Industrial Applications of Reactive Distillation: Recent Trends

Author(s):  
Rameshwar S Hiwale ◽  
Nitin V Bhate ◽  
Yogesh S Mahajan ◽  
Sanjay M. Mahajani

Last few years have seen a dramatic rise in the number of applications of reactive distillation (RD). This useful technology is now being applied for any scale of operation- from manufacture of fine chemicals to that of bulk chemicals. This article reviews the very recent applications and serves as a supplement for the exhaustive review on this subject by Sharma and Mahajani (2003). It not only furnishes the information on the ongoing research in the existing applications but also elaborates the newly discovered applications such as manufacture of phenol, linear alkyl benzene, carbonates, chlorosilane derivatives and chiral chemicals. Multiple reactions in RD, failure of RD in some cases and new RD configurations to increase the overall yields are some of the additional aspects being covered.

2019 ◽  
Vol 19 (2) ◽  
pp. 114-118
Author(s):  
Gian Luigi Mariottini ◽  
Irwin Darren Grice

Natural compounds extracted from organisms and microorganisms are an important resource for the development of drugs and bioactive molecules. Many such compounds have made valuable contributions in diverse fields such as human health, pharmaceutics and industrial applications. Presently, however, research on investigating natural compounds from marine organisms is scarce. This is somewhat surprising considering that the marine environment makes a major contribution to Earth's ecosystems and consequently possesses a vast storehouse of diverse marine species. Interestingly, of the marine bioactive natural compounds identified to date, many are venoms, coming from Cnidarians (jellyfish, sea anemones, corals). Cnidarians are therefore particularly interesting marine species, producing important biological compounds that warrant further investigation for their development as possible therapeutic agents. From an experimental aspect, this review aims to emphasize and update the current scientific knowledge reported on selected biological activity (antiinflammatory, antimicrobial, antitumoral, anticoagulant, along with several less studied effects) of Cnidarian venoms/extracts, highlighting potential aspects for ongoing research towards their utilization in human therapeutic approaches.


Molecules ◽  
2021 ◽  
Vol 26 (15) ◽  
pp. 4466
Author(s):  
Pablo Domínguez de María

Nitriles comprise a broad group of chemicals that are currently being industrially produced and used in fine chemicals and pharmaceuticals, as well as in bulk applications, polymer chemistry, solvents, etc. Aldoxime dehydratases catalyze the cyanide-free synthesis of nitriles starting from aldoximes under mild conditions, holding potential to become sustainable alternatives for industrial processes. Different aldoxime dehydratases accept a broad range of aldoximes with impressive high substrate loadings of up to >1 Kg L−1 and can efficiently catalyze the reaction in aqueous media as well as in non-aqueous systems, such as organic solvents and solvent-free (neat substrates). This paper provides an overview of the recent developments in this field with emphasis on strategies that may be of relevance for industry and sustainability. When possible, potential links to biorefineries and to the use of biogenic raw materials are discussed.


2021 ◽  
Vol 13 (5) ◽  
pp. 168781402110217
Author(s):  
Raj Shah ◽  
Blerim Gashi ◽  
Sergio González-Poggini ◽  
Melanie Colet-Lagrille ◽  
Andreas Rosenkranz

Future progress in hybrid and battery vehicles heavily relies on the optimization of involved battery components and lubricants. Attention must specifically be given to the material composition and surface coatings of the electrodes as well as the electrolyte used to maximize energy output, while also ensuring safety. Additionally, prioritizing the effective utilization of specific lubricants for electric motors and various tribological contacts, such as wheel bearings and the steering system, is the prospective goal of lubrication research. The energy output of the most promising battery, the Li-ion battery (LIB), must result in driving ranges, which can compete with the 600 km driving range of combustion engine (ICE) vehicles. Consequently, ongoing research activities in cell chemistry, electrode surface engineering, electrolyte engineering, and engine lubrication offer the greatest opportunity in achieving these goals.


2012 ◽  
Vol 67 (10) ◽  
pp. 961-975 ◽  
Author(s):  
Markus Hölscher ◽  
Christoph Gürtler ◽  
Wilhelm Keim ◽  
Thomas E. Müller ◽  
Martina Peters ◽  
...  

With the growing perception of industrialized societies that fossil raw materials are limited resources, academic chemical research and chemical industry have started to introduce novel catalytic technologies which aim at the development of economically competitive processes relying much more strongly on the use of alternative carbon feedstocks. Great interest is given world-wide to carbon dioxide (CO2) as it is part of the global carbon cycle, nontoxic, easily available in sufficient quantities anywhere in the industrialized world, and can be managed technically with ease, and at low cost. In principle carbon dioxide can be used to generate a large variety of synthetic products ranging from bulk chemicals like methanol and formic acid, through polymeric materials, to fine chemicals like aromatic acids useful in the pharmaceutical industry. Owing to the high thermodynamic stability of CO2, the energy constraints of chemical reactions have to be carefully analyzed to select promising processes. Furthermore, the high kinetic barriers for incorporation of CO2 into C-H or C-C bond forming reactions require that any novel transformation of CO2 must inevitably be associated with a novel catalytic technology. This short review comprises a selection of the most recent academic and industrial research developments mainly with regard to innovations in CO2 chemistry in the field of homogeneous catalysis and processes.


2004 ◽  
Vol 20 (03) ◽  
pp. 200-210 ◽  
Author(s):  
Frank Roland ◽  
Luciano Manzon ◽  
Pentti Kujala ◽  
Markus Brede ◽  
Jan Weitzenbock

Joining processes are an important key factor for the competitiveness of European shipbuilders. They not only represent a significant portion of the total man hour consumption in hull production and outfitting, but due to heat distortions they also have a significant impact on nonproductive work operations, such as straightening and fitting. Those operations can interfere with on-board outfitting and increase lead time and construction cost. In addition to their contribution to shipyard productivity, joining techniques have a significant impact on material properties and thus on product performance and quality. Those factors become increasingly important for complex structures using comparatively thin and high-strength materials. Considering the importance of efficient joining, European shipbuilders in the past decade have invested significant efforts to develop new joining techniques, such as laser welding, adhesive bonding, and mechanical joining. Based on research results, practical industrial applications have been developed recently. After reviewing the impact of joining processes on competitiveness, the article will summarize a number of past and ongoing research projects with special focus on design methods, process and equipment development, fatigue strength of joints, quality assurance, and approval. It will then present a number of recent applications of new joining techniques in European shipyards. Finally, open problems and future research needs will be briefly discussed. The article is based on a joint effort of leading European experts and will focus on laser and laser hybrid welding, adhesive bonding, and mechanical joining


2001 ◽  
Vol 56 (2) ◽  
pp. 387-394 ◽  
Author(s):  
A Tuchlenski ◽  
A Beckmann ◽  
D Reusch ◽  
R Düssel ◽  
U Weidlich ◽  
...  

2014 ◽  
Vol 792 ◽  
pp. 3-14
Author(s):  
Athanasios G. Mamalis

Some of the activities of the Project Center for Nanotechnology and Advanced Engineering (PC-NAE), a joint initiative of the Greek National Center for Scientific Research Demokritos and the Russian Research Center Kurchatov Institute, in advanced manufacturing engineering are briefly outlined, focusing onto some recent trends and developments in manufacturing from macro-, micro-, to nanoscale of advanced materials in the important engineering topics nowadays from industrial, research and academic point of view: nanotechnology/ultraprecision engineering and advanced materials under shock loading, with industrial applications to net-shape manufacturing, bioengineering, energy and transport.


2021 ◽  
Vol 12 ◽  
Author(s):  
Wentao Yao ◽  
Kaiquan Liu ◽  
Hongling Liu ◽  
Yi Jiang ◽  
Ruiming Wang ◽  
...  

As a powerful factory, microbial cells produce a variety of enzymes, such as lipase. Lipase has a wide range of actions and participates in multiple reactions, and they can catalyze the hydrolysis of triacylglycerol into its component free fatty acids and glycerol backbone. Lipase exists widely in nature, most prominently in plants, animals and microorganisms, among which microorganisms are the most important source of lipase. Microbial lipases have been adapted for numerous industrial applications due to their substrate specificity, heterogeneous patterns of expression and versatility (i.e., capacity to catalyze reactions at the extremes of pH and temperature as well as in the presence of metal ions and organic solvents). Now they have been introduced into applications involving the production and processing of food, pharmaceutics, paper making, detergents, biodiesel fuels, and so on. In this mini-review, we will focus on the most up-to-date research on microbial lipases and their commercial and industrial applications. We will also discuss and predict future applications of these important technologies.


Polymers ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 953 ◽  
Author(s):  
Fan-Long Jin ◽  
Miao Zhao ◽  
Mira Park ◽  
Soo-Jin Park

Polymer foams have low density, good heat insulation, good sound insulation effects, high specific strength, and high corrosion resistance, and are widely used in civil and industrial applications. In this paper, the classification of polymer foams, principles of the foaming process, types of blowing agents, and raw materials of polymer foams are reviewed. The research progress of various foaming methods and the current problems and possible solutions are discussed in detail.


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