scholarly journals Thermoplastic Reaction Injection Pultrusion for Continuous Glass Fiber-Reinforced Polyamide-6 Composites

Materials ◽  
2019 ◽  
Vol 12 (3) ◽  
pp. 463 ◽  
Author(s):  
Ke Chen ◽  
Mingyin Jia ◽  
Hua Sun ◽  
Ping Xue

In this paper, glass fiber-reinforced polyamide-6 (PA-6) composites with up to 70 wt% fiber contents were successfully manufactured using a pultrusion process, utilizing the anionic polymerization of caprolactam (a monomer of PA-6). A novel thermoplastic reaction injection pultrusion test line was developed with a specifically designed injection chamber to achieve complete impregnation of fiber bundles and high speed pultrusion. Process parameters like temperature of injection chamber, temperature of pultrusion die, and pultrusion speed were studied and optimized. The effects of die temperature on the crystallinity, melting point, and mechanical properties of the pultruded composites were also evaluated. The pultruded composites exhibited the highest flexural strength and flexural modulus, reaching 1061 MPa and 38,384 MPa, respectively. Then, effects of fiber contents on the density, heat distortion temperature, and mechanical properties of the composites were analyzed. The scanning electron microscope analysis showed the great interfacial adhesion between fibers and matrix at 180 °C, which greatly improved the mechanical properties of the composites. The thermoplastic reaction injection pultrusion in this paper provided an alternative for the preparation of thermoplastic composites with high fiber content.

2022 ◽  
Author(s):  
Chunhua Wang ◽  
Yingwei Zhang ◽  
Yong Yi ◽  
Dengwang Lai ◽  
Jun Yang ◽  
...  

2020 ◽  
Vol 54 (27) ◽  
pp. 4231-4239
Author(s):  
Vishal Gavande ◽  
Anoop Anand

Continuous glass fiber reinforced thermoplastic composites have been manufactured and their mechanical properties have been evaluated. A catalyzed monomer is infused through a stack of compacted dry reinforcement under vacuum. The monomer undergoes radical polymerization with a peroxide catalyst. Viscosity and reactivity profile have been characterized to determine the catalyst concentration and temperature of infusion. Glass fiber reinforced thermoplastic composites realized through this method have mechanical properties that are comparable with that of epoxy with an added advantage of excellent toughness and repairability. For example, the residual compressive strength of thermoplastic composites after low-velocity impact is found to be over 140% more than that of epoxy-based composites using the same reinforcement and realized under identical manufacturing methods.


1997 ◽  
Vol 12 (2) ◽  
pp. 116-122 ◽  
Author(s):  
S. Nagae ◽  
K. Nagura ◽  
N. Yamagiwa ◽  
Y. Yamane ◽  
K. Miyake ◽  
...  

Polymers ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 2019 ◽  
Author(s):  
Junjia Cui ◽  
Shaoluo Wang ◽  
Shuhao Wang ◽  
Guangyao Li ◽  
Peilin Wang ◽  
...  

Long glass fiber reinforced thermoplastic composites have been increasingly used in automotive parts due to their excellent mechanical properties and recyclability. However, the effects of strain rates on the mechanical properties and failure mechanisms of long glass fiber reinforced polypropylene composites (LGFRPPs) have not been studied systematically. In this study, the effects of strain rates (from 0.001 s−1 to 400 s−1) on the mechanical properties and failure mechanism of LGFRPPs were investigated. The results showed that ultimate strength and fracture strain of the LGFRPPs increased obviously, whereas the stiffness remained essentially unchanged with the strain rates from low to high. The micro-failure modes mainly consisted of fibers pulled out, fiber breakage, interfacial debonding, matrix cracking, and ductile to brittle (ductile pulling of fibrils/micro-fibrils) fracture behavior of the matrix. As the strain rates increased, the interfacial bonding properties of LGFRPPs increased, resulting in a gradual increase of fiber breakage at the fracture surface of the specimen and the gradual decrease of pull-out. In this process, more failure energy was absorbed, thus, the ultimate strength and fracture strain of LGFRPPs were improved.


2021 ◽  
Vol 1028 ◽  
pp. 223-227
Author(s):  
Salman Farishi ◽  
Retno Wulandari ◽  
Annisa Rifathin ◽  
Dasep Rusmana ◽  
Nurul Jamilah

This paper presents the effect of accelerated salt spray (fog) exposure on commercially glass fiber reinforced polyester composite to determine the durability of the material. Aging behavior after exposure in the salt-spray environment was studied by mechanical properties i.e. flexural stress and flexural modulus. The accelerated salt spray exposure was conducted by Copper-Accelerated Acetic Acid Salt Spray (CASS) Test according to ASTM B368. The CASS exposure was carried out for 120 hours and observed every 24 hours. The flexural modulus results tend to be constant up to 4 days and more significant change on 5th day of measurement. Furthermore, the morphology of specimens investigated by a Scanning Electron Microscopy (SEM). The SEM results also showed that only scratch occurred on the surface of the specimens test. The longer of the CASS exposure time, the higher the number of scratches. From this study, it could be concluded that Glass Fiber Reinforced Polyester Composite has slightly damage for 120 hours CASS test exposure.


Polymers ◽  
2020 ◽  
Vol 12 (5) ◽  
pp. 1041 ◽  
Author(s):  
Francisco J. Alonso-Montemayor ◽  
Quim Tarrés ◽  
Helena Oliver-Ortega ◽  
F. Xavier Espinach ◽  
Rosa Idalia Narro-Céspedes ◽  
...  

Automotive and industrial design companies have profusely used commodity materials like glass fiber-reinforced polypropylene. These materials show advantageous ratios between cost and mechanical properties, but poor environmental yields. Natural fibers have been tested as replacements of glass fibers, obtaining noticeable tensile strengths, but being unable to reach the strength of glass fiber-reinforced composites. In this paper, polyamide 6 is proposed as a matrix for cellulosic fiber-based composites. A variety of fibers were tensile tested, in order to evaluate the creation of a strong interphase. The results show that, with a bleached hardwood fiber-reinforced polyamide 6 composite, it is possible to obtain tensile strengths higher than glass-fiber-reinforced polyolefin. The obtained composites show the existence of a strong interphase, allowing us to take advantage of the strengthening capabilities of such cellulosic reinforcements. These materials show advantageous mechanical properties, while being recyclable and partially renewable.


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