Synthesis of sodium ammonium hydrophosphate and sodium dihydrophosphate based on extraction phosphoric acid from Central Kyzylkum phosphorites

2021 ◽  
pp. 19-25
Keyword(s):  
Phosphoric Acid ◽  
Sodium Carbonate ◽  
Gaseous Ammonia ◽  
Dihydrogen Phosphate ◽  
Hydrogen Phosphate ◽  
Sodium Dihydrogen Phosphate ◽  
Ammonium Hydrogen ◽  
Ammonium Hydrogen Phosphate ◽  
Sodium Dihydrogen ◽  
Extraction Phosphoric Acid

The aim of the research is the synthesis of sodium ammonium hydrogen phosphate and sodium dihydrogen phosphate based on purified extraction phosphoric acid. The acid was purified from accompanying impurities by precipitation methods using sodium carbonate and metasilicate, washed burnt phosphoconcentrate, barium carbonate, acid neutralization with gaseous ammonia. Pre-neutralization of the purified solution of monoammonium phosphate with sodium carbonate to the ratio Na2O:P2O5 = 0.44 and subsequent drying at a temperature of 50 °С allows to obtain sodium ammonium hydrogen phosphate tetrahydrate, and at 100 °С sodium dihydrogen phosphate monohydrate. The individuality and purity of the synthesized substances was established by the methods of X-ray diffraction, IR spectroscopy, thermogravimetry and scanning electron microscope.

scholarly journals Sorption of ions of some metals on synthesized weakly basic ion exchangers

2021 ◽  
pp. 14-18
Keyword(s):  
Sodium Carbonate ◽  
Barium Carbonate ◽  
Gaseous Ammonia ◽  
Dihydrogen Phosphate ◽  
X Ray Diffraction ◽  
Hydrogen Phosphate ◽  
Sodium Dihydrogen Phosphate ◽  
Ammonium Hydrogen ◽  
Ammonium Hydrogen Phosphate ◽  
Sodium Dihydrogen

The aim of the research is the synthesis of sodium ammonium hydrogen phosphate and sodium dihydrogen phosphate based on purified extraction phosphoric acid. The acid was purified from accompanying impurities by precipitation methods using sodium carbonate and metasilicate, washed burnt phosphoconcentrate, barium carbonate, acid neutralization with gaseous ammonia. Pre-neutralization of the purified solution of monoammonium phosphate with sodium carbonate to the ratio Na2O:P2O5 = 0.44 and subsequent drying at a temperature of 50 °С allows to obtain sodium ammonium hydrogen phosphate tetrahydrate, and at 100 °С sodium dihydrogen phosphate monohydrate. The individuality and purity of the synthesized substances was established by the methods of X-ray diffraction, IR spectroscopy, thermogravimetry and scanning electron microscope.

The Effect of Phosphatic Composite on Magnesium Phosphate Cement Performance

2014 ◽  
Vol 809-810 ◽  
pp. 477-484
Author(s):  
Zhao Qing Qi ◽  
Hong Tao Wang ◽  
Jun Liang Dang ◽  
Shi Hao Zhang ◽  
Jian Hua Ding
Keyword(s):  
Setting Time ◽  
Potassium Dihydrogen Phosphate ◽  
Magnesium Phosphate ◽  
Dihydrogen Phosphate ◽  
Ammonium Dihydrogen Phosphate ◽  
Hydrogen Phosphate ◽  
Sodium Dihydrogen Phosphate ◽  
Disodium Hydrogen Phosphate ◽  
Potassium Dihydrogen ◽  
Sodium Dihydrogen

The capacity of 10%, 30%, and 50% ammonium dihydrogen phosphate were replaced with an equal amount of three phosphate (potassium dihydrogen phosphate, sodium dihydrogen phosphate, disodium hydrogen phosphate) respectively. Magnesium phosphate cement was made by phosphate of replaced, which strength, setting time, fluidity, hydration temperature, and the hydration products was researched. The results show that: MPC was made that replaced with the equal amount of three kind of phosphate, which has good mechanical properties. Setting time and fluidity change along with the replacment. Three kind of phosphate replace ammonium dihydrogen phosphate, which change the hydration process of MPC. When ammonium dihydrogen phosphate was replaced by an equal amount of disodium hydrogen phosphate, the temperature of hydration is only 69.4 °C. XRD showed that the diffraction peaks of composite’s magnesium phosphate cement increases.

Osmolarity of Human Serum and of Chemical Solutions of Biologic Importance

1961 ◽  
Vol 7 (2) ◽  
pp. 156-164 ◽  
Author(s):  
Edward B Hendry
Keyword(s):  
Human Serum ◽  
Freezing Point ◽  
Potassium Dihydrogen Phosphate ◽  
Dihydrogen Phosphate ◽  
Hydrogen Phosphate ◽  
Sodium Dihydrogen Phosphate ◽  
Disodium Hydrogen Phosphate ◽  
Normal Human ◽  
Chemical Solutions ◽  
Sodium Dihydrogen

Abstract With the use of the Fiske Osmometer, the mean total osmolarity of normal human serum was found to be 289 mOsM (S.D., 4), which is equivalent to a mean freezing point of -0.537°. The isosmotic concentrations of some important biologic solutions were determined. It was also found that M/15 solutions of disodium hydrogen phosphate and of potassium dihydrogen phosphate are very hypotonic, and that 3.8% sodium citrate is hypertonic. Hemolysis of erythrocytes in isosmotic ammonium chloride solution can be considerably delayed by the addition of 3.0% glucose to the solution. Isosmotic concentrations of disodium hydrogen phosphate and sodium dihydrogen phosphate were precisely determined, as were pH levels of buffer solutions made from these two salts. The cause of the slight changes in osmolarity that occur when these two isosmotic solutions are mixed is discussed.

Optimization of Preparation of Sweet Potato Starch Phosphates of High Paste Stability by Response Surface Methodology

2011 ◽  
Vol 236-238 ◽  
pp. 2340-2343
Author(s):  
Guang Lei Li ◽  
Fei Lu ◽  
Su Juan Du ◽  
Jie Zeng
Keyword(s):  
Response Surface ◽  
Sweet Potato ◽  
Potato Starch ◽  
Phosphate Concentration ◽  
Dihydrogen Phosphate ◽  
Hydrogen Phosphate ◽  
Sodium Dihydrogen Phosphate ◽  
Disodium Hydrogen Phosphate ◽  
Sweet Potato Starch ◽  
Sodium Dihydrogen

The preparation of sweet potato starch phosphates which possess height stable paste was optimized in this study. A central composite design of response surface methodology involving phosphate (sodium dihydrogen phosphate and disodium hydrogen phosphate) concentration, the ratio of sodium dihydrogen phosphate and disodium hydrogen phosphate, phosphorylation temperature and urea concentration was used, and second-order model for paste stability was employed to generate the response surface. The optimum condition for preparation of sweet potato starch phosphates was as follows: phosphate concentration 4.89%, the ratio of sodium dihydrogen phosphate and disodium hydrogen 0.50, phosphorylation temperature 143°C, urea concentration 2.0%. The predicted value for paste stability of sweet potato starch phosphates at the optimum condition was 0.5721. Experimental verification gave values of 0.5708±0.0003.

THE USE OF P32 LABELED GLYCEROPHOSPHATE IN THE STUDY OF YOLK PHOSPHOLIPIDS

1949 ◽  
Vol 27b (7) ◽  
pp. 629-637 ◽  
Author(s):  
J. W. T. Spinks ◽  
C. C. Lee ◽  
J. B. O'Neil
Keyword(s):  
Enzymatic Hydrolysis ◽  
Phosphoric Acid ◽  
Comparative Studies ◽  
Inorganic Phosphate ◽  
Laying Hen ◽  
Trisodium Phosphate ◽  
Dihydrogen Phosphate ◽  
Sodium Dihydrogen Phosphate ◽  
Sodium Dihydrogen ◽  
Hydrolysis Of

Labeled sodium glycerophosphate has been prepared by phosphorylating glycerol with sodium dihydrogen phosphate containing P32. After the labeled sodium glycerophosphate had been fed to a laying hen, radiophosphorus from glycerophosphate appeared in the shells, whites, and yolks of the eggs. The uptake in different eggs followed a pattern similar to that found for inorganic phosphate, the maximum occurring at the fourth or fifth egg. Comparative studies using P32 labeled sodium glycerophosphate and trisodium phosphate indicate that the rate of utilization of the phosphorus from glycerophosphate is less than the rate of utilization of the phosphorus from inorganic phosphate. The possibility of an enzymatic hydrolysis of glycerophosphate followed by the incorporation of the resulting phosphoric acid into the phospholipids and the phosphorylation of lower glycerides (partially hydrolyzed fat) by inorganic phosphate as a mechanism for phospholipid formation is discussed.

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