Pulsed Laser Ablation Induced Fragmentation, Transformation, Internal Stress, Sn2+/H+ Cosignature, and Optical Property Change of SnO2 Powders in Water

2011 ◽  
Vol 115 (50) ◽  
pp. 24577-24585 ◽  
Author(s):  
Hui-Di Lu ◽  
Bo-Cheng Lin ◽  
Shuei-Yuan Chen ◽  
Pouyan Shen
1997 ◽  
Vol 498 ◽  
Author(s):  
Q. Wei ◽  
R. J. Narayan ◽  
A. K. Sharma ◽  
J. Sankar ◽  
J. Narayan

ABSTRACTWe have investigated the effect of dopants on the reduction of internal compressive stress in diamond-like carbon (DLC) films prepared by pulsed laser deposition on Si(100) substrates. A novel target configuration was used to incorporate dopants into DLC films by sequential pulsed laser ablation of two targets. These dopants include copper, titanium and silicon. The thickness of the DLC films deposited was measured in the range 400nm - 600nm using a profilometer. Raman spectroscopy was employed to analyze the chemistry of the films. The shifts of the G-peak position in the Raman spectrum, due to different concentrations of dopant, were used to estimate the internal stress changes. All of the films showed a Raman spectrum typical of DLC films containing a high fraction of sp3 species, with the G-peak centered at around 1510–1560cm−1. The shift of the G-peak due to the presence of dopants was observed for all the DLC films as compared to the undoped one. It was found that Ti has the strongest tendency to reduce the compressive stress of DLC films. This effect increases with increasing concentration of dopants. Silicon was also observed to have this effect, but the G-peak position did not appear to shift with different Si concentrations. Buckling occurred in the as-deposited, undoped DLC film because of the relief of the large compressive stress accumulated in the film, while all the doped DLC films showed good adhesion to the substrate. The results are discussed combining the atomic structure of DLC and the structure and properties of the dopants.


2009 ◽  
Vol 70 (12) ◽  
pp. 1505-1510 ◽  
Author(s):  
C.H. Lin ◽  
S.Y. Chen ◽  
N.J. Ho ◽  
D. Gan ◽  
P. Shen

Author(s):  
M. Grant Norton ◽  
C. Barry Carter

Pulsed-laser ablation has been widely used to produce high-quality thin films of YBa2Cu3O7-δ on a range of substrate materials. The nonequilibrium nature of the process allows congruent deposition of oxides with complex stoichiometrics. In the high power density regime produced by the UV excimer lasers the ablated species includes a mixture of neutral atoms, molecules and ions. All these species play an important role in thin-film deposition. However, changes in the deposition parameters have been shown to affect the microstructure of thin YBa2Cu3O7-δ films. The formation of metastable configurations is possible because at the low substrate temperatures used, only shortrange rearrangement on the substrate surface can occur. The parameters associated directly with the laser ablation process, those determining the nature of the process, e g. thermal or nonthermal volatilization, have been classified as ‘primary parameters'. Other parameters may also affect the microstructure of the thin film. In this paper, the effects of these ‘secondary parameters' on the microstructure of YBa2Cu3O7-δ films will be discussed. Examples of 'secondary parameters' include the substrate temperature and the oxygen partial pressure during deposition.


2019 ◽  
Vol 1 (10) ◽  
pp. 3963-3972 ◽  
Author(s):  
Arsène Chemin ◽  
Julien Lam ◽  
Gaétan Laurens ◽  
Florian Trichard ◽  
Vincent Motto-Ros ◽  
...  

While doping is crucial for numerous technological applications, its control remains difficult especially when the material is reduced down to the nanometric scale. We suggest a new way to dope nanoparticles using laser ablation in liquids.


2021 ◽  
pp. 103317
Author(s):  
Muidh Alheshibri ◽  
Sultan Akhtar ◽  
Abbad Al Baroot ◽  
Khaled Elsayed ◽  
Hassan S Al Qahtani ◽  
...  

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