Single-Molecule Magnets of Ferrous Cubes:  Structurally Controlled Magnetic Anisotropy

2004 ◽  
Vol 126 (28) ◽  
pp. 8805-8812 ◽  
Author(s):  
Hiroki Oshio ◽  
Norihisa Hoshino ◽  
Tasuku Ito ◽  
Motohiro Nakano
Keyword(s):  
Magnetic Anisotropy ◽  
Single Molecule ◽  
Single Molecule Magnets

Magnetic anisotropy on demand exploiting high-pressure as remote control: an ab initio proof-of-concept

2021 ◽  
Author(s):  
Matteo Briganti ◽  
Federico Totti
Keyword(s):  
High Pressure ◽  
High Temperature ◽  
Remote Control ◽  
Magnetic Anisotropy ◽  
Ab Initio ◽  
Single Molecule ◽  
Boiling Temperature ◽  
Proof Of Concept ◽  
Single Molecule Magnets ◽  
On Demand

Lanthanide based single molecule magnets have recently become very promising systems for creating single molecule device working at high temperature (nitrogen boiling temperature). However, the variation of direction of the...

Enhanced energy barriers triggered by magnetic anisotropy modulation via tuning the functional groups on the bridging ligands in Dy2 single-molecule magnets

2018 ◽  
Vol 47 (42) ◽  
pp. 15197-15205 ◽  
Author(s):  
Yaru Qin ◽  
Yu Jing ◽  
Yu Ge ◽  
Wei Liu ◽  
Yahong Li ◽  
...  
Keyword(s):  
Magnetic Anisotropy ◽  
Functional Groups ◽  
Single Molecule ◽  
Energy Barrier ◽  
Energy Barriers ◽  
Single Molecule Magnets ◽  
Bridging Ligands

Two dinuclear dysprosium complexes of 1 and 2 have been synthesized and both of them exhibit SMM behavior. The energy barrier is enhanced ca. 35 K by elaborately tuning the backbones of the ligands.

Electronic control of strong magnetic anisotropy in Co-based single-molecule magnets

2021 ◽  
Vol 104 (13) ◽  
Author(s):  
Zahra Hooshmand ◽  
Jie-Xiang Yu ◽  
Hai-Ping Cheng ◽  
Mark R Pederson
Keyword(s):  
Magnetic Anisotropy ◽  
Single Molecule ◽  
Electronic Control ◽  
Single Molecule Magnets

Three tetracoordinate Co(ii) complexes [Co(biq)X2] (X = Cl, Br, I) with easy-plane magnetic anisotropy as field-induced single-molecule magnets

2015 ◽  
Vol 44 (40) ◽  
pp. 17565-17571 ◽  
Author(s):  
L. Smolko ◽  
J. Černák ◽  
M. Dušek ◽  
J. Miklovič ◽  
J. Titiš ◽  
...  
Keyword(s):  
External Field ◽  
Magnetic Anisotropy ◽  
Single Molecule ◽  
Easy Plane ◽  
Single Molecule Magnets ◽  
Mononuclear Complexes ◽  
Superparamagnetic Behaviour

Three mononuclear complexes [CoII(biq)X2] (biq = 2,2′-biquinoline; X = Cl, Br, I) possess a sizable magnetic anisotropy, and they display a superparamagnetic behaviour in an applied external field that culminates between BDC = 0.2–0.3 T.

Structural correlations between the crystal field and magnetic anisotropy of Ln–Cu single-molecule magnets

CrystEngComm ◽  
2009 ◽  
Vol 11 (10) ◽  
pp. 2110 ◽  
Author(s):  
Takashi Kajiwara ◽  
Kohei Takahashi ◽  
Tomonari Hiraizumi ◽  
Shinya Takaishi ◽  
Masahiro Yamashita
Keyword(s):  
Magnetic Anisotropy ◽  
Crystal Field ◽  
Single Molecule ◽  
Single Molecule Magnets

A ligand-field study of the ground spin-state magnetic anisotropy in a family of hexanuclear Mn(iii) single-molecule magnets

2008 ◽  
pp. 2277 ◽  
Author(s):  
Stergios Piligkos ◽  
Jesper Bendix ◽  
Høgni Weihe ◽  
Constantinos J. Milios ◽  
Euan K. Brechin
Keyword(s):  
Magnetic Anisotropy ◽  
Field Study ◽  
Spin State ◽  
Single Molecule ◽  
Ligand Field ◽  
Single Molecule Magnets ◽  
Ground Spin State
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