New anaerobic process of nitrogen removal

2006 ◽  
Vol 54 (8) ◽  
pp. 163-170 ◽  
Author(s):  
S. Kalyuzhnyi ◽  
M. Gladchenko ◽  
A. Mulder ◽  
B. Versprille
Keyword(s):  
Activated Sludge ◽  
Electron Donor ◽  
Nitrogen Removal ◽  
Laboratory Testing ◽  
Oxidation Reaction ◽  
Loading Rate ◽  
Nitrogen Loading ◽  
Ammonium Oxidation ◽  
Conventional Activated Sludge ◽  
Activated Sludge Systems

This paper reports on successful laboratory testing of a new nitrogen removal process called DEAMOX (DEnitrifying AMmonium OXidation) for the treatment of strong nitrogenous wastewater such as baker's yeast effluent. The concept of this process combines the recently discovered ANAMMOX (ANaerobic AMMonium OXidation) reaction with autotrophic denitrifying conditions using sulfide as an electron donor for the production of nitrite within an anaerobic biofilm. The achieved results with a nitrogen loading rate of higher than 1, 000 mg/L/d and nitrogen removal of around 90% look very promising because they exceed (by 9–18 times) the corresponding nitrogen removal rates of conventional activated sludge systems. The paper describes also some characteristics of DEAMOX sludge, as well as the preliminary results of its microbiological characterization.

scholarly journals Autotrophic ammonia removal from landfill leachate using anaerobic membrane bioreactor

2017 ◽  
Author(s):  
S. Suneethi ◽  
Kurian Joseph
Keyword(s):  
Nitrogen Removal ◽  
Landfill Leachate ◽  
Membrane Bioreactor ◽  
Loading Rate ◽  
Ammonia Removal ◽  
Nitrogen Loading ◽  
Ammonium Oxidation ◽  
Anaerobic Membrane Bioreactor ◽  
N Removal ◽  
Anammox Process

Anaerobic Membrane Bioreactor (AnMBR) is an innovative high cell density system having complete biomass retention, high reactor loading and low sludge production and suitable for developing slow growing autotrophic bacterial cultures such as ANAMMOX. The Anaerobic Ammonium Oxidation (ANAMMOX) process is an advanced biological nitrogen removal removes ammonia using nitrite as the electron acceptor without oxygen. The NH4+-N in the landfill leachate that is formed due to the release of nitrogen from municipal solid waste (MSW), when discharged untreated, into the surface water can result in eutrophication, aquatic toxicity and emissions of nitrous oxide (N2O) to atmosphere. Besides, NH4+-N accumulation in landfills poses long term pollution issue with significant interference during post closure thereby requiring its removal prior to ultimate disposal into inland surface waters. The main objective of this study was to investigate the feasibility and treatment efficiency of treating landfill leachate (to check) for removing NH4+-N by adopting ANAMMOX process in AnMBR. The AnMBR was optimized for Nitrogen Loading Rate (NLR) varying from 0.025 to 5 kg NH4+-N/ m3/ d with hydraulic retention time (HRT) ranging from 1 to 3 d. NH4+-N removal efficacy of 85.13 ± 9.67% with the mean nitrogen removal rate (NRR) of 5.54 ± 0.63 kg NH4+-N/ m3/ d was achieved with nitrogen loading rate (NLR) of 6.51 ± 0.20 kg NH4+- N/ m3/ d at 1.5 d HRT. The nitrogen transformation intermediates in the form of hydrazine (N2H4) and hydroxylamine (NH2OH) were 0.008 ± 0.005 mg/L and 0.006 ± 0.001 mg/L, respectively, indicating co-existence of aerobic ammonia oxidizers (AOB) and ANAMMOX. The free ammonia (NH3) and free nitrous acid (HNO2) concentrations were 26.61 ± 16.54 mg/L and (1.66 ± 0.95) x 10-5 mg/L, preventing NO2--N oxidation to NO3--N enabling sustained NH4+- N removal.

scholarly journals Anammox biofilm process using sugarcane bagasse as an organic carrier

2021 ◽  
Vol 26 (1) ◽  
pp. 25
Author(s):  
Zulkarnaini Zulkarnaini ◽  
Puti Sri Komala ◽  
Arief Almi
Keyword(s):  
Sugarcane Bagasse ◽  
Nitrogen Removal ◽  
Removal Rate ◽  
Nitrogen Loading ◽  
Uasb Reactor ◽  
Anaerobic Sludge ◽  
Ammonium Oxidation ◽  
Biofilm Process ◽  
Anaerobic Sludge Blanket ◽  
Anammox Process

The anaerobic ammonium oxidation (anammox) biofilm process commonly uses various inorganic carriers to enhance nitrogen removal under anaerobic conditions. This study aims to analyze the performance of nitrogen removal in anammox process using sugarcane bagasse as an organic carrier. The experiment was carried out by using an up‐flow anaerobic sludge blanket (UASB) reactor for treating artificial wastewater at room temperature. The reactor was fed with ammonium and nitrite with the concentrations of 70‐150 mg–N/L and variations in the hydraulic retention time of 24 and 12 h. The granular anammox belongs to the genus Candidatus Brocadia sinica that was added as an inoculum of the reactor operation. The experimental stoichiometric of anammox for ΔNO2‐–N: ΔNH4+–N and ΔNO3‐: ΔNH4+ were 1.24 and 0.18, respectively, which is similar to anammox stoichiometry. The maximum Nitrogen Removal Rate (NRR) has achieved 0.29 kg–N/m3.d at Nitrogen Loading Rate (NLR) 0.6 kg–N/m3.d. The highest ammonium conversion efficiency (ACE) and nitrogen removal efficiency (NRE) were 88% and 85%, respectively. Based on this results, it indicated that sugarcane bagasse as organic carriers could increase the amount of total nitrogen removal by provided of denitrification process but inhibited the anammox process at a certain COD concentration.

Nitrogen removal in activated sludge systems including denitrification in secondary clarifiers

1994 ◽  
Vol 30 (6) ◽  
pp. 101-111 ◽  
Author(s):  
H. Siegrist ◽  
W. Gujer
Keyword(s):  
Activated Sludge ◽  
Nitrogen Removal ◽  
Retention Time ◽  
Secondary Clarifier ◽  
Solids Retention Time ◽  
Solids Retention ◽  
Activated Sludge Systems

Denitrification in the secondary clarifier can contribute substantially to the nitrogen removal of activated sludge systems. This is illustrated on two treatment plants with different secondary clarifier systems. A model to estimate denitrification capacity and to design activated sludge systems for nitrogen removal is developed and verified with data from two treatment plants. The model includes denitrification in the secondary clarifier, wastewater composition (soluble readily biodegradable COD, particulate degradable COD), oxygen input into the anoxic volume, temperature, and solids retention time (SRT). The influence of aerated grit chambers and primary sedimentation on denitrification is discussed.

New approaches to minimize excess sludge in activated sludge systems

2001 ◽  
Vol 44 (10) ◽  
pp. 203-208 ◽  
Author(s):  
G.-H. Chen ◽  
S. Saby ◽  
M. Djafer ◽  
H.-K. Mo
Keyword(s):  
Activated Sludge ◽  
Activated Sludge Process ◽  
Conventional System ◽  
Excess Sludge ◽  
Active Sludge ◽  
New Approaches ◽  
Conventional Activated Sludge ◽  
Sludge Settleability ◽  
Activated Sludge Systems ◽  
Sludge Production

This paper presents three new approaches to reduce excess sludge production in activated sludge systems: 1) modification of conventional activated sludge process with insertion of a sludge holding tank in the sludge return line; 2) chlorination of excess sludge so as to minimize excess sludge production; and 3) utilization of a metabolic uncoupler, 3, 3′, 4′, 5-Tetrachlorosalicylanilide (TCS) to maximize futile activity of sludge microorganisms thereby leading to a reduction of sludge growth. Pilot study was carried out to evaluate this modified activated sludge process (OSA). It has been confirmed that the OSA process is effective in reducing excess sludge; particularly when the ORP level in the sludge holding tank was kept at -250 mV, more than 50% of the excess sludge was reduced. This process can maintain the effluent quality and even perform with a better sludge settleability than a conventional system. Experimental work on the second approach showed that chlorination treatment of excess sludge at a chlorine dose of 0.066 g Cl2/g MLSS reduced the excess sludge by 60%, while concentration of THMS was found below 200 ppb in the treated sludge. However, such sludge chlorination treatment sacrificed sludge settleability. Thus, it is not feasible to introduce the chlorination step to a conventional system. The third approach confirmed that addition of TCS could reduce sludge growth effectively if the TCS concentration is greater than 0.4 ppm. A 0.8-ppm concentration of TCS actually reduced excess sludge by 45%. It was also experimentally demonstrated that presence of TCS increases the portion of active sludge microorganisms over the entire microbial population.

Assessment of Inocula and N-Removal Performance of Anaerobic Ammonium Oxidation (ANAMMOX) for the Treatment of Aged Landfill Leachates

2012 ◽  
Vol 518-523 ◽  
pp. 2391-2398
Author(s):  
Yan He ◽  
Gong Ming Zhou ◽  
Min Sheng Huang ◽  
Min Tong
Keyword(s):  
Activated Sludge ◽  
Nitrogen Removal ◽  
Removal Rate ◽  
Granular Sludge ◽  
Nitrogen Loading ◽  
Anaerobic Granular Sludge ◽  
Landfill Leachates ◽  
N Removal ◽  
Start Up ◽  
Anammox Process

Three kinds of seeding sludge, i.e. conventional activated sludge, anaerobic granular sludge and the nitrifying activated sludge from the nitritation reactor treating aged leachates were evaluated in batch mode to screen the optimized inoculum for the rapid start-up of ANAMMOX reactor. The feasibility of the ANAMMOX process for the treatment of aged leachates was also investigated in a modified upflow anaerobic sludge blanket (UASB, 0.05m3). The batch experiments revealed that the nitrifying activated sludge from the nitritation reactor could respectively achieve the NRR (nitrogen removal rate) of 0.0365 kg N/(m3.d) and the ARR (ammonium removal rate) of 0.013 kg N/(m3.d) on day 12, which were greatly higher than those of the other two tested sludge samples. The mixture of the aforementioned nitrifying activated sludge and anaerobic granular sludge was established as an effective inoculum for the prompt start-up of ANAMMOX reactor. The maximum total nitrogen removal rate of 0.826 kg N/(m3.d) could be obtained for the treatment of “old” leachates under NLR (nitrogen loading rate) of 1.028 kg N/(m3.d). It is concluded that the N-removal performance of ANAMMOX process is still to be improved for actual engineering application to aged landfill leachates.

Oxygen transfer in activated sludge – new insights and potentials for cost saving

2011 ◽  
Vol 63 (12) ◽  
pp. 3034-3038 ◽  
Author(s):  
J. Henkel ◽  
P. Cornel ◽  
M. Wagner
Keyword(s):  
Activated Sludge ◽  
Nutrient Removal ◽  
Oxygen Transfer ◽  
Transfer Rate ◽  
Oxygen Transfer Rate ◽  
Organic Load ◽  
Current Opinion ◽  
Conventional Activated Sludge ◽  
Current State ◽  
Activated Sludge Systems

The α-factor has the greatest impact on the calculation of the required standard oxygen transfer rate (SOTR) in activated sludge systems equipped with submerged aeration systems. Knowing the dependencies of the α-factor leads to a better design of the aeration devices and, consequently, to a more efficient use of aeration energy. Applying the current state of knowledge about oxygen transfer leads to the conclusion that, in contrast to current opinion, simultaneous aerobic stabilization requires the same SOTR as conventional activated sludge systems with advanced nutrient removal, even though a higher organic load is degraded.

A membrane bioreactor for an innovative biological nitrogen removal process

2010 ◽  
Vol 61 (3) ◽  
pp. 671-676 ◽  
Author(s):  
W. Chen ◽  
F. Y. Sun ◽  
X. M. Wang ◽  
X. Y. Li
Keyword(s):  
Total Nitrogen ◽  
Nitrogen Removal ◽  
Membrane Bioreactor ◽  
Loading Rate ◽  
Nitrogen Loading ◽  
Synthetic Wastewater ◽  
Biological Nitrogen Removal ◽  
Laboratory System ◽  
Working Volume ◽  
Biological Nitrogen

A hybrid system has been developed for biological nitrogen removal through nitrification-denitrification. The system includes an aerobic tank and an anoxic tank with an intermediate sludge settler connected to a membrane bioreactor (MBR) with a submerged 0.4 μm hollow-fiber membrane module. The laboratory system has a total working volume of 6.5 L treating a glucose-based synthetic wastewater. The experimental results demonstrate that the new process is highly effective for simultaneous organic and nitrogen removal. During the stationary operation, a sludge SS (suspended solids) concentration of 6 g/L or higher can be maintained in the reactors. The system has a COD (chemical oxygen demand) loading rate of up to 2,100 mg/L-d and a total nitrogen loading rate of up to 170 mg N/L-d. More than 95% COD can be degraded, and the total nitrogen removal efficiency can be 90% or higher as the nitrogen is reduced from 100 to around 7.5 mg/L. A high quality effluent is produced with a SS of less than 1 mg/L. With the MBR, organic degradation, nitrogen removal and sludge-liquid separation can be well achieved within a short HRT of about 10 hr.

Sign in / Sign up

Export Citation Format

Share Document