Quantum electrodynamics with nonrelativistic sources. V. Electromagnetic field correlations and intermolecular interactions between molecules in either ground or excited states

1993 ◽  
Vol 47 (4) ◽  
pp. 2539-2551 ◽  
Author(s):  
E. A. Power ◽  
T. Thirunamachandran
2020 ◽  
pp. 27-33
Author(s):  
Boris A. Veklenko

Without using the perturbation theory, the article demonstrates a possibility of superluminal information-carrying signals in standard quantum electrodynamics using the example of scattering of quantum electromagnetic field by an excited atom.


1951 ◽  
Vol 47 (2) ◽  
pp. 436-442 ◽  
Author(s):  
F. C. Auluck ◽  
L. S. Kothari

The object of the present paper is to discuss the Fourier expansion of the Riesz potential. For this purpose a new definition of the electromagnetic potentials, depending upon an arbitrary parameter α is given. It is shown that this definition is a generalization of the Wentzel potentials in the α-plane, whereas that given by Fremberg (3) is a generalization of the Maxwell potentials. The analysis is applied to the problem of eliminating, in a straightforward way, the longitudinal part of the potential describing the electromagnetic field. The problem of the quantization of the field, based on its Fourier expansion, will be considered in another paper. The recent work of Tomonaga, Schwinger and Dyson, and the regularization process of Pauli has lifted the theory of quantum electrodynamics to a much higher level of rigour and fruitful applicability. All the same, a further study of Riesz potential seems to us of some interest in this field.


2020 ◽  
Vol 22 (40) ◽  
pp. 23295-23306
Author(s):  
Saunak Das ◽  
Johannes Fiedler ◽  
Oliver Stauffert ◽  
Michael Walter ◽  
Stefan Yoshi Buhmann ◽  
...  

Van der Waals potentials determine supramolecular structures of molecules in ground and long-lived electronically excited states. We investigate how macroscopic quantum electrodynamics can be used to efficiently describe such potentials based on (TD)DFT-derived polarizabilities.


The procedure devised by Dirac for the canonical quantization of systems described by degenerate lagrangians is used to construct the hamiltonian for molecules interacting with the electromagnetic field. The hamiltonian obtained is expressed in terms of the gauge invariant field strengths and the electric and magnetic multipole moments of the molecules. The Coulomb gauge is introduced but other gauge conditions could be used. Finally, a physical interpretation of the unitary transformation that may be used to generate the multipole hamiltonian is given.


Physics ◽  
2020 ◽  
Vol 2 (1) ◽  
pp. 14-21 ◽  
Author(s):  
Gerd Leuchs ◽  
Margaret Hawton ◽  
Luis L. Sánchez-Soto

We present a new perspective on the link between quantum electrodynamics (QED) and Maxwell’s equations. We demonstrate that the interpretation of the electric displacement vector D = ε 0 E , where E is the electric field vector and ε 0 is the permittivity of the vacuum, as vacuum polarization is consistent with QED. A free electromagnetic field polarizes the vacuum, but the polarization and magnetization currents cancel giving zero source current. The speed of light is a universal constant, while the fine structure constant, which couples the electromagnetic field to matter runs, as it should.


1996 ◽  
Vol 10 (09) ◽  
pp. 385-391
Author(s):  
AMITABH JOSHI

We consider a new model of cavity quantum electrodynamics consisting of the interaction of a single mode of electromagnetic field with two non-identical two-level atoms undergoing one and two photon transition respectively in an ideal cavity. The exact analytic results for the vacuum Rabi splitting and the dynamical evolution of the model are given.


Symmetry ◽  
2018 ◽  
Vol 10 (7) ◽  
pp. 298 ◽  
Author(s):  
David Andrews

In the wide realm of applications of quantum electrodynamics, a non-covariant formulation of theory is particularly well suited to describing the interactions of light with molecular matter. The robust framework upon which this formulation is built, fully accounting for the intrinsically quantum nature of both light and the molecular states, enables powerful symmetry principles to be applied. With their origins in the fundamental transformation properties of the electromagnetic field, the application of these principles can readily resolve issues concerning the validity of mechanisms, as well as facilitate the identification of conditions for widely ranging forms of linear and nonlinear optics. Considerations of temporal, structural, and tensorial symmetry offer significant additional advantages in correctly registering chiral forms of interaction. More generally, the implementation of symmetry principles can considerably simplify analysis by reducing the number of independent quantities necessary to relate to experimental results to a minimum. In this account, a variety of such principles are drawn out with reference to applications, including recent advances. Connections are established with parity, duality, angular momentum, continuity equations, conservation laws, chirality, and spectroscopic selection rules. Particular attention is paid to the optical interactions of molecules as they are commonly studied, in fluids and randomly organised media.


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