Hydrogen-Bonding-Mediated Molecular Vibrational Suppression for Enhancing the Fluorescence Quantum Yield Applicable for Visual Phenol Detection

2021 ◽  
Author(s):  
Bo-Hyun Kim ◽  
Wontae Kim ◽  
Taemin Kim ◽  
Byoung Min Ko ◽  
Soon-Jik Hong ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Quantum Yield ◽  
Fluorescence Quantum Yield ◽  
Phenol Detection

scholarly journals Synthesis of carbon nitride oligomer as a precursor of melon with improved fluorescence quantum yield

2021 ◽  
Vol 2 (18) ◽  
pp. 6083-6093
Author(s):  
Yuto Miyake ◽  
Goichiro Seo ◽  
Kotaro Matsuhashi ◽  
Noriyuki Takada ◽  
Kaname Kanai
Keyword(s):  
Optical Properties ◽  
Quantum Yield ◽  
Fluorescence Quantum Yield ◽  
Carbon Nitride

Melem tetramer, the newly synthesized carbon nitride compound is composed of oligomers with four melem units, is stable in air, and has improved optical properties compared to melon.

UV-Trained and Metal-Enhanced Fluorescence of Biliverdin and Biliverdin Nanoparticles

Nanoscale ◽  
2021 ◽  
Author(s):  
Parinaz Fathi ◽  
Ayman Roslend ◽  
Kritika Mehta ◽  
Parikshit Moitra ◽  
Kai Zhang ◽  
...  
Keyword(s):  
Quantum Yield ◽  
Fluorescence Quantum Yield ◽  
Biomedical Imaging ◽  
Enhanced Fluorescence ◽  
Metal Enhanced Fluorescence

Increasing the fluorescence quantum yield of fluorophores is of great interest for in vitro and in vivo biomedical imaging applications. At the same time, photobleaching and photodegradation resulting from continuous...

Internal Conversion with 3,5-Dimethyl-4-(methylamino)benzonitrile in Alkane Solvents

2000 ◽  
Vol 214 (11) ◽  
Author(s):  
I. Rückert ◽  
A. Hebecker ◽  
A.B.J. Parusel ◽  
K.A. Zachariasse
Keyword(s):  
Quantum Yield ◽  
Fluorescence Quantum Yield ◽  
Internal Conversion ◽  
Alkane Solvents

With 3,5-dimethyl-4-(methylamino)benzonitrile (MHD) in n-hexane and n-hexadecane at 25°C, relatively small values are obtained for the fluorescence quantum yield Φ

Dramatic reduction in fluorescence quantum yield in mutants of Green Fluorescent Protein due to fast internal conversion

1998 ◽  
Vol 237 (1-2) ◽  
pp. 183-193 ◽  
Author(s):  
Andreas D Kummer ◽  
Christian Kompa ◽  
Harald Lossau ◽  
Florian Pöllinger-Dammer ◽  
Maria E Michel-Beyerle ◽  
...  
Keyword(s):  
Green Fluorescent Protein ◽  
Quantum Yield ◽  
Fluorescence Quantum Yield ◽  
Internal Conversion ◽  
Fluorescent Protein ◽  
Dramatic Reduction ◽  
Green Fluorescent

New soluble 4-(4-formyl-2,6-dimethoxyphenoxy) substituted phthalocyanines: Synthesis, characterization, photophysical and photochemical properties

2021 ◽  
pp. 1-10
Author(s):  
Ibrahim Erden ◽  
Betül Karadoğan ◽  
Fatma Aytan Kılıçarslan ◽  
Göknur Yaşa Atmaca ◽  
Ali Erdoğmuş
Keyword(s):  
Quantum Yield ◽  
Singlet Oxygen ◽  
Fluorescence Quantum Yield ◽  
Metal Ion ◽  
Mass Spectra ◽  
Quantum Yields ◽  
Therapeutic Outcomes ◽  
Ft Ir ◽  
Photochemical Properties ◽  
New Compounds

This work describes the synthesis, spectral and fluorescence properties of bis 4-(4-formyl-2,6-dimethoxyphenoxy) substituted zinc (ZnPc) and magnesium (MgPc) phthalocyanines. The new compounds have been characterized by elemental analysis, UV-Vis, FT-IR, 1H-NMR and mass spectra. Afterward, the effects of including metal ion on the photophysicochemical properties of the complexes were studied in biocompatible solvent DMSO to analyze their potential to use as a photosensitizer in photodynamic therapy (PDT). The fluorescence and singlet oxygen quantum yields were calculated as 0.04–0.15 and 0.70–0.52 for ZnPc and MgPc, respectively. According to the results, MgPc has higher fluorescence quantum yield than ZnPc, while ZnPc has higher singlet oxygen quantum yield than MgPc. The results show that the synthesized complexes can have therapeutic outcomes for cancer treatment.

Enhancement of Fluorescence in Colloidal CuInS2 Nanocrystals by Introduction of Crystal Defect

2009 ◽  
Vol 1176 ◽  
Author(s):  
Masato Uehara ◽  
Kosuke Watanabe ◽  
Yasuyuki Tajiri ◽  
Hiroyuki Nakamura ◽  
Hideaki Maeda
Keyword(s):  
Phase Separation ◽  
Quantum Yield ◽  
Metal Complexes ◽  
Fluorescence Intensity ◽  
Fluorescence Quantum Yield ◽  
Bulk Material ◽  
Crystal Defects ◽  
Crystal Defect ◽  
Cu Deficiency ◽  
Cuins2 Nanocrystals

AbstractCu-In-S nanocrystals were developed as a low toxic fluorescent. The stoichiometric CuInS2 nanocrystals were synthesized facilely by heating a solution of metal complexes. The fluorescence would be originated from the crystal defect. We intentionally introduced the crystal defects related to Cu deficiency in nanocrystal with the prospect that the fluorescence intensity would be increased. The nanocrystals have many defects without phase separation as observed in bulk material. Consequently, the fluorescence quantum yield achieved to c.a. 6%. Moreover, the fluorescence quantum yield was increased up to 15% by the ZnS-coating.

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