scholarly journals Global mercury emissions to the atmosphere from anthropogenic and natural sources

2010 ◽  
Vol 10 (13) ◽  
pp. 5951-5964 ◽  
Author(s):  
N. Pirrone ◽  
S. Cinnirella ◽  
X. Feng ◽  
R. B. Finkelman ◽  
H. R. Friedli ◽  
...  
Keyword(s):  
Power Plants ◽  
Point Sources ◽  
Anthropogenic Sources ◽  
Small Scale ◽  
Current Estimate ◽  
Cement Production ◽  
Natural Sources ◽  
Mercury Emissions ◽  
Source Regions ◽  
Primary Emissions

Abstract. This paper provides an up-to-date assessment of global mercury emissions from anthropogenic and natural sources. On an annual basis, natural sources account for 5207 Mg of mercury released to the global atmosphere, including the contribution from re-emission processes, which are emissions of previously deposited mercury originating from anthropogenic and natural sources, and primary emissions from natural reservoirs. Anthropogenic sources, which include a large number of industrial point sources, are estimated to account for 2320 Mg of mercury emitted annually. The major contributions are from fossil-fuel fired power plants (810 Mg yr−1), artisanal small scale gold mining (400 Mg yr−1), non-ferrous metals manufacturing (310 Mg yr−1), cement production (236 Mg yr−1), waste disposal (187 Mg yr−1) and caustic soda production (163 Mg yr−1). Therefore, our current estimate of global mercury emissions suggests that the overall contribution from natural sources (primary emissions + re-emissions) and anthropogenic sources is nearly 7527 Mg per year, the uncertainty associated with these estimates are related to the typology of emission sources and source regions.

scholarly journals Global mercury emissions to the atmosphere from anthropogenic and natural sources

2010 ◽  
Vol 10 (2) ◽  
pp. 4719-4752 ◽  
Author(s):  
N. Pirrone ◽  
S. Cinnirella ◽  
X. Feng ◽  
R. B. Finkelman ◽  
H. R. Friedli ◽  
...  
Keyword(s):  
Power Plants ◽  
Point Sources ◽  
Anthropogenic Sources ◽  
Small Scale ◽  
Current Estimate ◽  
Cement Production ◽  
Natural Sources ◽  
Mercury Emissions ◽  
Source Regions ◽  
Primary Emissions

Abstract. This paper provides an up-to-date assessment of global mercury emissions from anthropogenic and natural sources. On an annual basis, natural sources account for 5207 Mg of mercury released to the global atmosphere, including the contribution from re-emission processes, which are emissions of previously deposited mercury originating from anthropogenic and natural sources, and primary emissions from natural reservoirs. Anthropogenic sources, which include a large number of industrial point sources, are estimated to account for 2320 Mg of mercury emitted annually. The major contributions are from fossil-fuel fired power plants (810 Mg yr−1), artisanal small scale gold mining (400 Mg yr−1), non-ferrous metals manufacturing (310 Mg yr−1), cement production (236 Mg yr−1), waste disposal (187 Mg yr−1) and caustic soda production (163 Mg yr−1). Therefore, our current estimate of global mercury emissions suggests that the overall contribution from natural sources (primary emissions+re-emissions) and anthropogenic sources is nearly 7527 Mg per year, the uncertainty associated with these estimates are related to the typology of emission sources and source regions.

scholarly journals Detectability of CO<sub>2</sub> emission plumes of cities and power plants with the Copernicus Anthropogenic CO<sub>2</sub> Monitoring (CO2M) mission

2019 ◽  
Vol 12 (12) ◽  
pp. 6695-6719 ◽  
Author(s):  
Gerrit Kuhlmann ◽  
Grégoire Broquet ◽  
Julia Marshall ◽  
Valentin Clément ◽  
Armin Löscher ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Power Plants ◽  
Atmospheric Transport ◽  
Detection Algorithm ◽  
Daily Basis ◽  
Horizontal Resolution ◽  
Low Noise ◽  
Point Sources ◽  
Added Value ◽  
Small Scale

Abstract. High-resolution atmospheric transport simulations were used to investigate the potential for detecting carbon dioxide (CO2) plumes of the city of Berlin and neighboring power stations with the Copernicus Anthropogenic Carbon Dioxide Monitoring (CO2M) mission, which is a proposed constellation of CO2 satellites with imaging capabilities. The potential for detecting plumes was studied for satellite images of CO2 alone or in combination with images of nitrogen dioxide (NO2) and carbon monoxide (CO) to investigate the added value of measurements of other gases coemitted with CO2 that have better signal-to-noise ratios. The additional NO2 and CO images were either generated for instruments on the same CO2M satellites (2 km× 2 km resolution) or for the Sentinel-5 instrument (7.5 km× 7.5 km) assumed to fly 2 h earlier than CO2M. Realistic CO2, CO and NOX(=NO+NO2) fields were simulated at 1 km× 1 km horizontal resolution with the Consortium for Small-scale Modeling model extended with a module for the simulation of greenhouse gases (COSMO-GHG) for the year 2015, and they were used as input for an orbit simulator to generate synthetic observations of columns of CO2, CO and NO2 for constellations of up to six satellites. A simple plume detection algorithm was applied to detect coherent structures in the images of CO2, NO2 or CO against instrument noise and variability in background levels. Although six satellites with an assumed swath of 250 km were sufficient to overpass Berlin on a daily basis, only about 50 out of 365 plumes per year could be observed in conditions suitable for emission estimation due to frequent cloud cover. With the CO2 instrument only 6 and 16 of these 50 plumes could be detected assuming a high-noise (σVEG50=1.0 ppm) and low-noise (σVEG50=0.5 ppm) scenario, respectively, because the CO2 signals were often too weak. A CO instrument with specifications similar to the Sentinel-5 mission performed worse than the CO2 instrument, while the number of detectable plumes could be significantly increased to about 35 plumes with an NO2 instrument. CO2 and NO2 plumes were found to overlap to a large extent, although NOX had a limited lifetime (assumed to be 4 h) and although CO2 and NOX were emitted with different NOX:CO2 emission ratios by different source types with different temporal and vertical emission profiles. Using NO2 observations from the Sentinel-5 platform instead resulted in a significant spatial mismatch between NO2 and CO2 plumes due to the 2 h time difference between Sentinel-5 and CO2M. The plumes of the coal-fired power plant Jänschwalde were easier to detect with the CO2 instrument (about 40–45 plumes per year), but, again, an NO2 instrument could detect significantly more plumes (about 70). Auxiliary measurements of NO2 were thus found to greatly enhance the capability of detecting the location of CO2 plumes, which will be invaluable for the quantification of CO2 emissions from large point sources.

The Puzzle of Drastic Reduction of Point Source Emissions and Continuing High Deposition of Mercury in Florida

2005 ◽  
Author(s):  
N. J. Themelis
Keyword(s):  
Power Plants ◽  
Climatic Conditions ◽  
South Florida ◽  
Point Sources ◽  
Mercury Deposition ◽  
Similar Reduction ◽  
Deposition Rates ◽  
Mercury Emissions ◽  
Co Precipitation ◽  
Precipitation Season

This report shows that the combined emissions of mercury from major point sources of mercury in Florida decreased from about 4.8 short tons in 1994 to 1.3 tons in recent years. A similar reduction of mercury emissions was reported by Florida DEP for south Florida where the Everglades Park is located: Point sources of emissions decreased from a high of 3.4 short tons (3,100 kg) of mercury in 1991 to 0.22 tons (204 kg) in 2000. The Florida DEP study of the Everglades also showed that the mercury concentrations in largemouth bass and in great egret nestlings decreased by a factor of six between 1991 and 2000. On the other hand, our analysis of 330 sets of weekly mercury deposition data, obtained by the Everglades station of the national Mercury Deposition Network (MDN) showed that the annual average deposition in the Everglades did not change significantly from December 1995 to January 2004. Two other interesting findings were that 73% of the total mercury deposition during those eight years occurred in the high precipitation season, between May and October; and that 40% of the weekly samples taken during this eight-year period represented only 3.8 % of the recorded total deposition of mercury. This paper examines the reasons why the substantial decrease of local and regional point sources of mercury emission has not affected substantially the local deposition rates. A likely answer is that climatic conditions in Florida, associated mainly with the warmer months and higher rates of precipitation and evaporation, have a large effect on a) re-emission of previously deposited mercury and b) co-precipitation of global mercury from the atmosphere. This may also explain why Florida, where the present annual rate of mercury emissions from coal-fired power plants (in kilograms per square kilometer) is one fifth that of Pennsylvania, has mercury deposition rates that are twice those reported by MDN for Pennsylvania.

scholarly journals Accounting for the vertical distribution of emissions in atmospheric CO<sub>2</sub> simulations

2019 ◽  
Vol 19 (7) ◽  
pp. 4541-4559 ◽  
Author(s):  
Dominik Brunner ◽  
Gerrit Kuhlmann ◽  
Julia Marshall ◽  
Valentin Clément ◽  
Oliver Fuhrer ◽  
...  
Keyword(s):  
Power Plants ◽  
Atmospheric Transport ◽  
Traditional Approach ◽  
Vertical Mixing ◽  
Point Sources ◽  
Small Scale ◽  
Near Surface ◽  
Industrial Facilities ◽  
Scale Modeling ◽  
The Impact

Abstract. Inverse modeling of anthropogenic and biospheric CO2 fluxes from ground-based and satellite observations critically depends on the accuracy of atmospheric transport simulations. Previous studies emphasized the impact of errors in simulated winds and vertical mixing in the planetary boundary layer, whereas the potential importance of releasing emissions not only at the surface but distributing them in the vertical was largely neglected. Accounting for elevated emissions may be critical, since more than 50 % of CO2 in Europe is emitted by large point sources such as power plants and industrial facilities. In this study, we conduct high-resolution atmospheric simulations of CO2 with the mesoscale Consortium for Small-scale Modeling model extended with a module for the simulation of greenhouse gases (COSMO-GHG) over a domain covering the city of Berlin and several coal-fired power plants in eastern Germany, Poland and Czech Republic. By including separate tracers for anthropogenic CO2 emitted only at the surface or according to realistic, source-dependent profiles, we find that releasing CO2 only at the surface overestimates near-surface CO2 concentrations in the afternoon on average by 14 % in summer and 43 % in winter over the selected model domain. Differences in column-averaged dry air mole XCO2 fractions are smaller, between 5 % in winter and 8 % in summer, suggesting smaller yet non-negligible sensitivities for inversion modeling studies assimilating satellite rather than surface observations. The results suggest that the traditional approach of emitting CO2 only at the surface is problematic and that a proper allocation of emissions in the vertical deserves as much attention as an accurate simulation of atmospheric transport.

scholarly journals Atmospheric mercury in Australia

Elem Sci Anth ◽  
2020 ◽  
Vol 8 (1) ◽  
Author(s):  
Jenny A. Fisher ◽  
Peter F. Nelson
Keyword(s):  
Southern Hemisphere ◽  
Forest Fires ◽  
Power Plants ◽  
Monsoon Season ◽  
Surface Flux ◽  
Atmospheric Mercury ◽  
Anthropogenic Sources ◽  
Future Research ◽  
Mercury Cycling ◽  
Mercury Emissions

Mercury is a toxic bioaccumulative pollutant, with the atmosphere being the primary pathway for global distribution. Although atmospheric mercury cycling has been extensively monitored and modeled across the Northern Hemisphere, there has long been a dearth of mercury data for the Southern Hemisphere. Recent efforts in Australia are helping to fill this gap, with new observational records that span environments ranging from cool temperate to warm tropical climates and near-source to background conditions. Here, we review recent research on atmospheric mercury in Australia, highlighting new observational constraints on atmospheric concentrations, emissions, and deposition and, where possible, comparing these to model estimates. We also provide our best estimate of the current Australian atmospheric mercury budget. Ambient mercury observations collected to date show unique features not captured at other observing sites across the Southern Hemisphere, including very low concentrations at inland sites and a monsoon season drawdown in the tropical north. Previously compiled estimates of Australian anthropogenic mercury emissions differ substantially due to both methodological differences (e.g., assumptions about mercury control technology in coal-fired power plants) and recent closures of major Australian mercury sources, and none are appropriate for modern-day Australia. For mercury emissions from biomass burning, new measurements from Australian smoke plumes show emission factors for both savanna and temperate forest fires are significantly lower than measured elsewhere in the world, and prior estimates based on non-Australian data are likely too high. Although significant uncertainties remain, our analysis suggests that emissions from terrestrial sources (both newly released and legacy) significantly exceed those from anthropogenic sources. However, recent bidirectional air-surface flux observations suggest this source is likely balanced by deposition and surface uptake at local scales. Throughout, we highlight lingering uncertainties and identify critical future research needs for understanding Australian atmospheric mercury and its role in Southern Hemisphere mercury cycling.

scholarly journals Estimating CO2 Emissions from Large Scale Coal-Fired Power Plants Using OCO-2 Observations and Emission Inventories

Atmosphere ◽  
2021 ◽  
Vol 12 (7) ◽  
pp. 811
Author(s):  
Yaqin Hu ◽  
Yusheng Shi
Keyword(s):  
Power Plant ◽  
Co2 Emissions ◽  
Atmospheric Carbon Dioxide ◽  
Power Plants ◽  
Large Scale ◽  
Global Climate ◽  
Gaussian Model ◽  
Point Sources ◽  
Emission Inventories ◽  
Bottom Up

The concentration of atmospheric carbon dioxide (CO2) has increased rapidly worldwide, aggravating the global greenhouse effect, and coal-fired power plants are one of the biggest contributors of greenhouse gas emissions in China. However, efficient methods that can quantify CO2 emissions from individual coal-fired power plants with high accuracy are needed. In this study, we estimated the CO2 emissions of large-scale coal-fired power plants using Orbiting Carbon Observatory-2 (OCO-2) satellite data based on remote sensing inversions and bottom-up methods. First, we mapped the distribution of coal-fired power plants, displaying the total installed capacity, and identified two appropriate targets, the Waigaoqiao and Qinbei power plants in Shanghai and Henan, respectively. Then, an improved Gaussian plume model method was applied for CO2 emission estimations, with input parameters including the geographic coordinates of point sources, wind vectors from the atmospheric reanalysis of the global climate, and OCO-2 observations. The application of the Gaussian model was improved by using wind data with higher temporal and spatial resolutions, employing the physically based unit conversion method, and interpolating OCO-2 observations into different resolutions. Consequently, CO2 emissions were estimated to be 23.06 ± 2.82 (95% CI) Mt/yr using the Gaussian model and 16.28 Mt/yr using the bottom-up method for the Waigaoqiao Power Plant, and 14.58 ± 3.37 (95% CI) and 14.08 Mt/yr for the Qinbei Power Plant, respectively. These estimates were compared with three standard databases for validation: the Carbon Monitoring for Action database, the China coal-fired Power Plant Emissions Database, and the Carbon Brief database. The comparison found that previous emission inventories spanning different time frames might have overestimated the CO2 emissions of one of two Chinese power plants on the two days that the measurements were made. Our study contributes to quantifying CO2 emissions from point sources and helps in advancing satellite-based monitoring techniques of emission sources in the future; this helps in reducing errors due to human intervention in bottom-up statistical methods.

Design, calibration, and application of an airborne gamma spectrometer system in Switzerland

Geophysics ◽  
1997 ◽  
Vol 62 (5) ◽  
pp. 1369-1378 ◽  
Author(s):  
Georg F. Schwarz ◽  
Ladislaus Rybach ◽  
Emile E. Klingelé
Keyword(s):  
Power Plant ◽  
Nuclear Power ◽  
Power Plants ◽  
Gamma Ray ◽  
Point Sources ◽  
Swiss Alps ◽  
Artificial Radioactivity ◽  
Radiation Level ◽  
Satellite Navigation System ◽  
Emergency Situations

Airborne radiometric surveys are finding increasingly wider applications in environmental mapping and monitoring. They are the most efficient tool to delimit surface contamination and to locate lost radioactive sources. To secure radiometric capability in survey and emergency situations, a new sensitive airborne system has been built that includes an airborne spectrometer with 256 channels and a sodium iodide detector with a total volume of 16.8 liters. A rack mounted PC with memory cards is used for data acquisition, with a GPS satellite navigation system for positioning. The system was calibrated with point sources using a mathematical correction to take into account the effects of gamma‐ray scattering in the ground and in the atmosphere. The calibration was complemented by high precision ground gamma spectrometry and laboratory measurements on rock samples. In Switzerland, two major research programs make use of the capabilities of airborne radiometric measurements. The first one concerns nuclear power plant monitoring. The five Swiss nuclear installations (four power plants and one research facility) and the surrounding regions of each site are surveyed annually. The project goal is to monitor the dose‐rate distribution and to provide a documented baseline database. The measurements show that all sites (with the exception of the Gösgen power plant) can be identified clearly on the maps. No artificial radioactivity that could not be explained by the Chernobyl release or earlier nuclear weapons tests was detected outside of the fenced sites of the nuclear installations. The second program aims at a better evaluation of the natural radiation level in Switzerland. The survey focused on the crystalline rocks of the Central Massifs of the Swiss Alps because of their relatively high natural radioactivity and lithological variability.

Investigation of the Down-Scaling Effects on the Low Swirl Burner and its Application to Microturbines

2018 ◽  
Author(s):  
Alex Frank ◽  
Peter Therkelsen ◽  
Miguel Sierra Aznar ◽  
Vi H. Rapp ◽  
Robert K. Cheng ◽  
...  
Keyword(s):  
Power Systems ◽  
Power Plants ◽  
Energy Savings ◽  
The United States ◽  
Primary Energy ◽  
Department Of Energy ◽  
Small Scale ◽  
United States Department ◽  
Scaling Effects ◽  
Swirl Burner

About 75% of the electric power generated by centralized power plants feeds the energy needs from the residential and commercial sectors. These power plants waste about 67% of primary energy as heat emitting 2 billion tons of CO2 per year in the process (∼ 38% of total US CO2 generated per year) [1]. A study conducted by the United States Department of Energy indicated that developing small-scale combined heat and power systems to serve the commercial and residential sectors could have a significant impact on both energy savings and CO2 emissions. However, systems of this scale historically suffer from low efficiencies for a variety of reasons. From a combustion perspective, at these small scales, few systems can achieve the balance between low emissions and high efficiencies due in part to the increasing sensitivity of the system to hydrodynamic and heat transfer effects. Addressing the hydrodynamic impact, the effects of downscaling on the flowfield evolution were studied on the low swirl burner (LSB) to understand if it could be adapted to systems at smaller scales. Utilizing particle image velocimetry (PIV), three different swirlers were studied ranging from 12 mm to 25.4 mm representing an output range of less than 1 kW to over 23 kW. Results have shown that the small-scale burners tested exhibited similar flowfield characteristics to their larger-scale counterparts in the non-reacting cases studied. Utilizing this data, as a proof of concept, a 14 mm diameter LSB with an output of 3.33 kW was developed for use in microturbine operating on a recuperated Brayton cycle. Emissions results from this burner proved the feasibility of the system at sufficiently lean mixtures. Furthermore, integration of the newly developed LSB into a can style combustor for a microturbine application was successfully completed and comfortably meet the stringent emissions targets. While the analysis of the non-reacting cases was successful, the reacting cases were less conclusive and further investigation is required to gain an understanding of the flowfield evolution which is the subject of future work.

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