ESTIMATION OF CATION-EXCHANGE CAPACITY AND EXCHANGEABLE Ca, K, AND Na CONTENTS OF SOILS BY FLAME PHOTOMETER TECHNIQUES

Soil Science ◽  
1949 ◽  
Vol 67 (6) ◽  
pp. 439-446 ◽  
Author(s):  
S. J. TOTH ◽  
A. L. PRINCE
Keyword(s):  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Exchange Capacity ◽  
Flame Photometer ◽  
Exchangeable Ca

WHEAT YIELDS AND CHANGE IN CATIONS AFTER LEACHING SOIL WITH WATER CONTAINING INCREASING RATES OF POTASSIUM REFINERY DUST

1971 ◽  
Vol 51 (3) ◽  
pp. 405-410
Author(s):  
A. K. Ballantyne
Keyword(s):  
Adverse Effects ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Exchange Capacity ◽  
Silt Loam ◽  
Exchangeable K ◽  
Silt Loam Soil ◽  
Exchangeable Ca ◽  
Loam Soil ◽  
Soil Cation Exchange Capacity

Leaching a silt loam soil (cation exchange capacity 23 meq/100 g) with water containing increasing rates of potassium dust (KCl) indicated that high levels adversely affected germination and yields of wheat as well as response to fertilizer. Germination was greatly reduced by the treatment with 22.4 metric tons per hectare and nearly eliminated by 44.8 tons. The 44.8-ton/ha treatment also greatly reduced the yield of grain, but straw weights were affected very little by increasing rates of potassium dust. Response to fertilizer was also reduced by 22.4 and 44.8 tons. The exchangeable Ca and Mg decreased and K increased as increasing amounts of K dust were leached through the soil. The 44.8-ton treatment decreased the exchangeable Ca from 56.0 to 24.9% and the Mg from 21.2 to 4.9%, and increased the K from 7.2 to 51.9%. It would appear that K salts can be added to the soil, without any adverse effects, until the exchangeable K is increased to about 30%. With the soil under study this took more than 11.2 tons per ha (5 short tons/acre). The application of dolomite ameliorated the effect of excess K.

Radial variations in cation exchange capacity and base saturation rate in the wood of pedunculate oak and European beech

2002 ◽  
Vol 32 (10) ◽  
pp. 1829-1837 ◽  
Author(s):  
J Herbauts ◽  
V Penninckx ◽  
W Gruber ◽  
P Meerts
Keyword(s):  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
European Beech ◽  
Base Cation ◽  
Exchange Capacity ◽  
Water Soluble ◽  
Soluble Form ◽  
Pedunculate Oak ◽  
Exchangeable Ca ◽  
Saturation Rate

In a mixed forest stand on an ochreous brown earth in the Belgian Ardennes, pedunculate oak (Quercus robur L.) and European beech (Fagus sylvatica L.) have outwardly decreasing cation concentration profiles in wood. To test if these profiles can be ascribed to endogenous factors or to decreased availability of cations in the soil, radial profiles of water-soluble, exchangeable, and total cations and of cation exchange capacity (CEC) of wood were determined. In both species, [Formula: see text]75% of K is in the water-soluble form so is of little use for dendrochemical monitoring. About 80% of Mg is adsorbed on wood exchange sites. For Ca, 30 (beech) to 60% (oak) of total content cannot be extracted by SrCl2 and is, thus, relatively immobile in wood. Wood CEC decreases from pith to bark in European beech and from pith to outer heartwood in pedunculate oak. Decreasing profiles of exchangeable Ca and Mg in pedunculate oak and exchangeable Ca in European beech are strongly constrained by CEC and, thus, are not related to environmental change. Base cation saturation rate shows no consistent radial change in either species. European beech maintained much higher base cation saturation rate than pedunculate oak, although both species had similar CEC. In conclusion, the results do not provide convincing evidence for a significant change in nutritional status of pedunculate oak and European beech in the Belgian Ardennes due to atmospheric pollution.

scholarly journals Number of extractionsin determination of effective cation-exchange capacity

1986 ◽  
Vol 58 (2) ◽  
pp. 47-51
Author(s):  
Raina Niskanen
Keyword(s):  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Exchange Capacity ◽  
Degree Of Saturation ◽  
Virgin Soil ◽  
Exchangeable Acidity ◽  
Exchangeable Ca ◽  
Mineral Soils ◽  
High Degree ◽  
Cultivated Soils

The number of successive extractions with 1 M KCI needed for adequate estimation of effective cation-exchange capacity was studied with four mineral soils. The effective CEC estimated as the sum of equivalents of exchangeable Ca, Mg, Na, H and Al extracted by four successive treatments ranged from 57 to 206 meq/kg soil. In three cultivated soils, 63—90 % of CEC was saturated by Ca and Mg, in the fourth soil (a deeper layer virgin soil), 60 % of CEC by exchangeable H and Al. By two successive treatments often minutes duration with 50ml of 1 M KCI, the equivalent sum of exchangeable cations extracted amounted to 83—92 % of effective CEC in cultivated soils and 67 % of that in virgin soil; >90 % of exchangeable Ca and Mg, 78—97 % of Al, 48—62 % of H and 28—64 % of Na were extracted. By three successive treatments the equivalent sum amounted to 79—96 % of effective CEC, by the single treatment of 30 minutes duration with 100ml of 1 M KCI to 57—79 %. Two successive extractions with 1 M KCI may be enough for estimation of effective CEC in cultivated mineral soils with high degree of saturation by exchangeable Ca and Mg. Soils with high degree of saturation by exchangeable acidity require three successive extractions.

scholarly journals Estimation of cation-exchange capacity in routine soil testing

1986 ◽  
Vol 58 (1) ◽  
pp. 1-7
Author(s):  
Raina Niskanen ◽  
Antti Jaakkola
Keyword(s):  
Organic Carbon ◽  
Cation Exchange ◽  
Carbon Content ◽  
Cation Exchange Capacity ◽  
Ammonium Acetate ◽  
Exchange Capacity ◽  
Regression Equation ◽  
Soil Testing ◽  
Organic Carbon Content ◽  
Exchangeable Ca

The efficiency of the soil testing method used in Finland for predicting the effective cation-exchange capacity was studied in a material of 430 topsoil samples. The effective cation-exchange capacity was estimated 1) by summation of exchangeable Ca, Mg and acidity displaced by unbuffered 1 M KCI and 2) by summation of exchangeable Ca, Mg, K and Na displaced by neutral 1 M ammonium acetate and exchangeable acidity. In soil testing, Ca, Mg and K were extracted by acid ammonium acetate and soil pH measured in water-suspension. The estimates of the effective CEC were highly correlated and dependent on the clay and organic carbon content and pH(CaCl2) of the soil, the coefficient of multiple determination being over 80 %. Exchangeable Ca was the dominating cation. The proportion of Ca of the effective CEC was about 80 %. Acid ammonium acetate-extractable Ca together with pH(H2O) explained over 80 % of the variation in the effective CEC. For the whole material consisting of mineral soils with great variations in texture, organic carbon content and properties under evaluation, the regression equation predicting the effective CEC (KCI method) was CEC (mval/kg) = 309—56.8pH(H2O) + 0.085Ca(mg/l). Only 16 % of the estimates of the effective CEC calculated with this regression equation deviated more than 15 % from the measured values.

Impacts of whole-tree harvesting and winter windrowing on soil pH and base status of clayey sites of northwestern Quebec

1995 ◽  
Vol 25 (6) ◽  
pp. 997-1007 ◽  
Author(s):  
S. Brais ◽  
C. Camiré ◽  
D. Paré
Keyword(s):  
Cation Exchange ◽  
Soil Ph ◽  
Forest Floor ◽  
Cation Exchange Capacity ◽  
Exchange Capacity ◽  
Exchangeable Ca ◽  
Whole Tree Harvesting ◽  
The Impact ◽  
Whole Tree ◽  
Tree Harvesting

To assess the impact of forest operations on soil nutrient status, modifications to forest floor, to 0–10 and 10–20 cm mineral soil base status, and to pH were evaluated 5–12 years following whole-tree harvesting and winter windrowing on dry to fresh and moist clayey sites in the clay belt region of northwestern Quebec. Whole-tree harvesting had few impacts on base concentrations and soil pH of dry to fresh sites. On moist sites, significant decreases in pH (−0.60 to −0.84 units), exchangeable Ca, total Ca, and, exchangeable Mg concentrations, base saturation, and effective cation exchange capacity were observed following harvesting. On dry to fresh sites, a decrease in the forest floor weight (−55%) accounted for significant reductions in exchangeable Ca (−55%), total Ca (−61%), and exchangeable K (−40%) pools in this layer, while reserves of both mineral layers were not affected. On moist sites, significant decreases in exchangeable Ca (−42 to −65%) and Mg (−35 to −56%) reserves occurred in all soil layers, while forest floor reserves of total Ca, Mg, and K decreased by 67, 48, and 40%, respectively. These reductions were caused by a loss of substrate in the forest floor (−44%) and a decrease in effective cation exchange capacity, exchangeable Ca saturation, and total Ca concentrations. Impacts of windrowing following whole-tree harvesting were limited to a reduction in reserves of exchangeable Ca (−22%), exchangeable Mg (−27%), total Ca (−20%), and total Mg (−29%) pools of the forest floor of moist sites. Values reported here are much greater than values generally predicted by a balance sheet approach and underline the need for more process-oriented studies. Impacts of these losses on long-term site productivity remain to be investigated.

HIGH SOIL CALCIUM SATURATION LIMITS USE OF LEAF POTASSIUM DIAGNOSIS WHEN KCL IS APPLIED IN OIL PALM PLANTATIONS

2017 ◽  
Vol 54 (5) ◽  
pp. 794-804
Author(s):  
BERNARD DUBOS ◽  
VICTOR BARON ◽  
XAVIER BONNEAU ◽  
ALBERT FLORI ◽  
JEAN OLLIVIER
Keyword(s):  
Soil Properties ◽  
Cation Exchange ◽  
Oil Palm ◽  
Cation Exchange Capacity ◽  
Positive Response ◽  
Elaeis Guineensis ◽  
Exchange Capacity ◽  
Yield Response ◽  
Soil Calcium ◽  
Exchangeable Ca

SUMMARYPotassium chloride (KCl) is the most widely used fertilizer in oil palm (Elaeis guineensis) plantations and the rates applied are based on interpretation of leaf K contents. When no positive response on leaf K contents can be detected, no optimum content can be established whatever the yield response to KCl rates. We used data from 13 fertilization trials conducted on several continents to study the responses of leaf K, leaf Cl, leaf Ca and yield to KCl rates as a function of the soil properties of each site. We found that the abundance of exchangeable Ca in the soil expressed as a percent of the cation exchange capacity (CEC) was the best soil variable to predict if leaf K content would increase with KCl rates. In addition, we found that the leaf K contents of unfertilized controls at the end of the trials were also correlated with Ca/CEC. This ratio thus appears to be a better index of soil K reserves than soil exchangeable K content.

Chemical and mineral composition of ectomycorrhizosphere soils of subalpine fir (Abieslasiocarpa (Hook.) Nutt.) in the Ae horizon of a Luvisol

1999 ◽  
Vol 79 (1) ◽  
pp. 25-35 ◽  
Author(s):  
J. M. Arocena ◽  
K. R. Glowa ◽  
H. B. Massicotte ◽  
L. Lavkulich
Keyword(s):  
Cation Exchange ◽  
Soil Ph ◽  
Cation Exchange Capacity ◽  
Amorphous Materials ◽  
Exchange Capacity ◽  
Transformation Rate ◽  
Subalpine Fir ◽  
Exchangeable Ca ◽  
Ectomycorrhizal Colonization ◽  
C And N

Differences in the properties of bulk forest and rhizosphere soils are often attributed to ectomycorrhizal association, or the symbiosis characterized by a fungal sheath surrounding the root (mantle) and intercellular root colonization (Hartig net). We compared the soil pH, total C, N, cation exchange capacity, and the contents of mica, chlorite, kaolinite, 2:1 expandable clays, feldspars and amorphous materials between two ectomycorrhizosphere soils (or soil environment in the vicinity of ectomycorrhizae (ECM)) and non-ectomycorrhizosphere soils to study the influence of ectomycorrhizae on chemical and mineralogical properties of soils. The two ectomycorrhizosphere soils were characterized by ectomycorrhizal colonization dominated by (1) Piloderma spp., and (2) Mycelium radicis atrovirensand cottony yellow-brown (MRA-CYB) types or where Piloderma spp. colonization was <2%. Our results showed that total C and N were higher in ectomycorrhizosphere than non-ectomycorrhizosphere soils, and the ectomycorrhizosphere soils dominated by Piloderma spp. had almost twice the total C and N as ectomycorrhizosphere soils with MRA-CYB. Soil pH was lower by half a pH unit in ectomycorrhizosphere soils compared to non-ectomycorrhizosphere soils. Cation exchange capacity as well as exchangeable Ca2+, Mg2+ and K+ were lower in non-ectomycorrhizosphere soil compared to ectomycorrhizosphere soils. We also found that cation exchange capacity, exchangeable Ca2+, Mg2+ and K+ values in soils dominated by Piloderma spp. were higher compared to ectomycorrhizosphere soils with insignificant Piloderma spp. Our results suggest that transformation rate of mica and chlorite to 2:1 expandable clays was predominant in ectomycorrhizosphere compared to non-ectomycorrhizosphere soils, likely as a result of high production of organic acids and direct extraction of K+ and Mg2+ by fungal hyphae. In ectomycorrhizoplane samples, it is suggested that K+ and possibly amorphous Al2O3 and Fe2O3 could reconstitute the degraded mica and chlorite through the formation of hydroxy-interlayered 2:1 clays. Key words: Ectomycorrhizosphere soils, subalpine fir, Piloderma spp.

scholarly journals Comparison of and correlation between the characteristics of agricultural topsoil and subsoil at the southern coast of Finland

1984 ◽  
Vol 56 (4) ◽  
pp. 245-254
Author(s):  
Raili Jokinen
Keyword(s):  
Particle Size ◽  
Particle Size Distribution ◽  
Cation Exchange ◽  
Size Distribution ◽  
Cation Exchange Capacity ◽  
Exchange Capacity ◽  
Minor Effect ◽  
Organic C ◽  
Exchangeable Ca ◽  
Exchange Acidity

Topsoil and subsoil samples were taken at 382 sites from the agricultural area of Viikki Experimental Farm, University of Helsinki. The samples were determinated for particle size distribution, pH(CaCl2), organic C %, at pH 7 exchangeable Ca, Mg and K, effective cation exchange capacity (ECEC), exchange acidity (AI + H) and plant available (Bray 1) P. The differences between topsoil and subsoil were studied taking into consideration the fertilization and liming during the past ten years before sampling. The correlations between soil characteristics were also studied. The clay (< 2 µm) and silt (2—20 µm) contents, exchangeable Mg and exchange acidity were lower in the topsoil than in the subsoil; as for the remaining characteristics, the values for topsoil were higher than those for subsoil. The subsoil seemed to be more heterogenic than the topsoil. There was a closer correlation between exchangeable Ca, Mg and K and the clay content in the subsoil than in the topsoil. In Litorina soils, there was a weak correlation between exchangeable cations and clay. It is more difficult to predict the cation contents on the basis of soil particle size distribution in soils cropped intensively, since fertilization and liming have changed the original contents. Vertical movement of applied Ca occurred slightly, possibly because the topsoils were rich in organic C. There was some correlation between organic C and exchangeable Mg or K, indicating a minor effect of organic matter on the leaching of these cations. The plant available P content of the subsoil was about 10 % of that of the topsoil irrespective of the amount of P applied. Clay and organic C contents were the main constituents of effective cation exchange capacity in the topsoil; in the subsoil the significance of clay was greatest.

EVALUASI PERUBAHAN KUALITAS TANAH PADA LAHAN BEKAS PENAMBANGAN NIKEL DI PULAU GEBE

2018 ◽  
Vol 4 (1) ◽  
Author(s):  
Mardi Wibowo
Keyword(s):  
Organic Carbon ◽  
Cation Exchange ◽  
Cation Exchange Capacity ◽  
Exchange Capacity ◽  
Mining Activity ◽  
Evaluation Activity ◽  
Land Quality ◽  
Environment Quality

Since year 1977 until 2005, PT. ANTAM has been exploited nickel ore resources at Gebe Island – Center ofHalmahera District – North Maluku Province. Mining activity, beside give economically advantages also causedegradation of environment quality espicially land quality. Therefore, it need evaluation activity for change ofland quality at Gebe Island after mining activity.From chemical rehabilitation aspect, post mining land and rehabilitation land indacate very lack and lackfertility (base saturated 45,87 – 99,6%; cation exchange capacity 9,43 – 12,43%; Organic Carbon 1,12 –2,31%). From availability of nutrirnt element aspect, post mining land and rehabilitation land indicate verylack and lack fertility (nitrogen 0,1 – 1,19%). Base on that data, it can be concluded that land reclamationactivity not yet achieve standart condition of chemical land.Key words : land quality, post mining lan

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