Polymer Nanocomposites with High Energy Density and Breakdown Strength utilizing Oriented BNNS

2020 ◽  
Author(s):  
Yushu Li ◽  
Sang Cheng ◽  
Yujie Zhu ◽  
Jun Hu ◽  
Jinliang He ◽  
...  
Keyword(s):  
Energy Density ◽  
Polymer Nanocomposites ◽  
Breakdown Strength ◽  
High Energy ◽  
High Energy Density

scholarly journals Recent Advances in the Synthesis of Polymer-Grafted Low-K and High-K Nanoparticles for Dielectric and Electronic Applications

Molecules ◽  
2021 ◽  
Vol 26 (10) ◽  
pp. 2942
Author(s):  
Bhausaheb V. Tawade ◽  
Ikeoluwa E. Apata ◽  
Nihar Pradhan ◽  
Alamgir Karim ◽  
Dharmaraj Raghavan
Keyword(s):  
Energy Density ◽  
Polymer Nanocomposites ◽  
High Performance ◽  
Breakdown Strength ◽  
Polymer Nanocomposite ◽  
High Energy ◽  
Polymer Chains ◽  
High Energy Density ◽  
Grafted Nanoparticles ◽  
Grafting From

The synthesis of polymer-grafted nanoparticles (PGNPs) or hairy nanoparticles (HNPs) by tethering of polymer chains to the surface of nanoparticles is an important technique to obtain nanostructured hybrid materials that have been widely used in the formulation of advanced polymer nanocomposites. Ceramic-based polymer nanocomposites integrate key attributes of polymer and ceramic nanomaterial to improve the dielectric properties such as breakdown strength, energy density and dielectric loss. This review describes the ”grafting from” and ”grafting to” approaches commonly adopted to graft polymer chains on NPs pertaining to nano-dielectrics. The article also covers various surface initiated controlled radical polymerization techniques, along with templated approaches for grafting of polymer chains onto SiO2, TiO2, BaTiO3, and Al2O3 nanomaterials. As a look towards applications, an outlook on high-performance polymer nanocomposite capacitors for the design of high energy density pulsed power thin-film capacitors is also presented.

Enhanced electric breakdown strength and high energy density of barium titanate filled polymer nanocomposites

2013 ◽  
Vol 114 (17) ◽  
pp. 174107 ◽  
Author(s):  
Ke Yu ◽  
Yujuan Niu ◽  
Feng Xiang ◽  
Yongcun Zhou ◽  
Yuanyuan Bai ◽  
...  
Keyword(s):  
Energy Density ◽  
Barium Titanate ◽  
Polymer Nanocomposites ◽  
Breakdown Strength ◽  
High Energy ◽  
Electric Breakdown ◽  
High Energy Density ◽  
Filled Polymer

scholarly journals Designing polymer nanocomposites with high energy density using machine learning

2021 ◽  
Vol 7 (1) ◽  
Author(s):  
Zhong-Hui Shen ◽  
Zhi-Wei Bao ◽  
Xiao-Xing Cheng ◽  
Bao-Wen Li ◽  
Han-Xing Liu ◽  
...  
Keyword(s):  
Machine Learning ◽  
Energy Storage ◽  
Energy Density ◽  
Polymer Nanocomposites ◽  
Breakdown Strength ◽  
Phase Field Model ◽  
High Energy ◽  
High Energy Density ◽  
Electrostatic Energy ◽  
Wide Range

AbstractAddressing microstructure-property relations of polymer nanocomposites is vital for designing advanced dielectrics for electrostatic energy storage. Here, we develop an integrated phase-field model to simulate the dielectric response, charge transport, and breakdown process of polymer nanocomposites. Subsequently, based on 6615 high-throughput calculation results, a machine learning strategy is schemed to evaluate the capability of energy storage. We find that parallel perovskite nanosheets prefer to block and then drive charges to migrate along with the interfaces in x-y plane, which could significantly improve the breakdown strength of polymer nanocomposites. To verify our predictions, we fabricate a polymer nanocomposite P(VDF-HFP)/Ca2Nb3O10, whose highest discharged energy density almost doubles to 35.9 J cm−3 compared with the pristine polymer, mainly benefit from the improved breakdown strength of 853 MV m−1. This work opens a horizon to exploit the great potential of 2D perovskite nanosheets for a wide range of applications of flexible dielectrics with the requirement of high voltage endurance.

Enhanced dielectric properties and thermostability in polyimide composites with core-shell structured polyimide@BaTiO3 nanoparticles

2021 ◽  
pp. 095400832199352
Author(s):  
Wei Deng ◽  
Guanguan Ren ◽  
Wenqi Wang ◽  
Weiwei Cui ◽  
Wenjun Luo
Keyword(s):  
Dielectric Constant ◽  
Dielectric Loss ◽  
Energy Density ◽  
Breakdown Strength ◽  
In Situ Polymerization ◽  
Dielectric Materials ◽  
High Energy ◽  
Amic Acid ◽  
High Energy Density ◽  
Core Shell

Polymer composites with high dielectric constant and thermal stability have shown great potential applications in the fields relating to the energy storage. Herein, core-shell structured polyimide@BaTiO3 (PI@BT) nanoparticles were fabricated via in-situ polymerization of poly(amic acid) (PAA) and the following thermal imidization, then utilized as fillers to prepare PI composites. Increased dielectric constant with suppressed dielectric loss, and enhanced energy density as well as heat resistance were simultaneously realized due to the presence of PI shell between BT nanoparticles and PI matrix. The dielectric constant of PI@BT/PI composites with 55 wt% fillers increased to 15.0 at 100 Hz, while the dielectric loss kept at low value of 0.0034, companied by a high energy density of 1.32 J·cm−3, which was 2.09 times higher than the pristine PI. Moreover, the temperature at 10 wt% weight loss reached 619°C, demonstrating the excellent thermostability of PI@BT/PI composites. In addition, PI@BT/PI composites exhibited improved breakdown strength and toughness as compared with the BT/PI composites due to the well dispersion of PI@BT nanofillers and the improved interfacial interactions between nanofillers and polymer matrix. These results provide useful information for the structural design of high-temperature dielectric materials.

High-Energy-Density Polymer Nanocomposites Composed of Newly Structured One-Dimensional BaTiO3@Al2O3 Nanofibers

2017 ◽  
Vol 9 (4) ◽  
pp. 4024-4033 ◽  
Author(s):  
Zhongbin Pan ◽  
Lingmin Yao ◽  
Jiwei Zhai ◽  
Dezhou Fu ◽  
Bo Shen ◽  
...  
Keyword(s):  
Energy Density ◽  
Polymer Nanocomposites ◽  
High Energy ◽  
High Energy Density ◽  
One Dimensional

Flexible solvent-free supercapacitors with high energy density enabled by electrical-ionic hybrid polymer nanocomposites

2019 ◽  
Vol 7 (28) ◽  
pp. 16748-16760 ◽  
Author(s):  
Cheng Chi ◽  
Yang Li ◽  
Dezhao Li ◽  
He Huang ◽  
Qi Wang ◽  
...  
Keyword(s):  
Energy Density ◽  
Polymer Nanocomposites ◽  
Solid Electrolytes ◽  
High Energy ◽  
Solvent Free ◽  
High Energy Density ◽  
Hybrid Polymer ◽  
Flexible Supercapacitor ◽  
Interfacial Contact

The incorporation of polymer solid electrolytes into GO/CNT electrodes significantly improves interfacial contact, boosting the performance of the solvent-free flexible supercapacitor.

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