Quantitative Hrtem: Measuring Projected Potential, Surface Roughness and Chemical Composition

1994 ◽  
Vol 332 ◽  
Author(s):  
P. Schwander ◽  
C. Kisielowski ◽  
F.H. Baumann ◽  
Y.O. Kim ◽  
A. Ourmazd

ABSTRACTWe describe how general lattice images may be used to measure the variation of the potential in crystalline solids in any projection, with no knowledge of the imaging conditions. This approach is applicable to structurally perfect samples, in which interfacial topography, or changes in composition are of interest. We present the first atomic-level topographic map of a Si/SiO2 interface in plan-view, and the first microscopic compositional map of a Si/GeSi/Si quantum well in cross-section.

Materials ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1455 ◽  
Author(s):  
Michał Bembenek ◽  
Janusz Krawczyk ◽  
Łukasz Frocisz ◽  
Tomasz Śleboda

This paper presents the results of the investigations of the properties of saddle-shaped copper alloy chips briquettes produced in a roller press. The physical and mechanical properties of the investigated briquettes were examined on their external surfaces as well as on their cross-sections. The density, chemical composition, microstructure analysis obtained with a 3D and scanning microscope, surface roughness and hardness of the obtained briquettes were investigated. The research proved the differentiation of the physical and mechanical properties of briquettes depending on the investigated area of their surface. The analysis of changes in the porosity of briquettes on their cross-section showed zones of various densification levels. This research expands the knowledge of the processes taking place during the compaction and consolidation of granular materials in roller presses as well as the knowledge concerning designing the geometry of forming tools.


Author(s):  
P. Pradère ◽  
J.F. Revol ◽  
R. St. John Manley

Although radiation damage is the limiting factor in HREM of polymers, new techniques based on low dose imaging at low magnification have permitted lattice images to be obtained from very radiation sensitive polymers such as polyethylene (PE). This paper describes the computer averaging of P4MP1 lattice images. P4MP1 is even more sensitive than PE (total end point dose of 27 C m-2 as compared to 100 C m-2 for PE at 120 kV). It does, however, have the advantage of forming flat crystals from dilute solution and no change in d-spacings is observed during irradiation.Crystals of P4MP1 were grown at 60°C in xylene (polymer concentration 0.05%). Electron microscopy was performed with a Philips EM 400 T microscope equipped with a Low Dose Unit and operated at 120 kV. Imaging conditions were the same as already described elsewhere. Enlarged micrographs were digitized and processed with the Spider image processing system.


Author(s):  
H. Kinney ◽  
M.L. Occelli ◽  
S.A.C. Gould

For this study we have used a contact mode atomic force microscope (AFM) to study to topography of fluidized cracking catalysts (FCC), before and after contamination with 5% vanadium. We selected the AFM because of its ability to well characterize the surface roughness of materials down to the atomic level. It is believed that the cracking in the FCCs occurs mainly on the catalysts top 10-15 μm suggesting that the surface corrugation could play a key role in the FCCs microactivity properties. To test this hypothesis, we chose vanadium as a contaminate because this metal is capable of irreversibly destroying the FCC crystallinity as well as it microporous structure. In addition, we wanted to examine the extent to which steaming affects the vanadium contaminated FCC. Using the AFM, we measured the surface roughness of FCCs, before and after contamination and after steaming.We obtained our FCC (GRZ-1) from Davison. The FCC is generated so that it contains and estimated 35% rare earth exchaged zeolite Y, 50% kaolin and 15% binder.


Author(s):  
Ming-Hui Yao ◽  
David J. Smith

The chemical properties of catalysts often depend on the size, shape and structure of the supported metal particles. To characterize these morphological features and relate them to catalysis is one of the main objectives for HREM study of catalysts. However, in plan view imaging, details of the shape and structure of ultra-fine supported particles (<2nm) are often obscured by the overlapping contrast from the support, and supported sub-nanometer particles are sometimes even invisible. Image simulations may help in the interpretation at HREM images of supported particles in particular to extract useful information about the size, shape and structure of the particles. It should also be a useful tool for evaluating the imaging conditions in terms of visibility of supported particles. P. L. Gai et al have studied contrast from metal particles supported on amorphous material using multislice simulations. In order to better understand the influence of a crystalline support on the visibility and apparent morphological features of supported fine particles, we have calculated images of Pt and Re particles supported on TiO2(rutile) in both plan view and profile view.


2010 ◽  
Vol 16 (6) ◽  
pp. 662-669 ◽  
Author(s):  
S. Simões ◽  
F. Viana ◽  
A.S. Ramos ◽  
M.T. Vieira ◽  
M.F. Vieira

AbstractReactive multilayer thin films that undergo highly exothermic reactions are attractive choices for applications in ignition, propulsion, and joining systems. Ni/Al reactive multilayer thin films were deposited by dc magnetron sputtering with a period of 14 nm. The microstructure of the as-deposited and heat-treated Ni/Al multilayers was studied by transmission electron microscopy (TEM) and scanning transmission electron microscopy (STEM) in plan view and in cross section. The cross-section samples for TEM and STEM were prepared by focused ion beam lift-out technique. TEM analysis indicates that the as-deposited samples were composed of Ni and Al. High-resolution TEM images reveal the presence of NiAl in small localized regions. Microstructural characterization shows that heat treating at 450 and 700°C transforms the Ni/Al multilayered structure into equiaxed NiAl fine grains.


2021 ◽  
Vol 16 (1) ◽  
pp. 43-48
Author(s):  
Michal Krbaťa ◽  
◽  
Jana Escherová ◽  

The paper deals with the change in mechanical properties and wear of 1.2842 universal tool steel after plasma nitriding, which is widely used to produce cutting tools with good durability and low operating costs. Plasma nitriding was performed at a temperature of 500 °C for 10-hour period in a standard N2 /H2 atmosphere with 1:3 gases ratio. Microstructure, phase structure, thickness of a nitriding layer and surface roughness of samples were measured with optical microscopes and a profilometer. Verification of a chemical composition was carried out on the BAS TASMAN Q4 device. Wear resistance was measured on a universal TRIBOLAB UTM 3 tribometer, through a, “pin on disc“ method. The results of experiments have shown that plasma nitriding process, significantly improves the mechanical and tribological properties of selected materials.


1985 ◽  
Vol 25 (01) ◽  
pp. 78-88 ◽  
Author(s):  
T.K. Perkins ◽  
J.A. Gonzalez

Abstract When a cool fluid such as water is injected into a hot reservoir, a growing region of cooled rock is established around the injection well. The rock matrix within the cooled region contracts, and a thermoelastic stress field is induced around the well. For typical waterflooding of a moderately deep reservoir, horizontal earth stresses may be reduced by several hundred psi. If the injection pressure is too high or if suspended solids in the water plug the formation face at the perforations, the formation will be fractured hydraulically. As the fracture grows, the flow system evolves from an essentially circular geometry in the plan view to one characterized more nearly as elliptical. This paper considers thermoelastic stresses that would result from cooled regions of fixed thickness and of elliptical cross section. The stresses for an infinitely thick reservoir have been deduced from information available in public literature. A numerical method has been developed to calculate thermoelastic stresses induced within elliptically shaped regions of finite thickness. Results of these two approaches were combined, and empirical equations were developed to give an approximate but convenient, explicit method for estimating induced stresses. An example problem is given that shows how this theory can be applied to calculate the fracture lengths, bottomhole pressures (BHP's), and elliptical shapes of the flood front as the injection process progresses. Introduction When fluids are injected into a well, such as during waterflooding or other secondary or tertiary recovery processes, the temperatures of the injected fluids are typically cooler than the in-situ reservoir temperatures. A region of cooled rock forms around each injection well, and this region grows as additional fluid is injected. Formation rock within the cooled region contracts, and this leads to a decrease in horizontal earth stress near the injection well. In Ref. 1, the magnitude of the reduction in horizontal earth stress was given for the case of a radially symmetrical cooled region. Another factor, which may occur simultaneously, is the plugging of formation rock by injected solids. There is extensive literature indicating that waters normally available for injection contain suspended solids. Laboratory tests demonstrate that these waters, when injected into formation rocks, can plug the face of the rock or severely limit injectivity. In field operations, injection often simply continues at a BHP that is high enough to initiate and extend hydraulic fractures." The injected fluid then can leak off readily through the large fracture face area. Because of the lowering of horizontal earth stresses that results from cold fluid injection, hydraulic fracturing pressures can be much lower than would be expected for an ordinary low-leakoff hydraulic fracturing treatment. For this reason, the well operator may not be aware that injected fluid is being distributed through an extensive hydraulic fracture. If injection conditions are such that a hydraulic fracture is created, then the flow system will evolve from an essentially circular geometry in the plan view to one characterized more nearly as elliptical. In this paper, thermoelastic stresses for cooled regions of fixed thickness and of elliptical cross section are determined, and a theory of hydraulic fracturing of injection wells is developed. Conditions under which secondary fractures (perpendicular to the primary, main fracture) will open also are discussed. Finally, an example problem is given to illustrate how this theory can be applied to calculate fracture lengths, BHP'S, and elliptical shapes of the flood front as the injection process progresses. Thermoelastic Stresses in Regions of Elliptical Cross Section If fluid of constant viscosity is injected into a line crack (representing a two-wing, vertical hydraulic fracture), the flood front will progress outward. so its outer boundary at any time can be described approximately as an ellipse that is confocal with the line crack. If the injected fluid is at a temperature different from the formation temperature, a region of changed rock temperature with fairly sharply defined boundaries will progress outward from the injection well but lag behind the flood front. The outer boundary of the region of changed temperature also will be elliptical in its plan view and confocal with the line crack (see Fig. 1). Stresses within the region of altered temperature, as well as stress in the surrounding rock, which remains at its initial temperature, will be changed because of the expansion or contraction of the rock within the region of altered temperature. The thermoelastic stresses within an infinitely tall cylinder of elliptical cross section can be determined from information available in the literature. 10 The interior thermoelastic stresses perpendicular and parallel to the major axes of the ellipse are given by Eqs. 1 and 2, respectively. SPEJ P. 78^


2012 ◽  
Vol 730-732 ◽  
pp. 9-14 ◽  
Author(s):  
Bruno Henriques ◽  
Filipe Silva ◽  
Delfim Soares

The purpose of this work was to perform a chemical and mechanical characterization of a preoxidized CoCrMo alumina blasted surface. This is a commonly performed surface treatment used in metal-porcelain systems for dental restorations to remove oxides formed during preoxidation heat treatment from the metal’s surface. CoCrMo dental alloy’s specimens produced by lost wax process were examined in terms of chemical composition using X-Ray fluorescence spectroscopy (XRF), Scanning Electron Microscopy (SEM) and Energy Dispersive X-Ray Spectroscopy (EDS); in terms of mechanical characteristics through the means of a microhardness test and in terms of surface roughness using a profilometer. It was investigated the chemical composition of various surface conditions: non-preoxidized, preoxidized, ground oxidized surface and sandblasted oxidized surface. After alumina blasting, the oxides level on metal’s surface remained high. Alumina blasting treatment (Ø110 µm) produced an 84% increase of CoCrMo surface hardening and an increase in surface roughness (Ra=0.58 µm). It was found alumina contaminants on the metal’s surface. Therefore, it was concluded that alumina blasting do not entirely removes the oxide layer formed during preoxidation heat treatment. It produced a chemical and mechanical surface modification that can influence the metal-ceramic bond strength.


2020 ◽  
Vol 66 (3) ◽  
pp. 139-148
Author(s):  
Maja Vončina ◽  
Peter Cvahte ◽  
Ana Kračun ◽  
Tilen Balaško ◽  
Jožef Medved

AbstractThe alloys from Al–Mg–Si system provide an excellent combination of mechanical properties, heat treatment at extrusion temperature, good weldability, good corrosion resistance and formability. Owing to the high casting speed of rods or slabs, the solidification is rather non-equilibrium, resulting in defects in the material, such as crystalline segregations, the formation of low-melting eutectics, the unfavourable shape of intermetallic phases and the non-homogeneously distributed alloying elements in the cross-section of the rods or slabs and in the entire microstructure. The inhomogeneity of the chemical composition and the solid solution negatively affects the strength, the formability in the warm and the corrosion resistance, and can lead to the formation of undesired phases due to segregation in the material. In this experimental investigation, the cross-sections of the rods from two different alloys of the 6xxx group were investigated. From the cross-sections of the rods, samples for differential scanning calorimetry (DSC) at three different positions (edge, D/4 and middle) were taken to determine the influence of inhomogeneity on the course of DSC curve. Metallographic sample preparation was used for microstructure analysis, whereas the actual chemical composition was analysed using a scanning electron microscope (SEM) and an energy dispersion spectrometer (EDS).


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