scholarly journals Electro-optical interfacial effects on a graphene/π-conjugated organic semiconductor hybrid system

2018 ◽  
Vol 9 ◽  
pp. 963-974 ◽  
Author(s):  
Karolline A S Araujo ◽  
Luiz A Cury ◽  
Matheus J S Matos ◽  
Thales F D Fernandes ◽  
Luiz G Cançado ◽  
...  

The influence of graphene and retinoic acid (RA) – a π-conjugated organic semiconductor – interface on their hybrid system is investigated. The physical properties of the interface are assessed via scanning probe microscopy, optical spectroscopy (photoluminescence and Raman) and ab initio calculations. The graphene/RA interaction induces the formation of a well-organized π-conjugated self-assembled monolayer (SAM) at the interface. Such structural organization leads to the high optical emission efficiency of the RA SAM, even at room temperature. Additionally, photo-assisted electrical force microscopy, photo-assisted scanning Kelvin probe microscopy and Raman spectroscopy indicate a RA-induced graphene doping and photo-charge generation. Finally, the optical excitation of the RA monolayer generates surface potential changes on the hybrid system. In summary, interface-induced organized structures atop 2D materials may have an important impact on both design and operation of π-conjugated nanomaterial-based hybrid systems.

2015 ◽  
Vol 1754 ◽  
pp. 69-74
Author(s):  
Ravi Gaikwad ◽  
Tinu Abraham ◽  
Aharnish Hande ◽  
Fatemeh Bakhtiari ◽  
Siddhartha Das ◽  
...  

ABSTRACTAtomic force microscopy is employed to study the structural changes in the morphology and physical characteristics of asphaltene aggregates as a function of temperature. The exotic fractal structure obtained by evaporation-driven asphaltene aggregates shows an interesting dynamics for a large range of temperatures from 25°C to 80°C. The changes in the topography, surface potential and adhesion are unnoticeable until 70°C. However, a significant change in the dynamics and material properties is displayed in the range of 70°C - 80°C, during which the aspahltene aggregates acquire ‘liquid-like’ mobility and fuse together. This behaviour is attributed to the transition from the pure amorphous phase to a crystalline liquid phase which occurs at approximately 70°C as shown by using Differential Scanning Calorimetry (DSC). Additionally, the charged nature of asphaltenes and bitumen is also explored using kelvin probe microscopy. Such observations can lead to the development of a rational approach to the fundamental understanding of asphaltene aggregation dynamics and may help in devising novel techniques for the handling and separation of asphaltene aggregates using dielectrophoretic methods.


Author(s):  
Christophe De Nardi ◽  
Romain Desplats ◽  
Philippe Perdu ◽  
Félix Beaudoin ◽  
Jean Luc Gauffier

Abstract A method to measure “on site” programmed charges in EEPROM devices is presented. Electrical Scanning Probe Microscopy (SPM) based techniques such as Electric Force Microscopy (EFM) and Scanning Kelvin Probe Microscopy (SKPM) are used to directly probe floating gate potentials. Both preparation and probing methods are discussed. Sample preparation to access floating gate/oxide interfaces at a few nanometers distance without discharging the gate proves to be the key problem, more than the probing technique itself. Applications are demonstrated on 128 kbit EEPROMs from ST Microelectronics and 64 kbit EEPROMs from Atmel.


2001 ◽  
Vol 680 ◽  
Author(s):  
G. Koley ◽  
M. G. Spencer

ABSTRACTScanning Kelvin probe microscopy (SKPM) technique operated in feedback mode has been used to characterize GaN (unintentionally n-type doped, n+ doped and semi-insulating), and Al0.35Ga0.65N/GaN heterostructures (with varying Al0.35Ga0.65N thickness) grown by metalorganic chemical vapor deposition and molecular beam epitaxy. SKPM was used to measure the surface potential on these materials. The measurement technique was calibrated using metal calibration samples of Pt, Au, Ni and Al. The BSBH for n-doped GaN was measured to be 0.7 eV, which is in good agreement with values reported in the literature. Growth features such as dislocations present on the surfaces of III-nitrides were also investigated for their electrical properties using SKPM and non-contact mode atomic force microscopy, simultaneously. The dislocations have been found to be negatively charged for GaN as well as Al0.35Ga0.65N/GaN heterostructure samples.


2017 ◽  
Vol 3 (7) ◽  
pp. 1700117 ◽  
Author(s):  
Yanfei Wu ◽  
Xinglong Ren ◽  
Kathryn A. McGarry ◽  
Matthew J. Bruzek ◽  
Christopher J. Douglas ◽  
...  

1999 ◽  
Vol 75 (2) ◽  
pp. 286-288 ◽  
Author(s):  
Ch. Sommerhalter ◽  
Th. W. Matthes ◽  
Th. Glatzel ◽  
A. Jäger-Waldau ◽  
M. Ch. Lux-Steiner

2018 ◽  
Vol 10 (7) ◽  
pp. 6755-6763 ◽  
Author(s):  
Petro M. Lytvyn ◽  
Andrian V. Kuchuk ◽  
Yuriy I. Mazur ◽  
Chen Li ◽  
Morgan E. Ware ◽  
...  

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