefficients ◽  
X Ray ◽  
Mass Attenuation Coefficients ◽  
Mass Attenuation

In this study the value of linear  and mass  attenuation coefficients of Aluminum element (Al) were determinated by using x-ray Cu-tube of energies CuKα (8.048) KeV, CuKβ (8.906) KeV, and Mo-tube of energies MoKα (17.480) KeV and MoKβ (19.609) KeV.the voltage between the two electrodes are up to 35 KV.The measured  values are compared with other experimental data showing a general agreement within a precision of 0.2% - 0.8%. The mass attenuation cross-sections were thus derived and compared with other experimental data available on database of x-ray attenuation cross-sections. The agreement is always within ±7%.   http://dx.doi.org/10.25130/tjps.24.2019.013

Preparation And elemental analysis of ancient fibers

1987 ◽  
Vol 45 ◽  
pp. 410-411
Author(s):  
Allen Angel ◽  
Kathryn A. Jakes
Keyword(s):  
Cross Sections ◽  
Physical Structure ◽  
Energy Dispersive ◽  
Archaeological Sites ◽  
X Ray ◽  
Long Term Storage ◽  
Backscattered Electron ◽  
Electron Imaging

Fabrics recovered from archaeological sites often are so badly degraded that fiber identification based on physical morphology is difficult. Although diagenetic changes may be viewed as destructive to factors necessary for the discernment of fiber information, changes occurring during any stage of a fiber's lifetime leave a record within the fiber's chemical and physical structure. These alterations may offer valuable clues to understanding the conditions of the fiber's growth, fiber preparation and fabric processing technology and conditions of burial or long term storage (1).Energy dispersive spectrometry has been reported to be suitable for determination of mordant treatment on historic fibers (2,3) and has been used to characterize metal wrapping of combination yarns (4,5). In this study, a technique is developed which provides fractured cross sections of fibers for x-ray analysis and elemental mapping. In addition, backscattered electron imaging (BSI) and energy dispersive x-ray microanalysis (EDS) are utilized to correlate elements to their distribution in fibers.

Problems in Thin-Film X-ray Quantification

1990 ◽  
Vol 48 (2) ◽  
pp. 458-459
Author(s):  
J N Chapman ◽  
W A P Nicholson
Keyword(s):  
Thin Film ◽  
Specimen Thickness ◽  
X Rays ◽  
Characteristic Peak ◽  
Local Composition ◽  
X Ray ◽  
Measured Ratio ◽  
Path Lengths ◽  
Composition Changes

Energy dispersive x-ray microanalysis (EDX) is widely used for the quantitative determination of local composition in thin film specimens. Extraction of quantitative data is usually accomplished by relating the ratio of the number of atoms of two species A and B in the volume excited by the electron beam (nA/nB) to the corresponding ratio of detected characteristic photons (NA/NB) through the use of a k-factor. This leads to an expression of the form nA/nB = kAB NA/NB where kAB is a measure of the relative efficiency with which x-rays are generated and detected from the two species.Errors in thin film x-ray quantification can arise from uncertainties in both NA/NB and kAB. In addition to the inevitable statistical errors, particularly severe problems arise in accurately determining the former if (i) mass loss occurs during spectrum acquisition so that the composition changes as irradiation proceeds, (ii) the characteristic peak from one of the minority components of interest is overlapped by the much larger peak from a majority component, (iii) the measured ratio varies significantly with specimen thickness as a result of electron channeling, or (iv) varying absorption corrections are required due to photons generated at different points having to traverse different path lengths through specimens of irregular and unknown topography on their way to the detector.

scholarly journals Electronic Excitations and Radiation Damage in Macromolecular Crystallography

Crystals ◽  
2018 ◽  
Vol 8 (7) ◽  
pp. 273 ◽  
Author(s):  
José Brandão-Neto ◽  
Leonardo Bernasconi
Keyword(s):  
Chemical Information ◽  
X Rays ◽  
Electronic Excitations ◽  
Macromolecular Crystallography ◽  
X Ray Diffraction ◽  
X Ray ◽  
Atomic Structures ◽  
Successful Approach ◽  
Structural Research

Macromolecular crystallography at cryogenic temperatures has so far provided the majority of the experimental evidence that underpins the determination of the atomic structures of proteins and other biomolecular assemblies by means of single crystal X-ray diffraction experiments. One of the core limitations of the current methods is that crystal samples degrade as they are subject to X-rays, and two broad groups of effects are observed: global and specific damage. While the currently successful approach is to operate outside the range where global damage is observed, specific damage is not well understood and may lead to poor interpretation of the chemistry and biology of the system under study. In this work, we present a phenomenological model in which specific damage is understood as the result of a single process, the steady excitation of crystal electrons caused by X-ray absorption, which acts as a trigger for the bulk effects that manifest themselves in the form of global damage and obscure the interpretation of chemical information from XFEL and synchrotron structural research.

scholarly journals Electronic Excitations and Radiation Damage in Macromolecular Crystallography

2018 ◽  
Author(s):  
José Brandão-Neto ◽  
Leonardo Bernasconi
Keyword(s):  
Chemical Information ◽  
X Rays ◽  
Electronic Excitations ◽  
Macromolecular Crystallography ◽  
X Ray Diffraction ◽  
X Ray ◽  
Atomic Structures ◽  
Successful Approach ◽  
Structural Research

Macromolecular crystallography at cryogenic temperatures has so far provided the majority of the experimental evidence that underpins the determination of the atomic structures of proteins and other biomolecular assemblies by means of single crystal X-ray diffraction experiments. One of the core limitations of the current methods is that crystal samples degrade as they are subject to X-rays, and two broad groups of effects are observed: global and specific damage. While the currently successful approach is to operate outside the range where global damage is observed, specific damage is not well understood and may lead to poor interpretation of the chemistry and biology of the system under study. In this work, we present a phenomenological model in which specific damage is understood as the result of a single process, the steady excitation of crystal electrons caused by X-ray absorption, which acts as a trigger for the bulk effects that manifest themselves in the form of global damage and obscure the interpretation of chemical information from XFEL and synchrotron structural research.

Magnetic Structure of Multilayers from Soft-X-Ray Magnetic Circular Dichroism

1994 ◽  
Vol 375 ◽  
Author(s):  
C. T. Chen ◽  
Y. U. Idzerda ◽  
C.-C. Kao ◽  
L. H. Tjeng ◽  
H.-J. Lin ◽  
...  
Keyword(s):  
Thin Films ◽  
Circular Dichroism ◽  
Magnetic Circular Dichroism ◽  
Magnetic Thin Films ◽  
X Rays ◽  
X Ray ◽  
Specific Manner ◽  
Left And Right ◽  
The Difference ◽  
Circular Dichroïsm

AbstractSoft-x-ray magnetic circular dichroism (MCD) is the difference between the absorptivity or reflectivity of left and right circularly polarized soft-x-rays at the magnetically interesting L2,3- edges of 3d transition metals or the M4,5-edges of the 4f rare earth elements. Thanks to its large absorption cross-section and strong MCD effect, this technique has become a powerful new means for probing, in an element- and site-specific manner, the magnetic properties of ultra-thin films and multilayers. Soft-x-ray MCD experiments, recently conducted at the Dragon beamline, are utilized to demonstrate the recent progress in this technique and its applications in the research of magnetic thin films.

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