Molecular Motion in Liquids and Solutions. II.

1966 ◽  
Vol 21 (8) ◽  
pp. 1224-1230 ◽  
Author(s):  
G. J. Krüger ◽  
W. Müller-Warmuth ◽  
R. Van Steenwinkel
Keyword(s):  
Molecular Motion ◽  
Dipole Interaction ◽  
Proton Relaxation ◽  
Frequency Range ◽  
Kcal Mole ◽  
Relative Contribution ◽  
Random Motions ◽  
Large Frequency ◽  
Solvent Proton

Two methods are utilized to study the relaxation behaviour and molecular motion in solutions of free radicals in toluene: the investigation of longitudinal and transversal solvent proton relaxation at a properly chosen frequency (48 MHz), and the determination of enhancement factors of the dynamic proton polarization over a large frequency range. The temperature dependence of the quantities concerned is measured between +70°C and —120°C.The results can be interpreted in terms of a pure dipole-dipole interaction between proton and electron spins whose time dependence is provided by translational random motions of the molecules and rotational tumbling of associated complexes. The activation energies for both processes are 3.1 kcal/mole and 7.8 kcal/mole, respectively. The solvation is only very weak. The relative contribution of rotational tumbling is R=0.26, from which the average co-ordination number is estimated to be less than one.

scholarly journals The Application of Electromagnetic Sensors for Determination of Cherenkov Cone Inside and in the Vicinity of the Detector Volume in Any Environment Known

Sensors ◽  
2021 ◽  
Vol 21 (3) ◽  
pp. 992
Author(s):  
Valeriu Savu ◽  
Mădălin Ion Rusu ◽  
Dan Savastru
Keyword(s):  
Energy Levels ◽  
Cherenkov Detector ◽  
Electromagnetic Sensors ◽  
The Cost ◽  
Information Errors ◽  
The Universe ◽  
Large Frequency ◽  
Very High ◽  
Detector Volume

The neutrinos of cosmic radiation, due to interaction with any known medium in which the Cherenkov detector is used, produce energy radiation phenomena in the form of a Cherenkov cone, in very large frequency spectrum. These neutrinos carry with them the information about the phenomena that produced them and by detecting the electromagnetic energies generated by the Cherenkov cone, we can find information about the phenomena that formed in the universe, at a much greater distance, than possibility of actually detection with current technologies. At present, a very high number of sensors for detection electromagnetic energy is required. Thus, some sensors may detect very low energy levels, which can lead to the erroneous determination of the Cherenkov cone, thus leading to information errors. As a novelty, we propose, to use these sensors for determination of the dielectrically permittivity of any known medium in which the Cherenkov detector is used, by preliminary measurements, the subsequent simulation of the data and the reconstruction of the Cherenkov cone, leading to a significant reduction of problems and minimizing the number of sensors, implicitly the cost reductions. At the same time, we offer the possibility of reconstructing the Cherenkov cone outside the detector volume.

The pH dependence of solvent proton relaxation in carbonic anhydrase solutions: paramagnetic and diamagnetic effects

Biochemistry ◽  
1979 ◽  
Vol 18 (10) ◽  
pp. 1989-1995 ◽  
Author(s):  
James W. Wells ◽  
Stephen I. Kandel ◽  
Seymour H. Koenig
Keyword(s):  
Carbonic Anhydrase ◽  
Ph Dependence ◽  
Proton Relaxation ◽  
Solvent Proton

Steroids and steroidases. IX. Activation parameters and the mechanism of base- and enzyme-catalyzed isomerizations of androst-5-ene-3,17-dione. The nature of the active center of the Δ5 → Δ4-3-ketosteroid isomerase of Pseudomonas testosteroni

1969 ◽  
Vol 47 (23) ◽  
pp. 4459-4466 ◽  
Author(s):  
J. Bryan Jones ◽  
Donald C. Wigfield
Keyword(s):  
Amino Acids ◽  
Active Center ◽  
Activation Parameters ◽  
Circumstantial Evidence ◽  
Kcal Mole ◽  
Acid Base ◽  
Ketosteroid Isomerase ◽  
Enzyme Action ◽  
Enthalpy Of Activation

Determination of the activation parameters for the acid-, base-, and enzyme-catalyzed isomerizations of androst-5-ene-3,17-dione has revealed that the facility of the enzymic process is mainly due to an extremely low enthalpy of activation of 5.0 kcal mole−1. Further circumstantial evidence regarding the nature of the reacting groups at the active center has also been obtained, and a mechanism of enzyme action is proposed employing tyrosine and histidine as the principal amino acids responsible for catalyzing the isomerization.

Research of the Wood’s Alloy Crystallization Process Using the Acoustic Method

2021 ◽  
Vol 410 ◽  
pp. 855-861
Author(s):  
Aleksandr Yu. Yaroslavkin ◽  
Eugene A. Tyurin ◽  
Darya A. Melnikova
Keyword(s):  
Speed Of Sound ◽  
Crystallization Process ◽  
Ultrasonic Method ◽  
Single Pulse ◽  
Acoustic Method ◽  
The State ◽  
Sound Signal ◽  
Frequency Range ◽  
Wood’S Alloy

The article examines the process of crystallization of Wood alloy using the ultrasonic method. The dependence of the determination of the speed of sound in three aggregate states of the alloy (liquid, solid, transition (liquid-solid)) was derived. The relation-ship with the amplitude values of the sound signal, a single pulse in determining the speed of sound, as well as in determining the state of the alloy is carried out. The data obtained allow us to analyze the state of the alloy and the measurement time and the specified frequency range directly in the process of crystallization.

Method of Testing of Sound Absorption Properties of Materials Intended for Ultrasonic Noise Protection

2013 ◽  
Vol 38 (2) ◽  
pp. 191-195 ◽  
Author(s):  
Dariusz Pleban
Keyword(s):  
Sound Absorption ◽  
Free Field ◽  
Tone Burst ◽  
Mineral Wool ◽  
Frequency Range ◽  
Absorption Properties ◽  
Open Cell Foam ◽  
Properties Of Materials ◽  
Cell Foam

Abstract Efficient ultrasonic noise reduction by using enclosures requires the knowledge of absorbing properties of materials in the frequency range above 4 kHz. However, standardized methods enable determination of absorption coefficients of materials in the frequency range up to 4 kHz. For this reason, it is proposed to carry out measurements of the sound absorption properties of materials in the free field by means of a tone-burst technique in the frequency range from 4 kHz to 40 kHz at angles of incidence varying from 0° to 60°. The absorption coefficient of a material is calculated from the reflection coefficient obtained by reflecting a tone-burst from both a perfectly reflecting panel and a combination of this panel and the sample of the tested material. The tests results show that mineral wool and polyurethane open-cell foam possess very good absorbing properties in this frequency range.

Determination of Electric and Magnetic Properties of Commercial LTCC Soft Ferrite Material

2011 ◽  
Vol 8 (1) ◽  
pp. 1-9 ◽  
Author(s):  
Nelu Blaž ◽  
Andrea Marić ◽  
Goran Radosavljević ◽  
Nebojša Mitrović ◽  
Ibrahim Atassi ◽  
...  
Keyword(s):  
Electrical Properties ◽  
Low Frequency ◽  
Hysteresis Loops ◽  
Frequency Range ◽  
Dispersion Parameters ◽  
Simple Method ◽  
Component Design ◽  
Microwave Engineering ◽  
Characterization Procedure

This paper offers an effective, accurate, and simple method for permittivity and permeability determination of an LTCC (low temperature cofired ceramic) ferrite sample. The presented research can be of importance in the fields of ferrite component design and application, as well as for RF and microwave engineering. The characterization sample is a stack of LTCC tapes forming a toroid. Commercially available ferrite tape ESL 40012 was used and standard LTCC processing was applied for the sample fabrication. For the first time, the electrical properties of a ferrite toroid sample of ESL 40012 LTCC ferrite tape is presented at various frequencies. The electrical properties of LTCC ferrite materials, permittivity and specific resistivity, are shown in a frequency range from 10 kHz to 1 MHz using the capacitive method. The hysteresis properties of this material are also determined. B-H hysteresis loops were measured applying a maximum excitation of 2 kA/m and frequencies of 50 Hz, 500 Hz, and 1000 Hz. Permeability is determined in the frequency range from 10 kHz to 1 GHz and a characterization procedure is divided in two segments, for low and high frequencies. Low frequency measurements (from 10 kHz to 1 MHz) are performed using LCZ meter and discrete turns of wire, while a short coaxial sample holder and vector network analyzer were used for the higher frequency range (from 300 kHz to 1 GHz). In addition, another important factor required for the practical design of devices is presented, the temperature variation of the permeability dispersion parameters.

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