scholarly journals Enhancing Oil Recovery from Low-Permeability Reservoirs with a Thermoviscosifying Water-Soluble Polymer

Molecules ◽  
2021 ◽  
Vol 26 (24) ◽  
pp. 7468
Author(s):  
Xiaoqin Zhang ◽  
Bo Li ◽  
Feng Pan ◽  
Xin Su ◽  
Yujun Feng
Keyword(s):  
Oil Recovery ◽  
Water Soluble ◽  
Oil Reservoirs ◽  
Water Flooding ◽  
Low Permeability ◽  
Water Soluble Polymer ◽  
Water Soluble Polymers ◽  
Chemical Eor ◽  
Incremental Oil Recovery ◽  
Hydrolyzed Polyacrylamide

Water-soluble polymers, mainly partially hydrolyzed polyacrylamide (HPAM), have been used in the enhanced oil recovery (EOR) process. However, the poor salt tolerance, weak thermal stability and unsatisfactory injectivity impede its use in low-permeability hostile oil reservoirs. Here, we examined the adaptivity of a thermoviscosifying polymer (TVP) in comparison with HPAM for chemical EOR under simulated conditions (45 °C, 4500 mg/L salinity containing 65 mg/L Ca2+ and Mg2+) of low-permeability oil reservoirs in Daqing Oilfield. The results show that the viscosity of the 0.1% TVP solution can reach 48 mPa·s, six times that of HPAM. After 90 days of thermal aging at 45 °C, the TVP solution had 71% viscosity retention, 18% higher than that of the HPAM solution. While both polymer solutions could smoothly propagate in porous media, with permeability of around 100 milliDarcy, TVP exhibited stronger mobility reduction and permeability reduction than HPAM. After 0.7 pore volume of 0.1% polymer solution was injected, TVP achieved an incremental oil recovery factor of 13.64% after water flooding, 3.54% higher than that of HPAM under identical conditions. All these results demonstrate that TVP has great potential to be used in low-permeability oil reservoirs for chemical EOR.

Improving the Viscosity of Partially Hydrolyzed Polyacrylamide (PHPAM) Solution for Enhanced Oil Recovery (EOR) Application

2021 ◽  
Vol 874 ◽  
pp. 45-49
Author(s):  
Ihsan Arifin ◽  
Grandprix Thomryes Marth Kadja ◽  
Cynthia L. Radiman
Keyword(s):  
Enhanced Oil Recovery ◽  
Oil Recovery ◽  
Average Molecular Weight ◽  
Monomer Concentration ◽  
Water Soluble ◽  
Water Soluble Polymer ◽  
Produce Water ◽  
Water Soluble Polymers ◽  
Hydrolysis Method ◽  
Hydrolyzed Polyacrylamide

Enhanced Oil Recovery (EOR) is a promising technology for increasing crude oil production, especially from old wells. Polymer flooding is one of the techniques used in EOR in which the water-soluble polymer is added to increase the viscosity of the injected fluid. However, this technique has not been implemented in Indonesia due to the unavailability of locally-synthesized polymers. Therefore, this research aims to synthesize polyacrylamides and their partially-hydrolyzed derivatives and to study the possibility of their utilization for the EOR application. Various polymerization conditions using potassium persulfate (KPS) as initiators have been realized and the resulting polymers were characterized using FTIR spectroscopy and rheology measurement. It was found that higher monomer concentration resulted in higher viscosity-average molecular weight of polyacrylamide. Further study revealed that the hydrolysis of polyacrylamide by alkaline solution significantly increased the viscosity of 1000 ppm solution from 1.5 to 145.40 cP at room temperature, which is comparable to one of the commercial products. These results showed that the simple synthesis and hydrolysis method could be effectively used to produce water-soluble polymers for the EOR application.

A Novel Thermoviscosifying Water-Soluble Polymer for Enhancing Oil Recovery from High-Temperature and High-Salinity Oil Reservoirs

2011 ◽  
Vol 306-307 ◽  
pp. 654-657 ◽  
Author(s):  
Yu Wang ◽  
Zhi Yong Lu ◽  
Yu Gui Han ◽  
Yu Jun Feng ◽  
Chong Li Tang
Keyword(s):  
High Temperature ◽  
Oil Recovery ◽  
High Salinity ◽  
Water Soluble ◽  
Oil Reservoirs ◽  
Water Soluble Polymer ◽  
The Poor ◽  
Hydrolyzed Polyacrylamide ◽  
Increasing Temperature ◽  
Enhance Oil Recovery

Polymer flooding represents one of the most efficient processes to enhance oil recovery, but the poor thermostability and salt tolerance of the currently-used partially hydrolyzed polyacrylamide (HPAM) impeded its use in high-temperature and high-salinity oil reservoirs. “Smart” thermoviscosifying polymers (TVPs) may overcome the deficiencies of HPAM. Steady and dynamic rheological behaviors against temperature of a novel TVP were examined in this work in comparison with a commercial HPAM polymer. It was found when increasing temperature, both apparent viscosity and elastic modulus increase for TVP aqueous solution, but decrease for HPAM solution. The results indicate that TVP shows some potential to be used in enhancing oil recovery from high-temperature and high-salinity oil reservoirs.

Flow of Hydrophobically Modified Water-Soluble-Polymer Solutions in Porous Media: New Experimental Insights in the Diluted Regime

SPE Journal ◽  
2010 ◽  
Vol 16 (01) ◽  
pp. 43-54 ◽  
Author(s):  
Guillaume Dupuis ◽  
David Rousseau ◽  
René Tabary ◽  
Bruno Grassl
Keyword(s):  
Oil Recovery ◽  
Polymer Concentration ◽  
Adsorbed Layer ◽  
Water Soluble ◽  
Water Soluble Polymer ◽  
Improved Oil Recovery ◽  
Water Soluble Polymers ◽  
Resistance Factors ◽  
Soluble Polymers ◽  
Hydrophobically Modified

Summary The specific molecular structure of hydrophobically modified water-soluble polymers (HMWSPs), also called hydrophobically associative polymers, gives them interesting thickening and surface-adsorption abilities compared with classical water-soluble polymers (WSPs), which could be useful in polymer-flooding and well-treatment operations. However, their strong adsorption obviously can impair their injectivity, and, conversely, the shear sensitivity of their gels can be detrimental to well treatments. Determining for which improved-oil-recovery (IOR) application HMWSPs are best suited, therefore, remains difficult. The aim of this work is to bring new insight regarding the interaction mechanisms between HMWSPs and rock matrix and the consequences concerning their propagation in reservoirs. A consistent set of HMWSPs with sulfonated polyacrylamide backbones and alkyl hydrophobic side chains together with an equivalent WSP was synthesized and fully characterized. HMWSP and WSP solutions were then injected in model granular packs. As expected, with HMWSPs, high resistance factors (or mobility reductions, Rm) were observed. Yet, within the limit of the injected volumes, the effluent showed the same viscosity and polymer concentration as the injected solutions. A first significant outcome concerns the specificities of the Rm curves during HMWSP injections. Rm increases took place in two steps. The first corresponded to the propagation of the viscous front, as observed with WSP, whereas the second was markedly delayed, occurring several pore volumes (PV) after the breakthrough. This result is not compatible with the classical picture of multilayer adsorption of HMWSPs but suggests that injectivity is controlled solely by the adsorption of minor polymeric species. This hypothesis was confirmed by reinjecting the collected effluents into fresh cores; no second-step Rm increases were observed. Brine injections in HMWSP-treated cores revealed high residual resistance factors (or irreversible permeability reductions, Rk), which can be attributed to the presence of thick polymer-adsorbed layers on the pore surface. Nevertheless, Rk values strongly decreased when increasing the brine-flow rate. This second significant outcome shows that the adsorbed-layer thickness is shear-controlled. These new results should lead to proposing new adapted filtration and injection procedures for HMWSPs, aimed, in particular, at improving their injectivity.

scholarly journals Study on Prevention of Gas Channelling of Acid-resistant Gel Foam in CO2 Flooding of Low Permeability Reservoir

2020 ◽  
Vol 194 ◽  
pp. 01041
Author(s):  
Zhaoxia LIU ◽  
Ming GAO ◽  
Shanyan ZHANG ◽  
Wanlu LIU
Keyword(s):  
Oil Recovery ◽  
Retention Rate ◽  
Crosslinking Agent ◽  
Water Soluble ◽  
Oil Reservoirs ◽  
Low Permeability ◽  
Co2 Flooding ◽  
Water Separation ◽  
Co2 Gas ◽  
Low Permeability Reservoirs

With the shortage of recoverable reserves in conventional oil reservoirs, the development of low-permeability oil reservoirs has received more and more attention. The oil recovery of low-permeability reservoirs can be significantly improved by CO2 flooding, as it can effectively supply formation energy. CO2 flooding is an effective technology for increasing oil production in low-permeability reservoirs. However, because of the heterogeneity of the reservoir and the effect of natural fractures, CO2 gas channelling easily occurs during CO2 flooding, seriously reducing CO2 flooding effect. In this study, the gas channelling technology of acid-resistant gel foam was investigated. Preferred acid-resistant gel foam system formula was found as 0.1% by mass of AOS foaming agent with 0.3% to 0.4% by mass of instant HPAM polymer and 1% to 2% by mass of water-soluble phenolic resin crosslinking agent. This system still has a good foaming ability and blocking performance under at pH=2 and a salinity of 10×104 mg/L. After 60 days of aging under oil reservoir conditions, there is no obvious water separation, and the plugging strength retention rate reached more than 60%. The gel foam channelling system can be applied to highly heterogeneous and low permeability reservoirs with a permeability gradient higher than 14 and can increase the recovery rate by more than 20% based on the CO2 flooding. Acid-resistant gel foam channelling technology can effectively inhibit CO2 gas channelling and improve CO2 flooding effect in low permeability reservoirs.

scholarly journals Performance Evaluation of STARPAM Polymer and Application in High Temperature and Salinity Reservoir

2018 ◽  
Vol 2018 ◽  
pp. 1-13 ◽  
Author(s):  
Chengli Zhang ◽  
Peng Wang ◽  
Guoliang Song
Keyword(s):  
High Temperature ◽  
Salt Tolerance ◽  
Heat Resistance ◽  
Oil Recovery ◽  
Physical Simulation ◽  
Water Soluble ◽  
Water Flooding ◽  
Water Soluble Polymer ◽  
Oil Displacement ◽  
Star Shaped Polymer

Based on the properties of high temperature and salinity reservoir, the water-soluble polymer with good heat resistance and salt tolerance can be obtained through copolymerization between 2-acrylamide-2-methyl sulfonate monomer (AMPSN) and acrylamide monomer (AM) in water. The star shaped stable complexes (STARPAM) with the star nucleus of β-CD are prepared by living radical polymerization, which can improve the viscosity and change the percolation characteristics of the polymer in porous media. In the article, the performance of the STARPAM (star-shaped polymer) with heat resistance and salt tolerance was evaluated by comparing the viscosification property, heat and salt resistance, calcium and magnesium tolerance, and long-term thermal stability of STARPAM (star-shaped polymer) with those of HPAM (partially hydrolyzed polyacrylamide) and MO-4000 (linear polymer). The results of physical simulation experiment showed that the viscosity of the STARPAM is 3.3 times that of MO-4000 and 4 times that of HPAM under the conditions of mineralization degree of 20000 mg/L, concentration of 1500 mg/L, and 75°C, which indicated that heat resistance and salt tolerance of the STARPAM are excellent. Oil displacement experiments showed that STARPAM can enhance oil recovery by 20.53% after water flooding, and the effect of oil displacement is excellent. At present, 19 wells were effective with a ratio of 95.2%. Compared with before treatment, the daily liquid production increased by 136 m3, daily oil production increased by 44.6 t, water cut decreased by 4.67 percentage points, and flow pressure decreased by 1.15 MPa.

scholarly journals NEW AQUEOUS POLYMER FOR HIGH-TEMPERATURE RESERVOIRS

2018 ◽  
Vol 15 (30) ◽  
pp. 380-386
Author(s):  
Y. V. SAVINYKH ◽  
L. D. LANG
Keyword(s):  
High Temperature ◽  
Oil Recovery ◽  
High Salinity ◽  
Sea Water ◽  
Polymer Flooding ◽  
Water Soluble ◽  
Water Flooding ◽  
Polymer Gel ◽  
Sweep Efficiency ◽  
Water Soluble Polymer

Polymer flooding is technologically simple and highly effective method of enhanced oil recovery. The method is based on adding a small amount of polymer in conventional water flooding of oil reservoirs. The increase in viscosity and the reduction of the mobility of injected water are to equalize the displacement front by slowing the moving of water in the highly permeable zones and restricting the formation of water finger. These factors help to increase the sweep efficiency and oil-water displacement efficiency during flooding. Polymer flooding has been used successfully in clastic and carbonate reservoirs, as well as in low-permeability reservoirs such as a fractured basement. However, most of the current polymer gel used for control water flows are decayed by a high content of ions Ca2+ and Mg2+ in formation water or in injected water. Similarly, polymer gels lose their stability at high reservoir temperature (above 70°C). Developing water-soluble polymer, which does not change their rheological properties under high salinity and high temperature (over 100°C), is very important when producing offshore, where sea water is commonly used for flooding (high salinity of 30-40 g/L).

Smart Polymers and their Applications: A Review

2017 ◽  
Vol 8 (03) ◽  
Author(s):  
Gore S. A. ◽  
Gholve S. B. ◽  
Savalsure S. M. ◽  
Ghodake K. B. ◽  
Bhusnure O. G. ◽  
...  
Keyword(s):  
Oil Recovery ◽  
Water Soluble ◽  
Solution Temperature ◽  
Smart Polymers ◽  
Stimuli Responsive ◽  
Responsive Materials ◽  
Water Soluble Polymers ◽  
Commercial Applications ◽  
Stimuli Sensitive ◽  
External Stimuli

Smart polymers are materials that respond to small external stimuli. These are also referred as stimuli responsive materials or intelligent materials. Smart polymers that can exhibit stimuli-sensitive properties are becoming important in many commercial applications. These polymers can change shape, strength and pore size based on external factors such as temperature, pH and stress. The stimuli include salt, UV irradiation, temperature, pH, magnetic or electric field, ionic factors etc. Smart polymers are very promising applicants in drug delivery, tissue engineering, cell culture, gene carriers, textile engineering, oil recovery, radioactive wastage and protein purification. The study is focused on the entire features of smart polymers and their most recent and relevant applications. Water soluble polymers with tunable lower critical solution temperature (LCST) are of increasing interest for biological applications such as cell patterning, smart drug release, DNA sequencing etc.

The Mechanism of Flue Gas Injection for Enhanced Light Oil Recovery

2004 ◽  
Vol 126 (2) ◽  
pp. 119-124 ◽  
Author(s):  
O. S. Shokoya ◽  
S. A. (Raj) Mehta ◽  
R. G. Moore ◽  
B. B. Maini ◽  
M. Pooladi-Darvish ◽  
...  
Keyword(s):  
Oil Recovery ◽  
Flue Gas ◽  
Gas Injection ◽  
Cost Effective ◽  
Air Injection ◽  
Oil Reservoirs ◽  
Flue Gases ◽  
Low Permeability ◽  
Light Oil ◽  
Light Oil Reservoirs

Flue gas injection into light oil reservoirs could be a cost-effective gas displacement method for enhanced oil recovery, especially in low porosity and low permeability reservoirs. The flue gas could be generated in situ as obtained from the spontaneous ignition of oil when air is injected into a high temperature reservoir, or injected directly into the reservoir from some surface source. When operating at high pressures commonly found in deep light oil reservoirs, the flue gas may become miscible or near–miscible with the reservoir oil, thereby displacing it more efficiently than an immiscible gas flood. Some successful high pressure air injection (HPAI) projects have been reported in low permeability and low porosity light oil reservoirs. Spontaneous oil ignition was reported in some of these projects, at least from laboratory experiments; however, the mechanism by which the generated flue gas displaces the oil has not been discussed in clear terms in the literature. An experimental investigation was carried out to study the mechanism by which flue gases displace light oil at a reservoir temperature of 116°C and typical reservoir pressures ranging from 27.63 MPa to 46.06 MPa. The results showed that the flue gases displaced the oil in a forward contacting process resembling a combined vaporizing and condensing multi-contact gas drive mechanism. The flue gases also became near-miscible with the oil at elevated pressures, an indication that high pressure flue gas (or air) injection is a cost-effective process for enhanced recovery of light oils, compared to rich gas or water injection, with the potential of sequestering carbon dioxide, a greenhouse gas.

Review of characterization methods for water-soluble polymers used in oil sand and heavy oil industrial applications

2016 ◽  
Vol 24 (4) ◽  
pp. 460-470 ◽  
Author(s):  
Xiaomeng Wang
Keyword(s):  
Oil Recovery ◽  
Heavy Oil ◽  
Environmental Fate ◽  
Industrial Applications ◽  
Water Soluble ◽  
Oil Sand ◽  
Characterization Methods ◽  
Water Soluble Polymers ◽  
Soluble Polymers ◽  
Terrestrial Animal

Water-soluble polymers have been used in many applications in the oil sand and heavy oil industries, including drilling, enhanced oil recovery, tailings treatment, and water treatment. Because they are water soluble, residual polymer can remain with the aqueous phase, potentially leading to environmental impacts. Investigating the environmental fate of these water-soluble polymers is particularly important as they may be toxic to aquatic biota or terrestrial animal life. However, since polymers are somewhat complex because of their high molecular weight, there are many challenges in their measurement, especially in complex matrices. In this paper, polymers used in oilfield applications, particularly in the oil sand or heavy oil industries, are reviewed and various analytical methods for polymer characterization are compared.

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