Optical Spectra and Magnetic Behavior of a Wide Range of Europium(III) Oxo-Compounds: Analysis of the Ligand-Field Effects

2017 ◽  
Vol 56 (15) ◽  
pp. 9235-9246 ◽  
Author(s):  
Anna Bronova ◽  
Nils Kannengießer ◽  
Robert Glaum
Keyword(s):  
Magnetic Behavior ◽  
Optical Spectra ◽  
Ligand Field ◽  
Field Effects ◽  
Wide Range ◽  
Oxo Compounds

scholarly journals Correlating Axial and Equatorial Ligand Field Effects to the Single-Molecule Magnet Performances of a Family of Dysprosium Bis-Methanediide Complexes

2021 ◽  
Author(s):  
Lewis Thomas-Hargreaves ◽  
Marcus Giansiracusa ◽  
Matthew Gregson ◽  
Emanuele Zanda ◽  
Felix O'Donnell ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Single Molecule ◽  
Ligand Field ◽  
Single Molecule Magnet ◽  
Field Effects ◽  
Equatorial Ligand ◽  
Metal Alkyls

Treatment of the new methanediide-methanide complex [Dy(SCS)(SCSH)(THF)] (1Dy, SCS = {C(PPh2S)2}2-) with alkali metal alkyls and auxillary ethers produces the bis-methanediide complexes [Dy(SCS)2][Dy(SCS)2(K(DME)2)2] (2Dy), [Dy(SCS)2][Na(DME)3] (3Dy) and [Dy(SCS)2][K(2,2,2-cryptand)] (4Dy). For...

scholarly journals Ligand Field Effects on the Ground and Excited States of the Catalytically Active FeO2+ Species

2018 ◽  
Author(s):  
Justin K. Kirkland ◽  
Shahriar N. Khan ◽  
Bryan Casale ◽  
Evangelos Miliordos ◽  
Konstantinos Vogiatzis
Keyword(s):  
Excited States ◽  
Function Theory ◽  
Weak Field ◽  
Ligand Field ◽  
Model Complexes ◽  
Coordination Environment ◽  
Reactivity Descriptors ◽  
Field Effects ◽  
Catalytically Active ◽  
High Level

<p>We have performed high-level wave function theory calculations on bare FeO2+ and a series of non-heme Fe(IV)-oxo model complexes in order to elucidate the electronic properties and the ligand field effects on those channels. Our results suggest that a coordination environment formed by a weak field gives access to both competitive channels, yielding more reactive Fe(IV)-oxo sites. On the contrary, a strong ligand environment stabilizes only the σ-channel. Our concluding remarks will aid on the derivation of new structure-reactivity descriptors that can contribute on the development of the next generation of functional catalysts.</p>

scholarly journals Ligand Field Effects on the Ground and Excited States of the Catalytically Active FeO2+ Species

2018 ◽  
Author(s):  
Justin K. Kirkland ◽  
Shahriar N. Khan ◽  
Bryan Casale ◽  
Evangelos Miliordos ◽  
Konstantinos Vogiatzis
Keyword(s):  
Excited States ◽  
Function Theory ◽  
Weak Field ◽  
Ligand Field ◽  
Model Complexes ◽  
Coordination Environment ◽  
Reactivity Descriptors ◽  
Field Effects ◽  
Catalytically Active ◽  
High Level

<p>We have performed high-level wave function theory calculations on bare FeO2+ and a series of non-heme Fe(IV)-oxo model complexes in order to elucidate the electronic properties and the ligand field effects on those channels. Our results suggest that a coordination environment formed by a weak field gives access to both competitive channels, yielding more reactive Fe(IV)-oxo sites. On the contrary, a strong ligand environment stabilizes only the σ-channel. Our concluding remarks will aid on the derivation of new structure-reactivity descriptors that can contribute on the development of the next generation of functional catalysts.</p>

Unusual ligand field effects in square-planar cobalt(II) complexes of quadridentate Schiff bases

1985 ◽  
Vol 24 (8) ◽  
pp. 1159-1165 ◽  
Author(s):  
A. Ceulemans ◽  
M. Dendooven ◽  
L. G. Vanquickenborne
Keyword(s):  
Schiff Bases ◽  
Ligand Field ◽  
Field Effects ◽  
Square Planar

Ab InitioCalculations on KNiF3: Ligand-Field Effects

1972 ◽  
Vol 5 (11) ◽  
pp. 4291-4301 ◽  
Author(s):  
A. J. H. Wachters ◽  
W. C. Nieuwpoort
Keyword(s):  
Ligand Field ◽  
Field Effects

scholarly journals Extragalactic Supergiants

2016 ◽  
Vol 12 (S329) ◽  
pp. 297-304
Author(s):  
Miguel A. Urbaneja ◽  
Rolf P. Kudritzki
Keyword(s):  
Quantitative Analysis ◽  
Chemical Composition ◽  
Optical Spectra ◽  
Host Galaxies ◽  
High Quality ◽  
Distant Galaxies ◽  
Wide Range

AbstractBlue supergiant stars of B and A spectral types are amongst the visually brightest non-transient astronomical objects. Their intrinsic brightness makes it possible to obtain high quality optical spectra of these objects in distant galaxies, enabling the study not only of these stars in different environments, but also to use them as tools to probe their host galaxies. Quantitative analysis of their optical spectra provide tight constraints on their evolution in a wide range of metallicities, as well as on the present-day chemical composition, extinction laws and distances to their host galaxies. We review in this contribution recent results in this field.

Metal acetylacetonates: Interpretation of infrared spectra and new evidence for ligand field effects

1967 ◽  
Vol 3 (2) ◽  
pp. 51-55 ◽  
Author(s):  
R.D. Hancock ◽  
H.W. Sacks ◽  
Rosemary Thornton ◽  
David A. Thornton
Keyword(s):  
Infrared Spectra ◽  
Ligand Field ◽  
Metal Acetylacetonates ◽  
Field Effects ◽  
New Evidence

Ligand field effects on the transport of 3d metal ions across a bulk liquid membrane by lipophilic tetraamine carriers

1986 ◽  
Vol 25 (22) ◽  
pp. 3984-3987 ◽  
Author(s):  
Michela Di Casa ◽  
Luigi Fabbrizzi ◽  
Angelo Perotti ◽  
Antonio Poggi ◽  
Renato Riscassi
Keyword(s):  
Metal Ions ◽  
Liquid Membrane ◽  
Bulk Liquid ◽  
Ligand Field ◽  
Bulk Liquid Membrane ◽  
Field Effects
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