scholarly journals Investigation on the modification to solvent-containing two-component polyurethane coating by carbon nanotubes

2015 ◽  
Vol 44 (5) ◽  
pp. 300-305 ◽  
Author(s):  
X. Jiang ◽  
L. Lin ◽  
X. Bai ◽  
S. Wang ◽  
C. Wang
Keyword(s):  
Carbon Nanotubes ◽  
Thermal Properties ◽  
Composite Coating ◽  
Acid Treatment ◽  
Mechanical And Thermal Properties ◽  
Colour Properties ◽  
Content Type ◽  
Two Component ◽  
Appearance Properties

Purpose – The purpose of this paper is to investigate the effects of carbon nanotubes (CNTs) on the mechanical, thermal and colour properties of solvent-containing two-component polyurethane (PU) coating. Design/methodology/approach – Fourier transform infrared spectroscopy and observation of dispersion stability were used to assess the effects of acid treatment on CNTs. The CNTs and PU composite coating was synthesised by in situ polymerisation and bending polymerisation, and the mechanical, thermal and colour appearance properties of coating were characterised. Findings – It was found that desirable modifications to CNTs occurred after acid treatment; thus, mainly carboxylic acid groups were introduced onto the surface of CNTs. And the acid-treated CNTs could improve the mechanical and thermal properties of PU coating, and the properties of composite coating was improved more successfully by in situ polymerisation than by blending polymerisation. Practical implications – The investigation established a method to synthesise CNTs and PU composite coating. The mechanical and thermal properties of PU coating could be improved by the inclusion of CNTs. Originality/value – This study established a method to synthesise CNTs and PU composite coating by in situ polymerisation and blending polymerisation; the effects of CNTs on modifying mechanical, thermal and colour properties of PU coating were investigated and compared in detail.

In-situ probing the electrical, mechanical, and thermal properties of individual carbon nanotubes and nanowires by using a TEM-SPM platform

2008 ◽  
Vol 14 (S2) ◽  
pp. 398-399
Author(s):  
J-Y Huang
Keyword(s):  
Carbon Nanotubes ◽  
Thermal Properties ◽  
New Mexico ◽  
Mechanical And Thermal Properties

Extended abstract of a paper presented at Microscopy and Microanalysis 2008 in Albuquerque, New Mexico, USA, August 3 – August 7, 2008

scholarly journals Different Approaches to Oxygen Functionalization of Multi-Walled Carbon Nanotubes and Their Effect on Mechanical and Thermal Properties of Polyamide 12 Based Composites

Polymers ◽  
2020 ◽  
Vol 12 (2) ◽  
pp. 308 ◽  
Author(s):  
Magdalena Kwiatkowska ◽  
Robert Pełech ◽  
Anna Jędrzejewska ◽  
Dariusz Moszyński ◽  
Iwona Pełech
Keyword(s):  
Carbon Nanotubes ◽  
Thermal Properties ◽  
Acid Treatment ◽  
In Situ Polymerization ◽  
Chloroacetic Acid ◽  
Mechanical And Thermal Properties ◽  
High Concentration ◽  
Polyamide 12 ◽  
Surface Modified ◽  
Modified Carbon Nanotubes

In this work the preparation of polyamide 12 (PA12) based composites reinforced with pristine and surface-modified carbon nanotubes is reported. A qualitative and quantitative evaluation of multi-walled carbon nanotube functionalization with oxygen containing reactive groups achieved by different procedures of chemical treatment is presented. Simple strong oxidative acid treatment as well as chlorination with subsequent chloroacetic acid treatment were applied. Carbon nanotubes (CNTs) were also subjected to chlorine and ammonia in gaseous atmosphere with small differences in after-ammonia treatment. Commercial COOH-functionalized carbon nanotubes were compared with nanotubes that were laboratory modified. The effect of CNT functionalization was evaluated basing on the improvement of mechanical and thermal properties of polyamide 12 composites prepared by in situ polymerization. It was found that high concentration of oxygen-containing functional groups on nanotube surface is not sufficient to improve the composite performance if the structure of carbon nanotubes is defective. Indeed, the best effects were achieved for composites containing nanotubes modified under mild conditions, seemingly due to a compromise between morphology and surface chemical structure.

scholarly journals 3C-SiC Nanowires In-Situ Modified Carbon/Carbon Composites and Their Effect on Mechanical and Thermal Properties

Nanomaterials ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 894 ◽  
Author(s):  
Hongjiao Lin ◽  
Hejun Li ◽  
Qingliang Shen ◽  
Xiaohong Shi ◽  
Tao Feng ◽  
...  
Keyword(s):  
Shear Strength ◽  
Thermal Properties ◽  
Sol Gel ◽  
Interlaminar Shear Strength ◽  
Mechanical And Thermal Properties ◽  
Initial Oxidation ◽  
Sic Nanowires ◽  
Out Of Plane ◽  
Interlaminar Shear

An in-situ, catalyst-free method for synthesizing 3C-SiC ceramic nanowires (SiCNWs) inside carbon–carbon (C/C) composites was successfully achieved. Obtained samples in different stages were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and Raman scattering spectroscopy. Results demonstrated that the combination of sol-gel impregnation and carbothermal reduction was an efficient method for in-situ SiCNW synthesis, inside C/C composites. Thermal properties and mechanical behaviors—including out-of-plane and in-plane compressive strengths, as well as interlaminar shear strength (ILLS) of SiCNW modified C/C composites—were investigated. By introducing SiCNWs, the initial oxidation temperature of C/C was increased remarkably. Meanwhile, out-of-plane and in-plane compressive strengths, as well as interlaminar shear strength (ILLS) of C/C composites were increased by 249.3%, 109.2%, and 190.0%, respectively. This significant improvement resulted from simultaneous reinforcement between the fiber/matrix (F/M) and matrix/matrix (M/M) interfaces, based on analysis of the fracture mechanism.

Microstructure, mechanical, and thermal properties of in situ-synthesized (ZrB2+SiC)/Zr2[Al(Si)]4C5 composites

2013 ◽  
Vol 39 (7) ◽  
pp. 8559-8563 ◽  
Author(s):  
D.D. Guo ◽  
J. Yang ◽  
L. Yu ◽  
L.M. Pan ◽  
T. Qiu ◽  
...  
Keyword(s):  
Thermal Properties ◽  
Mechanical And Thermal Properties

Mechanical and thermal properties of PP/compatibilized PP/acid treated SWNTs nanocomposites: Effect of different acid treatment times

e-Polymers ◽  
2008 ◽  
Vol 8 (1) ◽  
Author(s):  
Morteza Ghorbanzadeh Ahangari ◽  
Abdolhosein Fereidoon ◽  
Seyfolah Saedodin
Keyword(s):  
Mechanical Properties ◽  
Thermal Properties ◽  
Acid Treatment ◽  
Treatment Process ◽  
Tensile Tests ◽  
Acid Mixture ◽  
Mechanical And Thermal Properties ◽  
Thermal And Mechanical Properties ◽  
Maleated Polypropylene ◽  
Carboxylic Groups

AbstractIn the present work, the effect of different acid treatment times of singlewalled carbon nanotubes (SWNTs) on the mechanical and thermal properties of polypropylene (PP)/maleated polypropylene (PP-g-MA) nanocomposites was investigated. The acid treatment process was based on a mixture of concentrated sulphuric and nitric acids. The SWNTs were treated with the acid mixture for 1, 3, and 6 h. FTIR, Raman spectroscopy and TEM revealed the values of carboxylic groups, graphitization and morphology of acid treated SWNTs, respectively. The thermal and mechanical properties and the morphology of nanocomposites were investigated by tensile tests, DMTA, DSC, and SEM.

Irradiation of poly(l-lactide) biopolymer reinforced with functionalized MWCNTs

RSC Advances ◽  
2015 ◽  
Vol 5 (68) ◽  
pp. 55544-55549 ◽  
Author(s):  
Ali Nabipour Chakoli ◽  
Jinmei He ◽  
Maryam Amirian Chayjan ◽  
Yudong Huang ◽  
Baode Zhang
Keyword(s):  
Carbon Nanotubes ◽  
Thermal Properties ◽  
Melting Point ◽  
Irradiation Effect ◽  
Mechanical And Thermal Properties ◽  
Functionalized Carbon Nanotubes ◽  
Functionalized Mwcnts

The γirradiation increases the modulus and strength, decreases the melting point of poly(l-lactide) during sterilization. The functionalized carbon nanotubes accelerate the irradiation effect on mechanical and thermal properties of poly(l-lactide).

Study on the In Situ Growth of Carbon Nanotubes for the Reinforcement of Cf/SiC Composite Fabricated by CVI+PIP Process

2013 ◽  
Vol 745-746 ◽  
pp. 582-586 ◽  
Author(s):  
Jian Bao Hu ◽  
Shao Ming Dong ◽  
Xiang Yu Zhang ◽  
Zhen Wang ◽  
Hai Jun Zhou ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Carbon Nanotubes ◽  
Bonding Strength ◽  
Volume Fraction ◽  
Interfacial Bonding ◽  
Mechanical And Thermal Properties ◽  
Fiber Volume ◽  
Pull Out ◽  
Interfacial Bonding Strength

Cf/SiC composites were fabricated through in situ growth of carbon nanotubes (CNTs) on three-dimensional needle-punched carbon fabric via chemical vapor deposition and polymer impregnation and pyrolysis process. The mechanical and thermal properties of the composites were investigated. The flexural strength and fracture toughness were decreased due to the fiber volume fraction loss and much shorter pull-out length of fibers which was caused by the higher interfacial bonding strength between fiber and matrix after the growth of CNTs. Brittle fracture character of CNTs was observed due to the strong interfacial bonding strength between CNTs and matrix. The parallel thermal conductivity and perpendicular thermal conductivity were improved to 14.5% and 8.0% respectively.

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