scholarly journals Large-area display textiles integrated with functional systems

2020 ◽  
Author(s):  
Huisheng Peng ◽  
Xiang Shi ◽  
Yong Zuo ◽  
Peng Zhai ◽  
Jiahao Shen ◽  
...  
Keyword(s):  
Building Blocks ◽  
Speech Disorders ◽  
Communication Tool ◽  
Electronic Textiles ◽  
Large Area ◽  
Practical Applications ◽  
Contact Points ◽  
Luminescent Coating ◽  
And Function ◽  
The Internet Of Things

Abstract Displays are basic building blocks of modern electronics1,2. Integrating displays into textiles offers exciting opportunities for smart electronic textiles – the ultimate form of wearables poised to change the way we interact with electronic devices3-6. Display textiles serve to bridge human-machine interactions7-9, offering for instance, a real-time communication tool for individuals with voice or speech disorders. Electronic textiles capable of communicating10, sensing11,12 and supplying electricity13,14 have been reported previously. However, textiles with functional, large-area displays have not been achieved so far because obtaining small illuminating units that are both durable and easy to assemble over a wide area is challenging. Here, we report a 6 m (L) * 25 cm (W) display textile containing 500000 electroluminescent (EL) units narrowly spaced to ~800 μm. Weaving conductive weft and luminescent warp fibres forms micron-scale EL units at the weft-warp contact points. Brightness between EL units deviates by < 6.3% and remains stable even when the textile is bent, stretched or pressed. We attribute this uniform and stable lighting to the smooth luminescent coating around the warp fibres and homogenous electric field distribution at the contact points. Our display textile is flexible and breathable and withstands repeatable machine-washing, making them suitable for practical applications. We show an integrated textile system consisting of display, keyboard and power supply can serve as a communication tool, which could potentially drive the Internet of Things in various areas including healthcare. Our approach unifies the fabrication and function of electronic devices with textiles, and we expect weaving fibre materials to shape the next-generation electronics.

scholarly journals Bioelectrocatalytic hydrogels from electron-conducting metallopolypeptides coassembled with bifunctional enzymatic building blocks

2008 ◽  
Vol 105 (40) ◽  
pp. 15275-15280 ◽  
Author(s):  
Ian R. Wheeldon ◽  
Joshua W. Gallaway ◽  
Scott Calabrese Barton ◽  
Scott Banta
Keyword(s):  
Polyphenol Oxidase ◽  
Building Block ◽  
Leucine Zipper ◽  
Electrical Contact ◽  
Building Blocks ◽  
Coiled Coils ◽  
Biofuel Cell ◽  
Random Coil ◽  
Catalytic Current ◽  
And Function

Here, we present two bifunctional protein building blocks that coassemble to form a bioelectrocatalytic hydrogel that catalyzes the reduction of dioxygen to water. One building block, a metallopolypeptide based on a previously designed triblock polypeptide, is electron-conducting. A second building block is a chimera of artificial α-helical leucine zipper and random coil domains fused to a polyphenol oxidase, small laccase (SLAC). The metallopolypeptide has a helix–random-helix secondary structure and forms a hydrogel via tetrameric coiled coils. The helical and random domains are identical to those fused to the polyphenol oxidase. Electron-conducting functionality is derived from the divalent attachment of an osmium bis-bipyrdine complex to histidine residues within the peptide. Attachment of the osmium moiety is demonstrated by mass spectroscopy (MS-MALDI-TOF) and cyclic voltammetry. The structure and function of the α-helical domains are confirmed by circular dichroism spectroscopy and by rheological measurements. The metallopolypeptide shows the ability to make electrical contact to a solid-state electrode and to the redox centers of modified SLAC. Neat samples of the modified SLAC form hydrogels, indicating that the fused α-helical domain functions as a physical cross-linker. The fusion does not disrupt dimer formation, a necessity for catalytic activity. Mixtures of the two building blocks coassemble to form a continuous supramolecular hydrogel that, when polarized, generates a catalytic current in the presence of oxygen. The specific application of the system is a biofuel cell cathode, but this protein-engineering approach to advanced functional hydrogel design is general and broadly applicable to biocatalytic, biosensing, and tissue-engineering applications.

So What is this Social Unconscious Anyway?

2007 ◽  
Vol 40 (3) ◽  
pp. 307-322 ◽  
Author(s):  
Haim Weinberg
Keyword(s):  
Building Blocks ◽  
Practical Applications ◽  
Working Definition ◽  
The Social ◽  
Social Unconscious ◽  
Complex Term

Although the concept of the Social Unconscious has increased in importance in the group analytic literature recently, there are still many misconceptions and misunderstandings about it and its practical applications. While some papers define the term, there are no papers explaining the basics of the social unconscious and what it includes. The purpose of this article is to address the misconceptions, describe the basic building blocks of the social unconscious, and develop a working definition for this complex term.

A Molecular Artisans Guide to Supramolecular Coordination Complexes and Metal Organic Frameworks

2015 ◽  
Vol 03 (01n02) ◽  
pp. 1540004 ◽  
Author(s):  
Xialu Wu ◽  
David J. Young ◽  
T. S. Andy Hor
Keyword(s):  
Chemical Reactivity ◽  
Metal Organic Frameworks ◽  
Building Blocks ◽  
Coordination Complexes ◽  
Large Molecules ◽  
Molecular Building Blocks ◽  
Supramolecular Coordination ◽  
Metal Organic ◽  
Molecular Synthesis ◽  
And Function

As molecular synthesis advances, we are beginning to learn control of not only the chemical reactivity (and function) of molecules, but also of their interactions with other molecules. It is this basic idea that has led to the current explosion of supramolecular science and engineering. Parallel to this development, chemists have been actively pursuing the design of very large molecules using basic molecular building blocks. Herein, we review the general development of supramolecular chemistry and particularly of two new branches: supramolecular coordination complexes (SCCs) and metal organic frameworks (MOFs). These two fields are discussed in detail with typical examples to illustrate what is now possible and what challenges lie ahead for tomorrow's molecular artisans.

Systematic Synthesis and Applications of Novel Multi-Degree-of-Freedom Differential Systems

1992 ◽  
Author(s):  
Sridhar Kota ◽  
Srinivas Bidare
Keyword(s):  
Degrees Of Freedom ◽  
Building Blocks ◽  
Degree Of Freedom ◽  
Differential Systems ◽  
Practical Applications ◽  
Epicyclic Gear ◽  
Differential Mechanism ◽  
Long Time ◽  
Gear Trains ◽  
Drive Systems

Abstract A two-degree-of-freedom differential system has been known for a long time and is widely used in automotive drive systems. Although higher degree-of-freedom differential systems have been developed in the past based on the well-known standard differential, the number of degrees-of-freedom has been severely restricted to 2n. Using a standard differential mechanism and simple epicyclic gear trains as differential building blocks, we have developed novel whiffletree-like differential systems that can provide n-degrees of freedom, where n is any integer greater than two. Symbolic notation for representing these novel differentials is also presented. This paper presents a systematic method of deriving multi-degree-of-freedom differential systems, a three and four output differential systems and some of their practical applications.

scholarly journals Shape-Dependent Aggregation of Silver Particles by Molecular Dynamics Simulation

Crystals ◽  
2018 ◽  
Vol 8 (11) ◽  
pp. 405 ◽  
Author(s):  
Xue Wang ◽  
Chaofeng Hou ◽  
Chengxiang Li ◽  
Yongsheng Han
Keyword(s):  
Building Blocks ◽  
High Viscosity ◽  
High Energy ◽  
Dynamics Simulation ◽  
Structure Evolution ◽  
Shape Effect ◽  
Silver Particles ◽  
Large Area ◽  
Research Problems ◽  
High Possibility

In crystallization, nanoparticle aggregation often leads to the formation of orderly structures, even single crystals. Why can nanoparticles form orderly structures and what is the mechanism dominating their orderly aggregation? These questions raise interesting research problems, but the occurrences that could answer them often fail to be directly observed, since the interaction among particles is invisible. Here, we report an attempt to discover the interaction and aggregation of building blocks through a computer simulation, focusing on the shape effect of building blocks on the aggregation. Four types of silver building blocks were selected, each consisting of (100) and (111) facets, but the ratio of these two facets was different. It was found that the area of facets played an important role in selecting the aggregation mode. The facets with a large area and high energy had a high possibility of aggregation. In addition, the effects of solvent viscosity and temperature were also investigated. High viscosity and low temperature enhanced the orderliness of aggregation. This paper reports a detailed view of the aggregation process of silver nanoparticles, which is expected to be helpful in understanding the structure evolution of materials in nonclassical crystallization.

scholarly journals Development and Application of an Atmospheric Pollutant Monitoring System Based on LoRa—Part I: Design and Reliability Tests

Sensors ◽  
2018 ◽  
Vol 18 (11) ◽  
pp. 3891 ◽  
Author(s):  
Yushuang Ma ◽  
Long Zhao ◽  
Rongjin Yang ◽  
Xiuhong Li ◽  
Qiao Song ◽  
...  
Keyword(s):  
Embedded System ◽  
Communication Technology ◽  
Atmospheric Pollutant ◽  
Practical Applications ◽  
Actual Application ◽  
Pollutant Concentrations ◽  
Application Data ◽  
Software And Hardware ◽  
The Internet Of Things ◽  
Monitoring Platform

At present, as growing importance continues to be attached to atmospheric environmental problems, the demand for real-time monitoring of these problems is constantly increasing. This article describes the development and application of an embedded system for monitoring of atmospheric pollutant concentrations based on LoRa (Long Range) wireless communication technology, which is widely used in the Internet of Things (IoT). The proposed system is realized using a combination of software and hardware and is designed using the concept of modularization. Separation of each function into independent modules allows the system to be developed more quickly and to be applied more stably. In addition, by combining the requirements of the remote atmospheric pollutant concentration monitoring platform with the specific requirements for the intended application environment, the system demonstrates its significance for practical applications. In addition, the actual application data also verifies the sound application prospects of the proposed system.

ASIC and FPGA Comparative Study for IoT Lightweight Hardware Security Algorithms

2019 ◽  
Vol 28 (12) ◽  
pp. 1930009 ◽  
Author(s):  
Nagham Samir ◽  
Abdelrahman Sobeih Hussein ◽  
Mohaned Khaled ◽  
Ahmed N. El-Zeiny ◽  
Mahetab Osama ◽  
...  
Keyword(s):  
Power Consumption ◽  
Comparative Study ◽  
Authenticated Encryption ◽  
Wireless Data ◽  
Large Area ◽  
Chip Design ◽  
Iot Applications ◽  
Main Requirement ◽  
Wireless Data Transmission ◽  
The Internet Of Things

Data security, privacy and authenticity are crucial in wireless data transmission. Low power consumption is the main requirement for any chip design targeting the Internet of Things (IoT) applications. In this research paper, a comparative study of eight authenticated encryption and decryption algorithms, selected from the “Competition for Authenticated Encryption: Security, Applicability and Robustness” (CAESAR), namely, ACORN, ASCON, CLOC, JOLTIK, MORUS, PRIMATEs, SCREAM and SILC, is presented. The FPGA and ASIC implementations of these eight algorithms are synthesized, placed and routed. Power, area, latency and throughput are measured for all algorithms. All results are analyzed to determine the most suitable algorithm for IoT applications. These results show that ACORN algorithm exhibits the lowest power consumption of the eight studied at the expense of lower throughput and higher latency. MORUS algorithm gives the highest throughput among the eight selected algorithms at the expense of large area utilization.

A Dynamic Route to Structure and Function: Recent Advances in Imine-Based Organic Nanostructured Materials

2013 ◽  
Vol 66 (1) ◽  
pp. 9 ◽  
Author(s):  
Yi Liu ◽  
Zhan-Ting Li
Keyword(s):  
Self Assembly ◽  
Reaction System ◽  
Functional Materials ◽  
Building Blocks ◽  
The Self ◽  
Interlocked Molecules ◽  
Functional Aspects ◽  
Imine Bond ◽  
And Function ◽  
Dynamic Route

The chemistry of imine bond formation from simple aldehyde and amine precursors is among the most powerful dynamic covalent chemistries employed for the construction of discrete molecular objects and extended molecular frameworks. The reversible nature of the C=N bond confers error-checking and proof-reading capabilities in the self-assembly process within a multi-component reaction system. This review highlights recent progress in the self-assembly of complex organic molecular architectures that are enabled by dynamic imine chemistry, including molecular containers with defined geometry and size, mechanically interlocked molecules, and extended frameworks and polymers, from building blocks with preprogrammed steric and electronic information. The functional aspects associated with the nanometer-scale features not only place these dynamically constructed nanostructures at the frontier of materials sciences, but also bring unprecedented opportunities for the discovery of new functional materials.

scholarly journals Microhydration of ionized building blocks of DNA/RNA: infrared spectra of pyrimidine$$^{+}$$-$$(\hbox {H}_{2}\hbox {O})_{\text {1-3}}$$ clusters

2021 ◽  
Vol 75 (3) ◽  
Author(s):  
Kuntal Chatterjee ◽  
Otto Dopfer
Keyword(s):  
Density Functional ◽  
Size Range ◽  
Density Functional Theory Calculations ◽  
Building Blocks ◽  
Ion Solvation ◽  
Structure Stability ◽  
Consistent Picture ◽  
Three Body ◽  
And Function ◽  
Stable Structures

Abstract Hydration of biomolecules is an important physiological process that governs their structure, stability, and function. Herein, we probe the microhydration structure of cationic pyrimidine (Pym), a common building block of DNA/RNA bases, by infrared photodissociation spectroscopy (IRPD) of mass-selected microhydrated clusters, $$\hbox {Pym}^{+}$$ Pym + -$$\hbox {W}_{n}$$ W n (W=$$\hbox {H}_{2}\hbox {O}$$ H 2 O ), in the size range $$n=1$$ n = 1 –3. The IRPD spectra recorded in the OH and CH stretch range are sensitive to the evolution of the hydration network. Analysis with density functional theory calculations at the dispersion-corrected B3LYP-D3/aug-cc-pVTZ level provides a consistent picture of the most stable structures and their energetic and vibrational properties. The global minima of $$\hbox {Pym}^{+}$$ Pym + -$$\hbox {W}_{n}$$ W n predicted by the calculations are characterized by H-bonded structures, in which the H-bonded $$\hbox {W}_{n}$$ W n solvent cluster is attached to the most acidic C4–H proton of $$\hbox {Pym}^{+}$$ Pym + via a single CH...O ionic H-bond. These isomers are identified as predominant carrier of the IRPD spectra, although less stable local minima provide minor contributions. In general, the formation of the H-bonded solvent network (exterior ion solvation) is energetically preferred to less stable structures with interior ion solvation because of cooperative nonadditive three-body polarization effects. Progressive hydration activates the C4–H bond, along with increasing charge transfer from $$\hbox {Pym}^{+}$$ Pym + to $$\hbox {W}_{n}$$ W n , although no proton transfer is observed in the size range $$n\leqslant $$ n ⩽ 3. The solvation with protic, dipolar, and hydrophilic W ligands is qualitative different from solvation with aprotic, quadrupolar, and hydrophobic $$\hbox {N}_{2}$$ N 2 ligands, which strongly prefer interior ion solvation by $$\uppi $$ π stacking interactions. Comparison of $$\hbox {Pym}^{+}$$ Pym + -W with Pym-W and $$\hbox {H}^{+}$$ H + Pym-W reveals the drastic effect of ionization and protonation on the Pym...W interaction. Graphic Abstract

scholarly journals NetFACS: Using network science to understand facial communication systems

2021 ◽  
Author(s):  
Alexander Mielke ◽  
Bridget M. Waller ◽  
Claire Pérez ◽  
Alan V. Rincon ◽  
Julie Duboscq ◽  
...  
Keyword(s):  
Network Analysis ◽  
Communication Systems ◽  
Network Science ◽  
Coding System ◽  
Communication Tool ◽  
Resampling Methods ◽  
Facial Movements ◽  
The Face ◽  
Analyse Data ◽  
And Function

AbstractUnderstanding facial signals in humans and other species is crucial for understanding the evolution, complexity, and function of the face as a communication tool. The Facial Action Coding System (FACS) enables researchers to measure facial movements accurately, but we currently lack tools to reliably analyse data and efficiently communicate results. Network analysis can provide a way to use the information encoded in FACS datasets: by treating individual AUs (the smallest units of facial movements) as nodes in a network and their co-occurrence as connections, we can analyse and visualise differences in the use of combinations of AUs in different conditions. Here, we present ‘NetFACS’, a statistical package that uses occurrence probabilities and resampling methods to answer questions about the use of AUs, AU combinations, and the facial communication system as a whole in humans and non-human animals. Using highly stereotyped facial signals as an example, we illustrate some of the current functionalities of NetFACS. We show that very few AUs are specific to certain stereotypical contexts; that AUs are not used independently from each other; that graph-level properties of stereotypical signals differ; and that clusters of AUs allow us to reconstruct facial signals, even when blind to the underlying conditions. The flexibility and widespread use of network analysis allows us to move away from studying facial signals as stereotyped expressions, and towards a dynamic and differentiated approach to facial communication.

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