Improved EOR Polymer Selection Using Field-Flow Fractionation

Various polyacrylamide polymers have been successfully applied in chemical EOR projects. These polymers are characterised by high molecular weights (MW) to achieve high viscosifying power. The molecular weight distribution (MWD) of the polymers has a major impact on polymer properties and performance. Measuring the molecular weight distribution is challenging using conventional methods. Field-Flow Fractionation (FFF) enables the determination of the distribution to select and quality check various polymers. Polymers with high molar masses (> 1 MDa) are used for EOR to obtain highly viscous aqueous solutions. The MWD of the polymers is crucial for the solution characteristics. Conventional analysis of polymers is performed using either viscometry – which is able to determine the average MW but does not give information on MWD, or size-exclusion chromatography – which is restricted to molecular weights of < 20 MDa. FFF is based on the analytes flowing at different speeds in a channel dependent on their size and mass. This effect leads to separation, which is then used to determine the MWD. FFF allows to determine the MW and MWD of various ultra-high molecular weight polyacrylamides (HPAAMs). The FFF measurements showed, that despite similar MWs are claimed, substantial differences in MWD are observed. This technology offered the quantification the MWD of HPAAMs up to a MW of 5 GDa. Furthermore, gyration radii of the HPAAM molecules were determined. Selecting polymers on viscosifying power only is not addressing issues related to different MW and MWDs such as selective polymer retention and degradation of the high molar mass part of the distribution. The results were used to improve the polymer selection for chemical EOR projects. Overall, this work presents a new technique for analysis of ultra-high molecular weight EOR polymers, which enables the possibility to determine the full range of polymer MWD. This available information enhances the EOR polymer selection process addressing selective polymer retention and mechanical degradation in addition to the viscosifying power of polymers.

Pelican Lake: Learning From the Largest Polymer Flood Expansion in a Heavy Oil Field

Polymer has been injected continuously since 2005-06 in the Pelican Lake field in Canada, starting with a pilot rapidly followed by an expansion. At some point, 900 horizontal wells were injecting 300,000 bbl/d of polymer solution and oil production related to polymer injection reached 65,000 bopd. As a result, the Pelican Lake polymer flood is the largest polymer flood in heavy oil in the world and the largest polymer flood using horizontal wells. Although some papers have already been devoted to the initial polymer flood pilots, very little has been published on the expansion of the polymer flood and this is what this paper will focus on. The paper will describe the various phases of the polymer flood expansion and their respective performances as well as discuss the specific challenges in the field including strong variations in oil viscosity (from 800 to over 10,000 cp), how irregular legacy well patterns were dealt with, and how primary, secondary and tertiary polymer injection compare. It will also show the performances of polymer injection in combination with multi-lateral wells and touch upon the surface issues including the facilities. The availability of field and production data (which are public in Canada) combined with the variability in the field properties provide us with a wealth of data to better understand the performances of polymer flooding in heavy oil. This case study will benefit engineers and companies that are interested in polymer flood, in particular in heavy oil. The paper will be a significant addition to the literature where few large scale chemical EOR expansions are described.

Evaluating Efficiency of Surfactant-Polymer Flooding with Single Well Chemical Tracer Tests at Kholmogorskoye Field

EOR technologies in general and surfactant-polymer flooding (SP) in particular is considered as a tertiary method for redevelopment of mature oil fields in Western Siberia, with potential to increase oil recovery to 60-70% OOIP. The selection of effective surfactant blend and a polymer for SP flooding a complex and multi-stage process. The selected SP compositions were tested at Kholmogorskoye oilfield in September-December 2020. Two single well tests with partitioning chemical tracers (SWCTT) and the injectivity test were performed. The surfactant and the polymer for chemical EOR were selecting during laboratory studies. Thermal stability, phase behavior, interfacial tension and rheology of SP formulation were investigated, then a prospective chemical design was developed. Filtration experiments were carried out for optimization of slugs and concentrations. Then SWCTT was used to evaluated residual oil saturation after water flooding and after implementation of chemical EOR in the near wellbore areas. The difference between the obtained values is a measure of the efficiency of surfactant-polymer flooding. Pandemic restriction shifted SWCTT to the period when temperature dropped below zero and suitable for winter conditions equipment was required. Two SWCTT were conducted with same surfactant, but different design of slugs in order to prove technical and economic models of SP-flooding. Long-term polymer injectivity was accessed at the third well. Oil saturation of sandstone reservoir after the injection of a surfactant-polymer solution was reduced about 10% points which is around one third of the residual oil after water flooding. Results were compared with other available data such as well logging, lab core flooding experiments, and hydrodynamic simulation. Modeling of SWCTT is ongoing, current interpretation confirms the increase the oil recovery factor after SP-flooding up to 20-25%, which is a promising result. Temperature model of the bottom hole zone was created and verified. The model predicts that temperature of those zones essentially below that average in the reservoir, which is important for interpretation of tracer test and surfactant efficiency. The tested surfactant showed an acceptable efficiency at under-optimum conditions, which is favorable for application of the SP formulation for neighboring field and layers with different reservoir temperatures, but similar water composition. In general, the results of the conducted field tests correlate with the results of the core experiments for the selected surfactant

Bulk Rheology and Injectivity Assessments of Potential Biopolymer and Synthetic Polymer for Applications in Carbonates Under Harsh Conditions

Polymer flooding is a well-established chemical EOR technology that is used to overcome challenges associated with conventional waterflooding including viscous fingering and early breakthrough. Nevertheless, polymers tend to perform poorly under harsh reservoir conditions of high temperature and high salinity (HTHS). The main objective of this study is to evaluate and compare the performance of two potential polymers, an ATBS-based polymer and a biopolymer (Scleroglucan), in carbonates under harsh reservoir conditions. This comparative study includes an analysis of polymer rheological experiments as well as polymer injectivity tests. The effects of water salinity and temperature on the performance of these two polymers was also investigated in this study. Rheological experiments were carried out on polymer samples at both ambient (25 °C) and high temperature conditions (90 °C). Polymer viscosity was measured as function of concentration, temperature, and salinity at different shear rates ranging from 1 to 1000 s−1. Injectivity characteristics of both polymers were also assessed through coreflooding experiments using high permeability carbonate outcrops at room (25 °C) and high (90 °C) temperature conditions. The injectivity tests included two stages of brine pre-flush and polymer injection, which allowed assessing the resistance factor (RF) of these polymers. These tests were conducted using high salinity formation water (167,114 ppm TDS) at both temperature conditions. The bulk rheological tests showed that both ATBS-based and Scleroglucan polymers exhibit a shear-thinning behavior. However, the shear-thinning effect is far more evident at higher concentrations in the case of Scleroglucan as opposed to that of the ATBS-based polymer. Viscosity measurements of the polymer samples at different salinities demonstrated the detrimental impact of salinity and divalent ions on the stability of ATBS-based whereas Scleroglucan was not much affected. Scleroglucan exhibited better filterability at the high temperature as opposed to the room temperature. From the injectivity tests, the shear-thinning behavior of the biopolymer in the porous media was confirmed as RF decreased with increasing the flow rate applied at both temperature conditions. Meanwhile, the ATBS-based polymer exhibited a shear-thickening behavior at 25 °C, but a shear-thinning one at 90 °C. Compared to the biopolymer, the ATBS-based polymer showed better injectivity at both the room and the high temperatures as the differential pressure stabilized within the first few pore volumes injected. This study highlights the importance of polymer screening for EOR applications in carbonate reservoirs under HTHS conditions.

Enhancing Oil Recovery from Low-Permeability Reservoirs with a Thermoviscosifying Water-Soluble Polymer

Water-soluble polymers, mainly partially hydrolyzed polyacrylamide (HPAM), have been used in the enhanced oil recovery (EOR) process. However, the poor salt tolerance, weak thermal stability and unsatisfactory injectivity impede its use in low-permeability hostile oil reservoirs. Here, we examined the adaptivity of a thermoviscosifying polymer (TVP) in comparison with HPAM for chemical EOR under simulated conditions (45 °C, 4500 mg/L salinity containing 65 mg/L Ca2+ and Mg2+) of low-permeability oil reservoirs in Daqing Oilfield. The results show that the viscosity of the 0.1% TVP solution can reach 48 mPa·s, six times that of HPAM. After 90 days of thermal aging at 45 °C, the TVP solution had 71% viscosity retention, 18% higher than that of the HPAM solution. While both polymer solutions could smoothly propagate in porous media, with permeability of around 100 milliDarcy, TVP exhibited stronger mobility reduction and permeability reduction than HPAM. After 0.7 pore volume of 0.1% polymer solution was injected, TVP achieved an incremental oil recovery factor of 13.64% after water flooding, 3.54% higher than that of HPAM under identical conditions. All these results demonstrate that TVP has great potential to be used in low-permeability oil reservoirs for chemical EOR.

A Comprehensive Project of Thermal, Gas and Chemical EOR Method Application for Bazhenov Shale Formation

The article describes the development aimed at a comprehensive study for enhanced oil recovery methods (EOR) of the Bazhenov shale oil formation. Potentially effective technologies for low-permeable reservoirs are under consideration: injection of associated petroleum gas in the mode of miscible displacement to recover light oil; injection of the surfactants water solutions, to separate sorbed hydrocarbons from the rock and change core wettability; and heating technologies to convert solid hydrocarbons into liquid and gaseous, and recover. The project explore potentially effective EOR technologies and their influence on the various types of hydrocarbons of the shale Bazhenov formation: mobile oil in closed pores, sorbed and solid (kerogen) hydrocarbons. Experimental studies were carried out: the selection of the gases composition, the selection of surfactant compositions, the study of the possibility of thermal exposure by over-heated water injection. The project is currently at the stage of determining the effectiveness of each method, selecting a technology for specific field conditions and identifying which hydrocarbon resources each method is aimed at extracting.

Propagation of Nano Sized CDG Deep into Porous Media

Enhanced Oil Recovery (EOR) technologies become more critical as number of mature oilfields grows continually. Among the variety of chemical EOR methods, conventional application of the polymer-based solutions occupies the largest space. One of the most perspective technologies is application of polymeric fluids that do not contain a 3D polymer structure. Among such compositions, colloid dispersion systems are especially worth mentioning as they could be simultaneously used for water-oil mobility ratio control as well as permeability profile modification. Presented study considers the propagation of colloidal dispersed gels in porous media under different mineralization of formation water. For this purpose were conducted rheological measurements, Particle size distribution and Propagation experiments. The results show that divalent ions cause higher viscosity reduction due to the formation a more severe electrolyte and average particle size decreased with ionic strength increment. The presence of divalent ions improves the propagation probably by cause of repulsion forces increase.

Heavy Oil Polymer Pilot with Active Bottom Water Drive – A Success Story

Bechraji is one of the major fields of heavy oil belt of Mehsana Asset in Western India. It contains heavy oil with average viscosity of ~270cp at reservoir temperature. During the early phase of production, high viscosity led to viscous fingering which resulted in sharp rise in field water cut to ~80%. Polymer flood in heavy oil has received significant attention after the numerous success across the globe namely, Marmul Oman, Bohai Bay offshore China and Pelican lake Canada fields. Screening studies were conducted followed by comprehensive laboratory evaluations of chemical flood potential which identified it as suitable process. Thus, a normal five spot pattern pilot testing was planned to understand the role of chemical EOR methods in the ultimate development strategy for the Bechraji. Comprehensive monitoring and quality control procedures were being followed to ensure smooth operations. Pressure surveys, tracer surveys, detailed produced fluid analyses and tests for monitoring the quality of injected fluids were all performed routinely. This paper deliberates the operational aspects of polymer flood, quality control and monitoring program followed, challenges faced and results of polymer flooding.