scholarly journals Carbon Fabric Reinforced Addition-Cure Phenolic Resins Based on Propargyl and Allyl Ether Functional Novolac Produced

2020 ◽  
Vol 22 (2) ◽  
pp. 99
Author(s):  
S. Nechausov ◽  
B. Bulgakov ◽  
D. Kalugin ◽  
A. Babkin ◽  
A. Kepman ◽  
...  

Composites consisting of propargyl- and allyl/propargyl- modified novolac resins and carbon fabric were obtained by the vacuum infusion molding process. It was established that the presence of potassium cations remaining after the synthesis increase the resin melt viscosity, and acid washing is needed to obtain resins suitable for cost-effective injection techniques of composite fabrication. The mechanical properties of all composites such as compressive strength, tensile strength, in plane shear strength, and interlaminar shear strength were determined at 25, 200 and 230 °С. The carbon fiber reinforced plastics (CFRPs) retained their mechanical properties at temperatures up to 200 °C. It was shown that the use of the obtained allyl-containing polymer matrices improved mechanical properties and increased the thermal stability of the CFRPs in comparison with the propargylated novolac matrices. The composite material with novolac matrices modified by 18% propargyl and 23% allyl groups retains only up to 70% of the initial interlaminar shear strength values at 230 °C which corresponds to the data of the dynamic mechanical analysis of neat cured resins.

Materials ◽  
2019 ◽  
Vol 12 (5) ◽  
pp. 778 ◽  
Author(s):  
Elwathig. Hassan ◽  
Tienah. Elagib ◽  
Hafeezullah Memon ◽  
Muhuo Yu ◽  
Shu Zhu

Due to the non-polar nature and low wettability of carbon fibers (CFs), the interfacial adhesion between CFs and the polyetheretherketone (PEEK) matrix is poor, and this has negative effects on the mechanical properties of CF/PEEK composites. In this work, we established a modification method to improve the interface between CFs and PEEK based chemical grafting of aminated polyetheretherketone (PEEK-NH2) on CFs to create an interfacial layer which has competency with the PEEK matrix. The changed chemical composition, surface morphology, surface energy, and interlaminar shear strength were investigated. After grafting, the interlaminar shear strength (ILSS) was improved by 33.4% due to the covalent bonds in the interface region, as well as having good compatibility between the interface modifier and PEEK. Finally, Dynamic Mechanical Analysis (DMA) and Scanning Electron Microscopy (SEM) observation also confirmed that the properties of the modified CF/PEEK composites interface were enhanced. This work is, therefore, a beneficial approach towards enhancing the mechanical properties of thermoplastic composites by controlling the interface between CFs and the PEEK matrix.


2020 ◽  
pp. 152808372096073
Author(s):  
Marwa A Abd El-baky ◽  
Mohamed A Attia

In this study, the effect of different weight percentages (wt. %) of halloysite nanotubes (HNTs) on the mechanical performance of glass laminate aluminum (Al) reinforced epoxy (GLARE) was investigated. GLARE (3/2) laminates with quasi-isotropic lay-up, [Al/[(0°/90°)/(45°/−45°)]s/Al/[(0°/90°)/(45°/−45°)]s/Al] filled with 0, 0.25, 0.5, 1, 2 and 3 wt. % of HNTs were fabricated using hand lay-up followed by compression molding. To explore the effect of HNTs on the mechanical properties, tensile, flexural, in-plane shear, interlaminar shear, bearing and impact tests were conducted. Results demonstrated that the inclusion of 1 wt. % of HNTs into GLARE leads to maximum improvements of 35.67, 8.50, 28.85, 50.47, 50.27, 30.43, 23.73, 72.08, 30.74, and 51.52% in tensile strength, tensile strain, Young's modulus, modulus of toughness, flexural strength, flexural strain, in-plane shear strength, interlaminar shear strength, bearing strength, and impact strength, respectively, compared to pristine GLARE. An enhancement of 38.89% in the flexural modulus was attained by adding 0.5 wt. % of HNTs to GLARE compared to pristine GLARE. The tensile strength, tensile strain, modulus of toughness, flexural strength, flexural modulus, flexural strain, in-plane shear strength, and interlaminar shear strength of GLARE filled with 3 wt. % of HNTs are 0.91, 0.88, 0.91, 0.91, 0.71, 0.83, 0.85, and 0.91 times those of the original GLARE. But Young’s modulus, bearing strength, and impact strength are 1.10, 1.15 and 1.20 times those of the original GLARE. To investigate the fracture mechanism, field emission scanning electron microscope (FE-SEM) and energy-dispersive X-ray spectroscopy (EDX) were used. The microscopic images revealed that adding HNTs lead to the improvement in the interaction between the epoxy matrix and glass fiber, thereby improving the mechanical properties.


2021 ◽  
pp. 096739112098651
Author(s):  
Saeedeh Saadatyar ◽  
Mohammad Hosain Beheshty ◽  
Razi Sahraeian

Unidirectional carbon fiber-reinforced epoxy (UCFRE) is suffering from weak transverse mechanical properties and through-thickness properties. The effect of different amount (0.1, 0.3 and 0.5 phr which is proportional to 0.09, 0.27 and 0.46 wt%, respectively) of multiwall carbon nanotube (MWCNT), on transverse tensile properties, flexural strength, fracture toughness in transverse and longitudinal fiber directions, interlaminar shear strength and lap shear strength of UCFRE has been investigated. Dicyandiamide was used as a thermal curing agent of epoxy resin. MWCNT was dispersed in the epoxy resin by ultrasonic instrument and their dispersion state was investigated by scanning electron microscopy (SEM). The curing behavior of epoxy resin and its nanocomposites was assessed by differential scanning calorimetry. Results show that transverse tensile strength, modulus and strain-at-break were increased by 28.5%, 25% and 14%, respectively by adding 0.1 phr of MWCNT. Longitudinal flexural properties of UCFRE was not changed by adding different amount of MWCNT. Although longitudinal flexural strength was increased by 5% by adding 0.1 phr of MWCNT. Fracture toughness in transverse and longitudinal fiber directions was increased by 39% and 9%, respectively at 0.3 phr of MWCNT. Results also show that interlaminar shear strength and lap shear strength were increased at 0.3 phr of MWCNT by 8% and 5%, respectively. These increases in mechanical properties were due to the good adhesion of fibers to the matrix, interlocking and toughening action of MWCNT as revealed by SEM.


2021 ◽  
pp. 152808372110523
Author(s):  
Kumaresan Gladys Ashok ◽  
Kalaichelvan Kani

In the present study, the significance of nanofiller lead oxide (PbO) on the dynamic mechanical analysis (DMA) and interlaminar shear strength (ILSS) performance of luffa fiber–reinforced epoxy composites was investigated. The epoxy matrix was altered with nanofiller PbO of different weight percent through a mechanical stirring process. The PbO-added luffa fiber epoxy composites were made through hand layup preceded by the compression molding method. The prepared composite samples were investigated for ILSS and DMA. The test results lead to the inference that the 1.25 wt% PbO nanofiller–added composite samples attained 25%, 17%, and 55% of higher loss modulus, storage modulus, and ILSS, respectively, as compared with the other prepared samples. The morphological investigation was conducted on the fractured surface of the interlaminar tested samples. The micrographic images show the bonding nature of the luffa fiber with the epoxy matrix, fiber breakage, and fiber pullouts. The characterization studies such as FTIR, XRD, and EDX were conducted on the fabricated composite samples. The XRD studies show that the rise in weight percent of the nanofiller PbO enhances the crystallinity of the composite samples. Moreover, the composite sample prepared with 1.25 wt% nanofiller PbO can be used to prepare low-cost roofing materials for sustainable housing projects.


2011 ◽  
Vol 335-336 ◽  
pp. 244-248 ◽  
Author(s):  
Gang Liu ◽  
Dai Jun Zhang ◽  
Peng Zhang ◽  
Xiao Su Yi

This article is intended to outline a novel concept of interlaminar 3-3 connectivity of fiber-reinforced laminated composites. This microstructure is typically realized by using thorny ZnO whiskers exactly located in the interlayer of glass or carbon fabric for RTM. From the initial testing, the interlaminar shear strength (ILSS) is noted to increase up to 150% while retaining the most other in-plane properties. Mechanistic penetrating and pinning are considered to be the dominant mechanism of interlaminar toughening effect, with the evidence of the broken, fragmented and pull-out whiskers observed in the fracture morphologies.


2020 ◽  
Vol 4 (4) ◽  
pp. 162
Author(s):  
Mohamed Ali Charfi ◽  
Ronan Mathieu ◽  
Jean-François Chatelain ◽  
Claudiane Ouellet-Plamondon ◽  
Gilbert Lebrun

Composite materials are widely used in various manufacturing fields from aeronautic and aerospace industries to the automotive industry. This is due to their outstanding mechanical properties with respect to their light weight. However, some studies showed that the major flaws of these materials are located at the fiber/matrix interface. Therefore, enhancing matrix adhesion properties could significantly improve the overall material characteristics. This study aims to analyze the effect of graphene particles on the adhesion properties of carbon fiber-reinforced polymer (CFRP) through interlaminar shear strength (ILSS) and flexural testing. Seven modified epoxy resins were prepared with different graphene contents. The CFRP laminates were next manufactured using a method that guarantees a repeatable and consistent fiber volume fraction with a low porosity level. Short beam shear and flexural tests were performed to compare the effect of graphene on the mechanical properties of the different laminates. It was found that 0.25 wt.% of graphene filler enhanced the flexural strength by 5%, whilst the higher concentrations (2 and 3 wt.%) decreased the flexural strength by about 7%. Regarding the ILSS, samples with low concentrations (0.25 and 0.5 wt.%) demonstrated a decent increase. Meanwhile, 3 wt.% slightly decreases the ILSS.


2016 ◽  
Vol 848 ◽  
pp. 189-195
Author(s):  
Nan Nan Ni ◽  
Yue Fang Wen ◽  
De Long He ◽  
Miao Cai Guo ◽  
Xiao Su Yi

A new kind of structural damping composites was prepared by interleaving polyamide nonwoven fabrics (PNF) between the carbon fiber reinforced epoxy composite laminates. The damping behaviors of the composites made were experimentally investigated using cantilever beam test and dynamic mechanical analysis. The damping ratios of the nonwoven fabrics interleaved composites were compared with the ones of non-interleaved composites. In addition, the interlaminar shear strength and flexible modulus of the composites were also investigated, as well as the composite compression after impact (CAI), Mode I and Mode II interlaminar fracture toughness (GIC and GIIC), in order to evaluate the influence of the polyamide nonwoven fabric layers on the composite mechanical properties. It has been observed that the interleaved polyamide nonwoven fabric layers greatly improved the composite damping loss factors, and the composites containing 7 layers of PNF showed the best damping behavior. Meanwhile, the addition of PNF showed a negligible influence on the composite flexible strength and modulus and interlaminar shear strength. Most importantly, the CAI, GIC and GIIC tests indicated that the composite interlaminar toughness and impact resistance were significantly improved by the interleaved PNF. Finally, the reinforcing mechanism of this kind of composites is discussed.


2007 ◽  
Vol 546-549 ◽  
pp. 1521-1524
Author(s):  
Xiao Hu Zhang ◽  
He Jun Li ◽  
Zhi Biao Hao ◽  
Hong Cui

The influence of needling parameters on mechanical properties of carbon-carbon (C-C)composites reinforced by needled carbon cloth was studied in the present investigation. The results showed that needling density (ND)and needle-punching depth (PD) both had a larger effect on interlaminar shear strength (ILSS) than on compression strength and flexible strength of Needling C-C(NC-C). The mechanical properties of NC-C increased with increasing punching density in the range of 20-45 punch/cm2 and also with increasing punching depth range from10 to16mm. The NC-C with the highest ND value of 55punch/cm2 had highest ILSS value of 27 MPa.The optimized ND and PD parameters was 30 punch/cm2 and 12mm respectively, which resulted in a high value of tensile strength(119MPa), bending strength (220MPa) and compression strength (235 MPa) in the X-Y direction .


2017 ◽  
Vol 37 (3) ◽  
pp. 261-269 ◽  
Author(s):  
Leilei Song ◽  
Jialu Li ◽  
Yufen Zhao ◽  
Xiaoming Chen ◽  
Li Chen

Abstract In this study, the short-cut web interlayer and three-dimensional (3D) needle-punched technique were used to improve the interlaminar shear strength (ILSS) of 2.5D fabric laminated composites. The ILSS was measured by the short beam testing method, and the tensile and bending tests were carried out to investigate the in-plane mechanical properties. Observations on microstructure and crack propagation were carried out. The damage mechanisms of different 2.5D fabric laminated composites were analyzed. The results showed that the short-cut web interlayer and 3D needle-punched technique resulted in the improvement of ILSS, and they affected the tensile and bending properties of 2.5D fabric laminated composites.


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