scholarly journals A model of crystal-size evolution in polar ice masses

2014 ◽  
Vol 60 (221) ◽  
pp. 463-477 ◽  
Author(s):  
Felix NG ◽  
T.H. Jacka

AbstractIn the deep ice cores drilled at the GRIP, NGRIP and GISP2 sites in Greenland and at Byrd Station and the summit of Law Dome in Antarctica, the mean crystal size increases with depth in the shallow subsurface and reaches steady values at intermediate depth. This behaviour has been attributed to the competition between grain-boundary migration driven crystal growth and crystal polygonization, but the effects of changing crystal dislocation density and non-equiaxed crystal shape in this competition are uncertain. We study these effects with a simple model. It describes how the mean height and width of crystals evolve as they flatten under vertical compression, and as crystal growth and polygonization compete. The polygonization rate is assumed to be proportional to the mean dislocation density across crystals. Migration recrystallization, which can affect crystal growth via strain-induced grain boundary migration but whose impact on the mean crystal size is difficult to quantify for ice at present, is not accounted for. When applied to the five ice-core sites, the model simulates the observed crystal-size profiles well down to the bottom of their steady regions, although the match for Law Dome is less satisfactory. Polygonization rate factors retrieved for the sites range from 10–5 to 10–2 a–1. We conclude that since crystal size and dislocation density evolve in a strongly coupled manner, consistent modelling requires multiple differential equations to track both of these variables. Future ice-core analysis should also determine crystal size in all three principal directions.

2004 ◽  
Vol 39 ◽  
pp. 49-52 ◽  
Author(s):  
Luca Placidi ◽  
Sérgio H. Faria ◽  
Kolumban Hutter

AbstractWe outline how to incorporate microscale effects of polycrystalline ice into a continuum description. Actually, analyses of ice cores in Antarctica show that different microstructures generally produce different responses, i.e. a non-uniform distribution of c axes gives rise to anisotropic behaviour. It has been recognized that, to describe certain microstructural processes, like recrystallization or polygonization, we need a parameter able to switch them on (e.g. dislocation density or its associated lattice distortion energy). With this in mind, balance equations for a continuum theory of an anisotropic ice sheet undergoing recrystallization have been recently proposed. In this work, we examine relations for some constitutive quantities, in order to take into account the effects of grain-boundary migration, nucleation and polygonization. We check our assumptions by explicit comparison with the first 1200 m of the Byrd (Antarctica) ice core. Current literature usually gives a relation between normal grain growth and grain boundary migration rate. Here, an equation for normal grain growth which also incorporates the influence of polygonization is suggested. It is based on experimental data from the same core in Antarctica. Polygonization is a microscopic process, but here we present a continuum description of the bending stresses which promote the fragmentation of crystallites in terms of the theory of mixtures with continuous diversity.


Anales AFA ◽  
2019 ◽  
Vol Vol.30 (Vol.30 N.2) ◽  
pp. 25-30
Author(s):  
P. I. Achával ◽  
C. A. Rodríguez Luca ◽  
C. L. Di Prinzio

In this work, the evolution of a tridimensional (3D) spherical crystal with mobile particles using a Monte Carlo algorithm is presented. The mean radius R of spherical crystal without particles changes according to the law: R2 = -4kt + Ro2, where Ro is the initial radius and k is a crystal constant. However, this law is modified when mobile particles are included. The effect of two types of mobile particles on the grain boundary migration of a spherical grain was also studied. One type of particle remained located in the middle of the grain boundary once it was incorporated (CT), and the other type of particle remained at the grain boundary without having any particular location (NC). It could be seen that the CT particle slowed down more the grain boundary migration than the NC particles. It was also found that the rate of reduction of the grain area is inversely proportional to the concentration of CT particles in the grain boundary for all the CT particles concentrations. Finally, it was established that the grain reaches a limit radius for CT particles which is related to the amount of particles that can be accommodated in the grain boundary.


2013 ◽  
Vol 753 ◽  
pp. 481-484 ◽  
Author(s):  
Tobias Binder ◽  
Ilka Weikusat ◽  
Johannes Freitag ◽  
Christoph S. Garbe ◽  
Dietmar Wagenbach ◽  
...  

Ice cores through an ice sheet can be regarded as a sample of a unique natural deformation experiment lasting up to a million years. Compared to other geological materials forming the earth‘s crust, the microstructure is directly accessible over the full depth. Controlled sublimation etching of polished ice sections reveals pores, air bubbles, grain boundaries and sub-grain boundaries at the surface. The microstructural features emanating at the surface are scanned. A dedicated method of digital image processing has been developed to extract and characterize the grain boundary networks. First preliminary results obtained from an ice core drilled through the Greenland ice sheet are presented. We discuss the role of small grains in grain size analysis and derive from the shape of grain boundaries the acting driving forces for grain boundary migration.


Author(s):  
D. B. Williams ◽  
A. D. Romig

The segregation of solute or imparity elements to grain boundaries can occur by three well-defined processes. The first is Gibbsian segregation in which an element of minimal matrix solubility confines itself to a monolayer at the grain boundary. Classical examples include Bi in Cu and S or P in Fe. The second process involves the depletion of excess matrix solute by volume diffusion to the boundary. In the boundary, the solute atoms diffuse rapidly to precipitates, causing them to grow by the ‘collector-plate mechanism.’ Such grain boundary diffusion is thought to initiate “Diffusion-Induced Grain Boundary Migration,” (DIGM). This process has been proposed as the origin of eutectoid transformations or discontinuous grain boundary reactions. The third segregation process is non-equilibrium segregation which result in a solute build-up around the boundary because of solute-vacancy interactions.All of these segregation phenomena usually occur on a sub-micron scale and are often affected by the nature of the grain boundary (misorientation, defect structure, boundary plane).


Author(s):  
K. Vasudevan ◽  
H. P. Kao ◽  
C. R. Brooks ◽  
E. E. Stansbury

The Ni4Mo alloy has a short-range ordered fee structure (α) above 868°C, but transforms below this temperature to an ordered bet structure (β) by rearrangement of atoms on the fee lattice. The disordered α, retained by rapid cooling, can be ordered by appropriate aging below 868°C. Initially, very fine β domains in six different but crystallographically related variants form and grow in size on further aging. However, in the temperature range 600-775°C, a coarsening reaction begins at the former α grain boundaries and the alloy also coarsens by this mechanism. The purpose of this paper is to report on TEM observations showing the characteristics of this grain boundary reaction.


Anales AFA ◽  
2019 ◽  
Vol 30 (3) ◽  
pp. 47-51
Author(s):  
P.I. Achával ◽  
C. L. Di Prinzio

In this paper the migration of a grain triple junction in apure ice sample with bubbles at -5°C was studied for almost 3hs. This allowed tracking the progress of the Grain Boundary (BG) and its interaction with the bubbles. The evolution of the grain triple junction was recorded from successive photographs obtained witha LEICA® optical microscope. Simultaneously, numerical simulations were carried out using Monte Carlo to obtain some physical parameters characteristic of the BG migration on ice.


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