Janus building block-enabled fabrication of dual metal equipped coordination polymers: an ideal precursor for noble metal/metal oxide nanocomposites with excellent catalytic performance

2015 ◽  
Vol 3 (40) ◽  
pp. 20073-20079 ◽  
Author(s):  
Fang Cui ◽  
Qing Shao ◽  
Tieyu Cui ◽  
Linxu Xu ◽  
Tongjie Yao ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Metal Oxide ◽  
Metal Ions ◽  
Noble Metal ◽  
Coordination Polymers ◽  
Building Block ◽  
Catalytic Performance ◽  
Metal Metal ◽  
Dual Metal ◽  
Excellent Catalytic Performance

Coordination polymer nanoribbons equipped with dual metal ions are fabricated by using a Janus building block.

Directed self-assembly of dual metal ions with ligands: towards the synthesis of noble metal/metal oxide composites with controlled facets

2018 ◽  
Vol 54 (16) ◽  
pp. 2044-2047 ◽  
Author(s):  
Fang Cui ◽  
Jiajia Zhang ◽  
Qing Shao ◽  
Linxu Xu ◽  
Xinzi Pan ◽  
...  
Keyword(s):  
Metal Oxide ◽  
Metal Ions ◽  
Noble Metal ◽  
Self Assembly ◽  
Large Scale ◽  
Assembly Strategy ◽  
Metal Metal ◽  
Exposed Facet ◽  
Dual Metal ◽  
Oxide Composites

Despite numerous reports on noble metal/metal oxide composites, the control of the exposed facet is still a great challenge. Here, the large-scale synthesis of noble metal/metal oxide spheres with controlled facets is enabled by making use of a bottom-up self-assembly strategy.

The development of novel Au/CaO nanoribbons from bifunctional building block for biodiesel production

Nanoscale ◽  
2017 ◽  
Vol 9 (41) ◽  
pp. 15990-15997 ◽  
Author(s):  
Jiajia Zhang ◽  
Fang Cui ◽  
Linxu Xu ◽  
Xinzi Pan ◽  
Xiaoqiang Wang ◽  
...  
Keyword(s):  
Metal Nanoparticles ◽  
Uniform Distribution ◽  
Building Block ◽  
Catalytic Performance ◽  
Transesterification Reaction ◽  
Biodiesel Production ◽  
Dual Metal ◽  
Excellent Catalytic Performance

Au/CaO nanoribbons with uniform distribution of dual metal nanoparticles were fabricated, which exhibited excellent catalytic performance in the transesterification reaction.

Reusability of metals/metal oxide coupled zinc oxide nanorods in degradation of rhodamine B dye

2020 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Anh Thi Le ◽  
Swee-Yong Pung
Keyword(s):  
Metal Oxide ◽  
Metal Ions ◽  
Rhodamine B ◽  
Zno Nanorods ◽  
Zinc Oxide Nanorods ◽  
Uv Exposure ◽  
Precipitation Method ◽  
Subsequent Stage ◽  
Content Type ◽  
Metal Metal

Purpose This paper aims to investigate the reusability of metal/metal oxide-coupled ZnO nanorods (ZnO NRs) to degrade rhodamine B (RhB). Design/methodology/approach ZnO NRs particles were synthesized by precipitation method and used to remove various types of metal ions such as Cu2+, Ag+, Mn2+, Ni2+, Pb2+, Cd2+ and Cr2+ ions under UV illumination. The metal/metal oxide-coupled ZnO NRs were characterized by scanning electron microscope, X-ray diffraction and UV-Vis diffuse reflectance. The photodegradation of RhB dye by these metal/metal oxide-coupled ZnO NRs under UV exposure was assessed. Findings The metal/metal oxide-coupled ZnO NRs were successfully reused to remove RhB dye in which more than >90% of RhB dye was degraded under UV exposure. Furthermore, the coupling of Ag, CuO, MnO2, Cd and Ni particles onto the surface of ZnO NRs even enhanced the degradation of dye. The dominant reactive species involved in the degradation of RhB dye were •OH- and •O2−-free radicals. Research limitations/implications The coupling of metal/metal oxide onto the surface of ZnO NRs after metal ions removal could affect the photocatalytic performance of ZnO NRs in the degradation of organic pollutants in subsequent stage. Practical implications A good reusability performance of metal/metal oxide-coupled ZnO NRs make ZnO NRs become a desirable photocatalyst material for the treatment of wastewater, which consists of both heavy metal ions and organic dyes. Originality/value Metal/metal oxide coupling onto the surface of ZnO NRs particles improved subsequent UV-assisted photocatalytic degradation of RhB dye.

scholarly journals Surface modification of plasmonic noble metal–metal oxide core–shell nanoparticles

2019 ◽  
Vol 1 (12) ◽  
pp. 4578-4591 ◽  
Author(s):  
Somayeh Talebzadeh ◽  
Clémence Queffélec ◽  
D. Andrew Knight
Keyword(s):  
Surface Modification ◽  
Metal Oxide ◽  
Noble Metal ◽  
Molecular Ions ◽  
Core Shell ◽  
Shell Nanoparticles ◽  
Metal Metal ◽  
Comprehensive Survey ◽  
Core Shell Nanoparticles

A comprehensive survey on methods for surface modification of noble metal–metal oxide core–shell nanoparticles is presented and highlights various strategies for binding of molecules and molecular ions to core–shell nanoparticles.

The mechanochemical conversion of potassium coordination polymer nanostructures to interpenetrated sodium coordination polymers with halogen bond, metal–carbon and metal–metal interactions

CrystEngComm ◽  
2020 ◽  
Vol 22 (5) ◽  
pp. 888-894 ◽  
Author(s):  
Ashkan Kianimehr ◽  
Kamran Akhbari ◽  
Jonathan White ◽  
Anukorn Phuruangrat
Keyword(s):  
Hydrogen Bonding ◽  
Solid State ◽  
Coordination Polymer ◽  
Coordination Polymers ◽  
Halogen Bond ◽  
Metal Interactions ◽  
Polymer Nanostructures ◽  
Hydrogen Bonding Interactions ◽  
Metal Metal

Two new Na and K coordination polymers with halogen bond, metallophilic and hydrogen bonding interactions were synthesized. These two compounds were synthesized sonochemically and solid-state conversions of them to each other were investigated.

Two novel lanthanide (Nd, Gd) coordination polymers with chromate anion as building block of the 2D metal oxide

2006 ◽  
Vol 9 (12) ◽  
pp. 1187-1190 ◽  
Author(s):  
Jiu-Hui Liu ◽  
Xiao-Yuan Wu ◽  
Quan-Zheng Zheng ◽  
Xiang He ◽  
Wen-Bin Yang ◽  
...  
Keyword(s):  
Metal Oxide ◽  
Coordination Polymers ◽  
Building Block ◽  
Chromate Anion

scholarly journals Nanoplasmon–Semiconductor Hybrid for Interface Catalysis

Catalysts ◽  
2018 ◽  
Vol 8 (10) ◽  
pp. 429 ◽  
Author(s):  
Jingang Wang ◽  
Naixing Feng ◽  
Ying Sun ◽  
Xijiao Mu
Keyword(s):  
Optical Properties ◽  
Metal Oxide ◽  
Noble Metal ◽  
Hybrid System ◽  
Physical Mechanism ◽  
Theoretical Calculations ◽  
Experimental Investigations ◽  
Exciton Coupling ◽  
Surface Catalysis ◽  
Metal Metal

We firstly, in this review, introduce the optical properties of plasmonic metals, and then focus on introducing the unique optical properties of the noble metal–metal-oxide hybrid system by revealing the physical mechanism of plasmon–exciton interaction, which was confirmed by theoretical calculations and experimental investigations. With this noble metal–metal-oxide hybrid system, plasmonic nanostructure–semiconductor exciton coupling interactions for interface catalysis has been analyzed in detail. This review can provide a deeper understanding of the physical mechanism of exciton–plasmon interactions in surface catalysis reactions.

SERS Application of Noble Metal–Metal Oxide Hybrid Nanoparticles

2019 ◽  
pp. 457-486 ◽  
Author(s):  
Vipul Sharma ◽  
Ramachandran Balaji ◽  
Nisha Kumari ◽  
Venkata Krishnan
Keyword(s):  
Metal Oxide ◽  
Noble Metal ◽  
Hybrid Nanoparticles ◽  
Metal Metal

scholarly journals Synthesis, Crystal Structure, and Luminescence of Cadmium(II) and Silver(I) Coordination Polymers Based on 1,3-Bis(1,2,4-triazol-1-yl)adamantane

Molecules ◽  
2021 ◽  
Vol 26 (17) ◽  
pp. 5400
Author(s):  
Roman D. Marchenko ◽  
Taisiya S. Sukhikh ◽  
Alexey A. Ryadun ◽  
Andrei S. Potapov
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Metal Ions ◽  
Single Crystal ◽  
Diffraction Analysis ◽  
Coordination Polymers ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray

Coordination polymers with a new rigid ligand 1,3-bis(1,2,4-triazol-1-yl)adamantane (L) were prepared by its reaction with cadmium(II) or silver(I) nitrates. Crystal structure of the coordination polymers was determined using single-crystal X-ray diffraction analysis. Silver formed two-dimensional coordination polymer [Ag(L)NO3]n, in which metal ions are linked by 1,3-bis(1,2,4-triazol-1-yl)adamantane ligands, coordinated by nitrogen atoms at positions 2 and 4 of 1,2,4-triazole rings. Layers of the coordination polymer consist of rare 18- and 30-membered {Ag2L2} and {Ag4L4} metallocycles. Cadmium(II) nitrate formed two kinds of one-dimensional coordination polymers depending on the metal-to-ligand ratio used in the synthesis. Coordination polymer [Cd(L)2(NO3)2]n was obtained in case of a 1:2 M:L ratio, while for M:L = 2:1 product {[Cd(L)(NO3)2(CH3OH)]·0.5CH3OH}n was isolated. All coordination polymers demonstrated ligand-centered emission near 450 nm upon excitation at 370 nm.

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